Giorgio Caramanna

Bio: Giorgio Caramanna is an academic researcher from Heriot-Watt University. The author has contributed to research in topics: Sinkhole & Water column. The author has an hindex of 12, co-authored 28 publications receiving 2518 citations. Previous affiliations of Giorgio Caramanna include University of Nottingham & United States Environmental Protection Agency.

An overview of current status of carbon dioxide capture and storage technologies

Abstract: Global warming and climate change concerns have triggered global efforts to reduce the concentration of atmospheric carbon dioxide (CO2). Carbon dioxide capture and storage (CCS) is considered a crucial strategy for meeting CO2 emission reduction targets. In this paper, various aspects of CCS are reviewed and discussed including the state of the art technologies for CO2 capture, separation, transport, storage, leakage, monitoring, and life cycle analysis. The selection of specific CO2 capture technology heavily depends on the type of CO2 generating plant and fuel used. Among those CO2 separation processes, absorption is the most mature and commonly adopted due to its higher efficiency and lower cost. Pipeline is considered to be the most viable solution for large volume of CO2 transport. Among those geological formations for CO2 storage, enhanced oil recovery is mature and has been practiced for many years but its economical viability for anthropogenic sources needs to be demonstrated. There are growing interests in CO2 storage in saline aquifers due to their enormous potential storage capacity and several projects are in the pipeline for demonstration of its viability. There are multiple hurdles to CCS deployment including the absence of a clear business case for CCS investment and the absence of robust economic incentives to support the additional high capital and operating costs of the whole CCS process.

A review of mineral carbonation technologies to sequester CO2

Abstract: Carbon dioxide (CO2) capture and sequestration includes a portfolio of technologies that can potentially sequester billions of tonnes of CO2 per year Mineral carbonation (MC) is emerging as a potential CCS technology solution to sequester CO2 from smaller/medium emitters, where geological sequestration is not a viable option In MC processes, CO2 is chemically reacted with calcium- and/or magnesium-containing materials to form stable carbonates This work investigates the current advancement in the proposed MC technologies and the role they can play in decreasing the overall cost of this CO2 sequestration route In situ mineral carbonation is a very promising option in terms of resources available and enhanced security, but the technology is still in its infancy and transport and storage costs are still higher than geological storage in sedimentary basins ($17 instead of $8 per tCO2) Ex situ mineral carbonation has been demonstrated on pilot and demonstration scales However, its application is currently limited by its high costs, which range from $50 to $300 per tCO2 sequestered Energy use, the reaction rate and material handling are the key factors hindering the success of this technology The value of the products seems central to render MC economically viable in the same way as conventional CCS seems profitable only when combined with EOR Large scale projects such as the Skyonic process can help in reducing the knowledge gaps on MC fundamentals and provide accurate costing and data on processes integration and comparison The literature to date indicates that in the coming decades MC can play an important role in decarbonising the power and industrial sector

A review of natural sinkhole phenomena in Italian plain areas

Abstract: Italian sinkholes, which are mainly related to karst phenomena (i.e., solution sinkholes, collapse sinkholes, etc.), are widespread along the Apennine ridge and in pedemontane areas where there are carbonatic bedrock outcrops. However, other collapses, which seem unrelated to karst dissolution, have been identified in plain areas with a thick sedimentary cover over buried bedrock. The main goal of this work is to study the geological, geomorphological, and structural setting of these areas to identify the possible mechanism of the generation and evolution of these collapses. About 750 cases were identified by research based on historical archives, specific geological literature, and information from local administrations. Geological, geomorphological, and hydro-geochemical surveys were conducted in 300 cases, supported by literature, borehole, and seismic data. A few examples were discarded because they could be ascribed to karst dissolution, volcanic origin (i.e., maar), or anthropogenic causes. Field studies regarding the other 450 cases are in progress. These cases occur along the Tyrrhenian margin (Latium, Abruzzo, Campania, Tuscany) in tectonic, coastal, and alluvial plains close to carbonate ridges. These plains are characterized by the presence of pressurized aquifers in the buried bedrock, overlaid by unconsolidated sediments (i.e., clay, sands, pyroclastic deposits, etc.). The majority of these collapses are aligned along regional master and seismogenetic faults. About 50% of the studied cases host small lakes or ponds, often characterized by highly mineralized springs enriched with CO2 and H2S. The Periadriatic margin does not seem to be affected by these phenomena, and only a few cases have been found in Sicily, Sardinia, and Liguria. The obtained scenarios suggests that this type of collapse could be related to upward erosion through vertical conduits (i.e., deep faults) caused by deep piping processes whose erosive strength is increased by the presence of acidic fluids. In order to distinguish these collapses from typical karst dissolution phenomena, they are defined as deep piping sinkholes (DPS).

A Review of Mineral Carbonation Technologies to Sequester CO2

Abstract: Carbon dioxide (CO2) capture and sequestration includes a portfolio of technologies that can potentially sequester billions of tonnes of CO2 per year. Mineral carbonation (MC) is emerging as a potential CCS technology solution to sequester CO2 from smaller/medium emitters, where geological sequestration is not a viable option. In MC processes, CO2 is chemically reacted with calcium- and/or magnesium-containing materials to form stable carbonates. This work investigates the current advancement in the proposed MC technologies and the role they can play in decreasing the overall cost of this CO2 sequestration route. In situ mineral carbonation is a very promising option in terms of resources available and enhanced security, but the technology is still in its infancy and transport and storage costs are still higher than geological storage in sedimentary basins ($17 instead of $8 per tCO2). Ex situ mineral carbonation has been demonstrated on pilot and demonstration scales. However, its application is currently limited by its high costs, which range from $50 to $300 per tCO2 sequestered. Energy use, the reaction rate and material handling are the key factors hindering the success of this technology. The value of the products seems central to render MC economically viable in the same way as conventional CCS seems profitable only when combined with EOR. Large scale projects such as the Skyonic process can help in reducing the knowledge gaps on MC fundamentals and provide accurate costing and data on processes integration and comparison. The literature to date indicates that in the coming decades MC can play an important role in decarbonising the power and industrial sector.

An overview of current status of carbon dioxide capture and storage technologies

Abstract: Global warming and climate change concerns have triggered global efforts to reduce the concentration of atmospheric carbon dioxide (CO2). Carbon dioxide capture and storage (CCS) is considered a crucial strategy for meeting CO2 emission reduction targets. In this paper, various aspects of CCS are reviewed and discussed including the state of the art technologies for CO2 capture, separation, transport, storage, leakage, monitoring, and life cycle analysis. The selection of specific CO2 capture technology heavily depends on the type of CO2 generating plant and fuel used. Among those CO2 separation processes, absorption is the most mature and commonly adopted due to its higher efficiency and lower cost. Pipeline is considered to be the most viable solution for large volume of CO2 transport. Among those geological formations for CO2 storage, enhanced oil recovery is mature and has been practiced for many years but its economical viability for anthropogenic sources needs to be demonstrated. There are growing interests in CO2 storage in saline aquifers due to their enormous potential storage capacity and several projects are in the pipeline for demonstration of its viability. There are multiple hurdles to CCS deployment including the absence of a clear business case for CCS investment and the absence of robust economic incentives to support the additional high capital and operating costs of the whole CCS process.

Carbon capture and storage (CCS): the way forward

Abstract: Carbon capture and storage (CCS) is broadly recognised as having the potential to play a key role in meeting climate change targets, delivering low carbon heat and power, decarbonising industry and, more recently, its ability to facilitate the net removal of CO2 from the atmosphere. However, despite this broad consensus and its technical maturity, CCS has not yet been deployed on a scale commensurate with the ambitions articulated a decade ago. Thus, in this paper we review the current state-of-the-art of CO2 capture, transport, utilisation and storage from a multi-scale perspective, moving from the global to molecular scales. In light of the COP21 commitments to limit warming to less than 2 °C, we extend the remit of this study to include the key negative emissions technologies (NETs) of bioenergy with CCS (BECCS), and direct air capture (DAC). Cognisant of the non-technical barriers to deploying CCS, we reflect on recent experience from the UK's CCS commercialisation programme and consider the commercial and political barriers to the large-scale deployment of CCS. In all areas, we focus on identifying and clearly articulating the key research challenges that could usefully be addressed in the coming decade.

The technological and economic prospects for CO2 utilization and removal

Abstract: The capture and use of carbon dioxide to create valuable products might lower the net costs of reducing emissions or removing carbon dioxide from the atmosphere. Here we review ten pathways for the utilization of carbon dioxide. Pathways that involve chemicals, fuels and microalgae might reduce emissions of carbon dioxide but have limited potential for its removal, whereas pathways that involve construction materials can both utilize and remove carbon dioxide. Land-based pathways can increase agricultural output and remove carbon dioxide. Our assessment suggests that each pathway could scale to over 0.5 gigatonnes of carbon dioxide utilization annually. However, barriers to implementation remain substantial and resource constraints prevent the simultaneous deployment of all pathways. Ten pathways for the utilization of carbon dioxide are reviewed, considering their potential scale, economics and barriers to implementation.

Recent Advances in Carbon Dioxide Hydrogenation to Methanol via Heterogeneous Catalysis.

Abstract: The utilization of fossil fuels has enabled an unprecedented era of prosperity and advancement of well-being for human society. However, the associated increase in anthropogenic carbon dioxide (CO2) emissions can negatively affect global temperatures and ocean acidity. Moreover, fossil fuels are a limited resource and their depletion will ultimately force one to seek alternative carbon sources to maintain a sustainable economy. Converting CO2 into value-added chemicals and fuels, using renewable energy, is one of the promising approaches in this regard. Major advances in energy-efficient CO2 conversion can potentially alleviate CO2 emissions, reduce the dependence on nonrenewable resources, and minimize the environmental impacts from the portions of fossil fuels displaced. Methanol (CH3OH) is an important chemical feedstock and can be used as a fuel for internal combustion engines and fuel cells, as well as a platform molecule for the production of chemicals and fuels. As one of the promising approaches, thermocatalytic CO2 hydrogenation to CH3OH via heterogeneous catalysis has attracted great attention in the past decades. Major progress has been made in the development of various catalysts including metals, metal oxides, and intermetallic compounds. In addition, efforts are also put forth to define catalyst structures in nanoscale by taking advantage of nanostructured materials, which enables the tuning of the catalyst composition and modulation of surface structures and potentially endows more promising catalytic performance in comparison to the bulk materials prepared by traditional methods. Despite these achievements, significant challenges still exist in developing robust catalysts with good catalytic performance and long-term stability. In this review, we will provide a comprehensive overview of the recent advances in this area, especially focusing on structure-activity relationship, as well as the importance of combining catalytic measurements, in situ characterization, and theoretical studies in understanding reaction mechanisms and identifying key descriptors for designing improved catalysts.