Showing papers by "G. I. Nikishin published in 1970"
TL;DR: In this article, the thermal decomposition of α-hydroxyethyl peracetate to peracetic acid and acetaldehyde was studied and the rate constants and activation energy of the decomposition were determined.
Abstract: 1.
α-Hydroxyethyl peracetate (the adduct of peracetic acid with acetaldehyde) reacts extremely readily with cobalt diacetate, whereupon cobalt is converted to the trivalent state.
2.
This reaction plays an important role in the catalytic oxidation of acetaldehyde.
3.
The kinetics of the thermal decomposition ofα-hydroxyethyl peracetate to peracetic acid and acetaldehyde were studied. The rate constants and activation energy of the decomposition were determined.
4 citations
TL;DR: The free radical addition of carbon tetrachloride and chloroform to unsaturated epoxy compounds, initiated by benzoyl peroxide, was carried out in this article.
Abstract: The free radical addition of carbon tetrachloride and chloroform to unsaturated epoxy compounds, initiated by benzoyl peroxide, was carried out nt[mis|Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No 7, pp 1642–1644, July, 1970
1 citations
TL;DR: The kinetics of the decomposition of tertiary butyl hydroperoxide and the rate of generation of free radicals from it at 130° in methyl caproate and its chlorobenzene solutions were studied in this paper.
Abstract: 1.
The kinetics of the decomposition of tertiary butyl hydroperoxide and the rate of generation of free radicals from it at 130° in methyl caproate and its chlorobenzene solutions was studied.
2.
In thermal decomposition in esters, tert-butyl hydroperoxide decomposes chiefly through its acylation by the ester, followed by homolysis of the intermediate perester formed.
1 citations
TL;DR: In this paper, the thermal decomposition of peroxydisuccinic acid and its dimethyl ester was studied in acetic acid, benzene, and isopropanol.
Abstract: 1.
The thermal decomposition of peroxydisuccinic acid and its dimethyl ester was studied in acetic acid, benzene, and isopropanol. In benzene and acetic acid, a first order of the reaction with respect to the peroxide is observed.
2.
Products of thermal decomposition of the peroxides were identified and a mechanism of their formation was proposed.
3.
Radicals formed from peroxydisuccinic acid under the action of UV irradiation and as a result of secondary reactions in the absence of irradiation were investigated by the EPR method. A mechanism of photodecomposition with the participation of radical pair was proposed.