G
G. I. Nikishin
Researcher at Russian Academy of Sciences
Publications - 280
Citations - 583
G. I. Nikishin is an academic researcher from Russian Academy of Sciences. The author has contributed to research in topics: Radical & Homolysis. The author has an hindex of 11, co-authored 280 publications receiving 540 citations.
Papers
More filters
Journal ArticleDOI
Dimerization of 1-alkynes catalyzed by RhCl(PMe3)3. Isolation of the intermediate (alkynyl)(vinyl)rhodium(III) complexes
TL;DR: In this article, the authors showed that the reaction proceeds by alkyne insertion into the metal-hydride bond of the intermediate (alkynyl)(hydride)Rh III complexes VII, VIII to give the (alklynyl)(vinyl) rh III species cis - (IX) and cis- (X) which were isolated.
Journal ArticleDOI
Electrochemical synthesis of cyclopropanes
TL;DR: In this paper, the most promising methods for the synthesis of functionally substituted cyclopropanes, namely, the electrocatalytic cascade and multicomponent transformations of CH acids and also the joint electrolysis of CH acid and activated alkenes or carbonyl compounds in the presence of alkali metal halides as mediators, are discussed.
Journal ArticleDOI
Unusual type of catalysis by paramagnetic cobalt(0) complexes. Isolation of catalytically active 17-electron intermediate, (Ph3P)2Co(CH2CHCH2CH2CHO), in the 4-pentenal intramolecular hydroacylation
TL;DR: In this paper, the kinetics and mechanism of intramolecular hydroacylation catalyzed by complexes Co2(μ-N2)(PPh3)6 (III) and (PPh 3)2Co(dppe) (IV) (dppe-1,2-bis(di-phenylphosphino)ethane) were studied.
Journal ArticleDOI
Synthesis of peroxide compounds by the BF3-catalyzed reaction of acetals and enol ethers with H2O2
A. O. Terent"ev,Alexander V. Kutkin,M. M. Platonov,Ivan I. Vorontsov,M. Yu. Antipin,Yu. N. Ogibin,G. I. Nikishin +6 more
TL;DR: Aliphatic and alicyclic gem-bis-hydroperoxides and their derivatives, bis(1-hydric peroxides), dispiro-and tetraalkyl-1,2,4,5-tetroxanes were synthesized by the reaction of aliphatic alicycic acetals and enol ethers with H2O2 in the presence of BF3 in anhydrous Et2O.
Journal ArticleDOI
Synthesis of peroxides from β,δ-triketones under heterogeneous conditions
TL;DR: The trioxolane ring is formed by the carbonyl groups located in the δ-position with respect to each other as discussed by the authors, which is the same as the trioxoline ring formed by β,δ-triketones.