G. R. Argade

Bio: G. R. Argade is an academic researcher from University of North Texas. The author has contributed to research in topics: Corrosion & Friction stir processing. The author has an hindex of 8, co-authored 15 publications receiving 500 citations. Previous affiliations of G. R. Argade include Missouri University of Science and Technology.

Stress corrosion cracking susceptibility of ultrafine grained Al–Mg–Sc alloy

Abstract: General corrosion and stress corrosion cracking (SCC) behavior of coarse grained, fine grained and ultrafine grained (UFG) AA5083 and Al–Mg–Sc–Zr alloy in different thermomechanical conditions were studied in the present work. Friction stir processing (FSP) was carried out to refine the grain size. The average grain size achieved after FSP for AA5083 was 7±3 μm, whereas that for Al–4Mg–0.8Sc–0.08Zr was 0.39±0.16 μm with 100% UFG microstructure. Linear polarization resistance and cyclic polarization techniques were used to study general corrosion behavior of these alloys in 3.5 wt% NaCl solution. The UFG microstructure showed the highest polarization resistance ( R p ) of ∼93 kΩ which increased to ∼160 kΩ after 24 h of exposure in chloride solution. The peak aged Al–Mg–0.8Sc–0.08Zr showed the most positive breakdown potential with passivity in the range of −800 to −600 mV vs SCE. A power law type relationship was observed between grain size and R p for Al–Mg alloys. SCC susceptibility was estimated in 3.5 wt% NaCl solution using slow strain rate testing (SSRT) at initial strain rate of 10 −6 s −1 .The parent AA5083 alloy showed moderate susceptibility while the FSP AA5083 microstructure showed no susceptibility. The UFG Al–Mg–0.8Sc–0.08Zr condition showed >55% loss in ductility when tested in chloride solution.

Stress corrosion cracking susceptibility of ultrafine grained AZ31

Abstract: In this study, stress corrosion cracking (SCC) behavior of AZ31 magnesium alloy was carried out using slow strain rate testing (SSRT) technique in 3.5 wt% NaCl solution. The influence of microstructural scale on the stress corrosion behavior was investigated in AZ31 alloy with three different mean grain sizes. Single-pass and two-pass friction stir processing (FSP) was employed to obtain fine grain and ultrafine grain microstructures, respectively. For FSP, SSRT specimens were extracted from the processed region. SSRTs were carried out in air and solution at an initial strain rate of 10−6/s. A significant decrease in the ultimate tensile strength was observed for FSP specimens tested in chloride solution as compared to specimens tested in air. More than 75 % loss in total elongation was observed for the specimens tested in chloride solution as compared to the ones tested in air. In comparison with base material, lower time to failure was observed for processed samples. The higher SCC susceptibility of processed microstructure is attributed to increased hydrogen adsorption and favorable basal texture.

Corrosion Inhibition Study of Mg-Nd-Y High Strength Magnesium Alloy Using Organic Inhibitor

Abstract: A study on corrosion inhibition mechanism has been performed on rare earth containing WE43 magnesium alloy in 3.5 wt.% NaCl containing 8-hydroxyquinoline (HQ). After an initial increase in corrosion rate due to the formation of sparingly soluble MgQ2 complex, it was found to decrease owing to inhibition effect of the complex. Scanning electrochemical microscopic analysis showed a decrease in corrosion currents and enhanced resistance to pitting corrosion was observed for WE43 samples in the presence of HQ after an exposure of 48 h. With time, the MgQ2 thus generated formed a protective layer on the Mg alloy surface to prevent further corrosion. The corrosion rate of WE43 samples decreased by ~ 50% in HQ containing medium after a constant exposure of 28 days (from ~ 0.22 mg/cm2 day in no HQ to ~ 0.11 mg/cm2 day in HQ). For the WE43 samples in the presence of HQ, formation of MgO and MgQ2 was detected by x-ray photoelectron spectroscopy and x-ray diffraction. Shallower and smaller pits appeared on the magnesium alloy with HQ in the solution as compared to deeper and larger pits on the samples with no HQ in the solution. The significance of metal-complexing organic agent, hydroxyquinoline, in initial acceleration and subsequent prevention of Mg corrosion via protective MgQ2 complex layer formation is demonstrated.

Principles Of Fluorescence Spectroscopy

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Corrosion of magnesium alloys: the role of alloying

Abstract: The demand for light-weighting in transport and consumer electronics has seen rapid growth in the commercial usage of magnesium (Mg). The major use of Mg is now in cast Mg products, as opposed to the use of Mg as an alloying element in other alloy systems and there is an emerging market of wrought Mg products and biomedical Mg components – such that the past two decades have seen a significant number of new Mg-alloys reported. None-the-less, the corrosion of Mg alloys continues to be a challenge facing engineers seeking weight reductions by deployment of Mg. Herein, authors review the influence of alloying on the corrosion of Mg-alloys, with particular emphasis on the underlying electrochemical kinetics that dictate the ultimate corrosion rate. Such a review focusing on the chemistry–corrosion link, both in depth and in a holistic approach, is lacking. As such the authors do not describe aspects such as high-temperature oxidation or cracking, but focus on delivering the state-of-the-art with regar...

Magnesium extrusion alloys: a review of developments and prospects

Abstract: Magnesium (Mg) alloys have received a significant interest in the past 20 years, owing to a nonlinearly increasing demand for lightweight structural materials. Magnesium extrusions alloys to date h...