G
George V. Buxton
Researcher at University of Leeds
Publications - 99
Citations - 3599
George V. Buxton is an academic researcher from University of Leeds. The author has contributed to research in topics: Radiolysis & Aqueous solution. The author has an hindex of 28, co-authored 99 publications receiving 3358 citations. Previous affiliations of George V. Buxton include University of Tokyo & Central Electricity Generating Board.
Papers
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Journal ArticleDOI
Re-evaluation of the thiocyanate dosimeter for pulse radiolysis
George V. Buxton,Craig R. Stuart +1 more
TL;DR: In this article, the super-Fricke dosimeter was used as a secondary standard for the thiocyanate dosimeter in O2-saturated water and the results were improved to 3.47 ± 0.06.
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Estimation of rate constants for near-diffusion-controlled reactions in water at high temperatures
TL;DR: In this paper, it was shown that only a small fraction of the reactions which are pertinent to water radiolysis are truly diffusion controlled at elevated temperatures, with the exception of reactions of the hydrated electron with nitrate and nitrite ions and nitrous oxide.
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CAPRAM 2.4 (MODAC mechanism): An extended and condensed tropospheric aqueous phase mechanism and its application
Barbara Ervens,Christian George,J. E. Williams,J. E. Williams,George V. Buxton,G. A. Salmon,Mark Bydder,F. Wilkinson,Frank Dentener,Philippe Mirabel,Ralf Wolke,Hartmut Herrmann +11 more
TL;DR: A detailed and extended chemical mechanism describing tropospheric aqueous phase chemistry (147 species and 438 reactions) is presented in this article as Chemical Aqueous Phase Radical Mechanism (CAPRAM) 2.4 (MODAC mechanism).
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The reactivity of chlorine atoms in aqueous solution Part II.The equilibrium SO4-+Cl-ClNsbd+SO42-
TL;DR: In this article, a study of the two simultaneous equilibria, reactions (1) and (2), has been performed by pulse radiolysis in Ar-saturated aqueous solution at 25°C.
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Reactivity of chlorine atoms in aqueous solution Part 1The equilibrium ClMNsbd+Cl-Cl2-
TL;DR: In this article, the equilibrium constant for reaction (1) has been determined in neutral solution to be (1.4±0.1)×105 d mol-1, with forward and reverse rate constants, k1 and k-1.