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G. Vinitha

Bio: G. Vinitha is an academic researcher from VIT University. The author has contributed to research in topics: Single crystal & Crystal. The author has an hindex of 23, co-authored 251 publications receiving 2106 citations. Previous affiliations of G. Vinitha include B. S. Abdur Rahman University & Anna University.


Papers
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Journal ArticleDOI
TL;DR: In this paper, the L-arginium adipate (LAA) single crystal was analyzed from the X-ray diffraction analysis and the extent of polarization phenomena was examined for selected temperatures at dissimilar frequencies from the dielectric studies.
Abstract: The l-arginium adipate (LAA) single crystal, is an organic component material efficiently grown by a simple technique called slow evaporation solution technique at ambient temperature. The monoclinic crystal system with the space group of P21 is exhibited for LAA from the X-ray diffraction analysis. FTIR spectroscopy that designates different molecular vibrations existing in LAA crystal was studied. The absorbance spectrum from the UV profile proclaims very less cut-off wavelength down to 206 nm and its wide optical band gap is also calculated. The perfection of the crystal is shown from Urbach's energy determination. The extent of polarization phenomena was examined for selected temperatures at dissimilar frequencies from the dielectric studies. The double harmonic output and triple-order nonlinear response for LAA are inspected from Kurtz-Perry and Z-scan technique, respectively.

3 citations

Journal ArticleDOI
TL;DR: In this article, the structural aspects of the grown 2-aminopyridinium diphenylacetate (2-AMD) crystal have been confirmed by single crystal X-ray diffraction study.

3 citations

Journal ArticleDOI
TL;DR: In this article, an organic 4aminopyridine monophthalate (PA4AP) single crystal grown by solvent evaporation at room temperature was studied for third-order nonlinear optical and antibacterial applications.
Abstract: An organic 4-aminopyridine monophthalate (PA4AP) single crystal grown by solvent evaporation at room temperature was studied for third-order nonlinear optical and antibacterial applications. The title material was found to crystallize in a non-centrosymmetric orthorhombic system with space group P212121, and the crystallographic information was acquired by its response to X-ray diffraction analysis. The functional groups and their different modes of vibration were studied by FTIR spectroscopy to identify the various chemical bonds present in PA4AP. Optical absorption study revealed less absorption in the visible region with an absorption cut-off wavelength at 315 nm, below which the material shows complete absorption. The title crystal was characterized for luminescence and based on this the inter-band structures were analysed for crystal defects. Mechanical and dielectric properties with an emphasis on solid-state parameters were investigated to understand the crystal stability for device applications. Kurtz–Perry powder analysis revealed that the PA4AP crystal has comparable second harmonic generation efficiency with the well-known KDP crystal. The third-order nonlinear optical susceptibility (χ(3)), nonlinear absorption coefficient (β) and nonlinear refractive index (n2) of title material were found to be 1.06 × 10−6 (esu), 6.51 × 10−5 (cm W−1) and 2.33 × 10−8 (cm2 W−1), respectively. The reverse saturable absorption observed in open aperture Z-scan indicates the suitability of PA4AP for optical limiting application. The antibacterial activity was investigated against few foodborne pathogens which show the antibacterial stability of PA4AP against Shigella flexneri and Vibrio cholerae bacteria.

3 citations

Journal ArticleDOI
29 Sep 2020
TL;DR: In this article, organic non-linear optical BISA single crystals were harvested from methanol solution by slow evaporation method and the properties of the grown BISA crystal were confirmed by PXRD.
Abstract: Organic non-linear optical Benzimidazolium salicylate (BISA) single crystals have been harvested from methanol solution by slow evaporation method. The grown crystals belong to the monoclinic crystal system with space group P21/c. Good crystalline nature of grown BISA crystal was confirmed by PXRD. The FTIR spectrum analysis affirms the presence of functional groups in BISA crystal. From the UV‒Vis-Absorption spectrum, the lower cut-off wavelength (356 nm) and its energy band gap and linear refractive index were calculated. Luminescence spectrum was recorded to explore the emission peak at 426 nm. The mechanical strength of BISA crystal was determined by Vickers microhardness tester and mechanical parameters like C11, Hk, Kc, and Bi were calculated for the first time. Dielectric properties of grown crystals were systematically investigated for different temperatures. Further, electronic polarizability (α) were calculated using Penn analysis and Clausius‒Mossotti equation. Z‒scan measurement was taken to explore the third-order NLO properties of BISA crystal. For the first attempt, the BISA crystals were tested against five human pathogenic bacterial, i.e. Bacillus cereus, Staphylococcus aureus, Shigella flexneri, Vibrio cholerae, and Klebsiella pneumoniae. Existing results established that Benzimidazolium salicylate crystals might find useful applications in nonlinear optics and antimicrobial field.

3 citations

Journal ArticleDOI
TL;DR: In this paper, single crystals of pure and crystal violet dye-doped L-Argininium bis dihydrogen phosphate (LADP) were grown using slow evaporation technique.

3 citations


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Journal Article
TL;DR: In this article, a class of π;-conjugated compounds that exhibit large δ (as high as 1, 250 × 10−50 cm4 s per photon) and enhanced two-photon sensitivity relative to ultraviolet initiators were developed and used to demonstrate a scheme for three-dimensional data storage which permits fluorescent and refractive read-out, and the fabrication of 3D micro-optical and micromechanical structures, including photonic-bandgap-type structures.
Abstract: Two-photon excitation provides a means of activating chemical or physical processes with high spatial resolution in three dimensions and has made possible the development of three-dimensional fluorescence imaging, optical data storage, and lithographic microfabrication. These applications take advantage of the fact that the two-photon absorption probability depends quadratically on intensity, so under tight-focusing conditions, the absorption is confined at the focus to a volume of order λ3 (where λ is the laser wavelength). Any subsequent process, such as fluorescence or a photoinduced chemical reaction, is also localized in this small volume. Although three-dimensional data storage and microfabrication have been illustrated using two-photon-initiated polymerization of resins incorporating conventional ultraviolet-absorbing initiators, such photopolymer systems exhibit low photosensitivity as the initiators have small two-photon absorption cross-sections (δ). Consequently, this approach requires high laser power, and its widespread use remains impractical. Here we report on a class of π;-conjugated compounds that exhibit large δ (as high as 1, 250 × 10−50 cm4 s per photon) and enhanced two-photon sensitivity relative to ultraviolet initiators. Two-photon excitable resins based on these new initiators have been developed and used to demonstrate a scheme for three-dimensional data storage which permits fluorescent and refractive read-out, and the fabrication of three-dimensional micro-optical and micromechanical structures, including photonic-bandgap-type structures.

1,833 citations

Journal ArticleDOI
TL;DR: This Review gives emphasis to the nonlinear optical properties of photoactive materials for the function of optical power limiting and describes the known mechanisms of optical limiting for the different types of materials.
Abstract: The control of luminous radiation has extremely important implications for modern and future technologies as well as in medicine. In this Review, we detail chemical structures and their relevant photophysical features for various groups of materials, including organic dyes such as metalloporphyrins and metallophthalocyanines (and derivatives), other common organic materials, mixed metal complexes and clusters, fullerenes, dendrimeric nanocomposites, polymeric materials (organic and/or inorganic), inorganic semiconductors, and other nanoscopic materials, utilized or potentially useful for the realization of devices able to filter in a smart way an external radiation. The concept of smart is referred to the characteristic of those materials that are capable to filter the radiation in a dynamic way without the need of an ancillary system for the activation of the required transmission change. In particular, this Review gives emphasis to the nonlinear optical properties of photoactive materials for the functi...

424 citations

Journal ArticleDOI
TL;DR: In this article, a review highlights the applied protocols to ameliorate the photoactivity of graphitic carbon nitride (g-C3N4) based nanocomposites through combining with various materials.

381 citations

Journal ArticleDOI
TL;DR: In this article, the authors survey the recent advances in nonlinear optics and the applications of two-dimensional (2D) materials and highlight a few representative current applications of 2D materials to photonic and optoelectronic devices.
Abstract: In this review, we survey the recent advances in nonlinear optics and the applications of two-dimensional (2D) materials. We briefly cover the key developments pertaining to research in the nonlinear optics of graphene, the quintessential 2D material. Subsequently, we discuss the linear and nonlinear optical properties of several other 2D layered materials, including transition metal chalcogenides, black phosphorus, hexagonal boron nitride, perovskites, and topological insulators, as well as the recent progress in hybrid nanostructures containing 2D materials, such as composites with dyes, plasmonic particles, 2D crystals, and silicon integrated structures. Finally, we highlight a few representative current applications of 2D materials to photonic and optoelectronic devices.

235 citations

Journal ArticleDOI
TL;DR: In this article, the nonlinear optical properties of metal nanoparticles (including copper, silver, gold, and bismuth nanoparticles) doped in various bases have been discussed.
Abstract: Metal nanoparticles (MNPs) hold great technological promise because of the possibility of engineering their electronic and optical properties through material design. One of the effective methods to fabricate MNPs is ion implantation. In this review, recent results on the nonlinear optical properties of nanoparticles (including copper, silver, gold, and bismuth nanoparticles) doped in various bases have been discussed. Some specific optical nonlinear properties, such as nonlinear refraction, two-photon absorption, and optical limiting, for femtosecond, picosecond, and nanosecond laser pulses have also been covered. In addition to ion implantation, we have summarized several other methods for the preparation of composite materials, and Z-scan has been used to study the nonlinear optical properties of these materials.

232 citations