G
Gianni Palmieri
Researcher at University of Camerino
Publications - 119
Citations - 2304
Gianni Palmieri is an academic researcher from University of Camerino. The author has contributed to research in topics: Enantiopure drug & Alkylation. The author has an hindex of 25, co-authored 118 publications receiving 2224 citations. Previous affiliations of Gianni Palmieri include Sapienza University of Rome & Ca' Foscari University of Venice.
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The reaction of vinyl grignard reagents with 2-substituted nitroarenes: A new approach to the synthesis of 7-substituted indoles
TL;DR: The reaction of three moles of vinylmagnesium bromide with one mole of nitroarene leads to the formation of indoles after aqueous work up of the mixture as mentioned in this paper.
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Chemo- and Diastereoselective Reduction of .beta.-Enamino Esters: A Convenient Synthesis of Both cis- and trans-.gamma.-Amino Alcohols and .beta.-Amino Esters
TL;DR: In this paper, the chemo-and diastereoselective reduction of β-enamino esters is described, with the use of inexpensive reagents Na/i-PrOH or NaHB(OAc) 3 /AcOH, respectively.
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Stereoselective Reduction of Enantiopure β-Enamino Esters by Hydride: A Convenient Synthesis of Both Enantiopure β-Amino Esters
TL;DR: By choosing the appropriate chiral amine, this procedure allows a straightforward preparation of both the enantiopure β-amino esters and derivatives with known biological activity, using readily available starting materials and inexpensive reagents and conditions.
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Solvent-Free Asymmetric Aminoalkylation of Electron-Rich Aromatic Compounds: Stereoselective Synthesis of Aminoalkylnaphthols by Crystallization-Induced Asymmetric Transformation
TL;DR: Electron-rich aromatic compounds such as 2-naphthol give a faster and asymmetric 1-aminoalkylation with high yields when treated with (R)-1-phenylethylamine and aromatic aldehydes in solvent-free conditions.
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A practical o-hydroxybenzylamines promoted enantioselective addition of dialkylzincs to aldehydes with asymmetric amplification
TL;DR: In this paper, a strong positive nonlinear relationship was observed for the reaction enantioselctivity with the use of o -hydroxybenzylamine 2e, which is very accessible through a short stereoselective synthetic route.