To say that this is the best book on the quantum theory of fields is no praise, since to my knowledge it is the only book on this subject But it is a very good and most useful book The original was written in German and appeared in 1942 This is a translation with some minor changes A few remarks have been added, concerning meson theory and nuclear forces, also footnotes referring to modern work in this field, and finally an appendix on the symmetrization of the energy momentum tensor according to Belinfante Quantum Theory of Fields Prof Gregor Wentzel Translated from the German by Charlotte Houtermans and J M Jauch Pp ix + 224, (New York and London: Interscience Publishers, Inc, 1949) 36s

Quantum Theory of Fields

Stochastic thermodynamics as reviewed here systematically provides a framework for extending the notions of classical thermodynamics such as work, heat and entropy production to the level of individual trajectories of well-defined non-equilibrium ensembles. It applies whenever a non-equilibrium process is still coupled to one (or several) heat bath(s) of constant temperature. Paradigmatic systems are single colloidal particles in time-dependent laser traps, polymers in external flow, enzymes and molecular motors in single molecule assays, small biochemical networks and thermoelectric devices involving single electron transport. For such systems, a first-law like energy balance can be identified along fluctuating trajectories. For a basic Markovian dynamics implemented either on the continuum level with Langevin equations or on a discrete set of states as a master equation, thermodynamic consistency imposes a local-detailed balance constraint on noise and rates, respectively. Various integral and detailed fluctuation theorems, which are derived here in a unifying approach from one master theorem, constrain the probability distributions for work, heat and entropy production depending on the nature of the system and the choice of non-equilibrium conditions. For non-equilibrium steady states, particularly strong results hold like a generalized fluctuation–dissipation theorem involving entropy production. Ramifications and applications of these concepts include optimal driving between specified states in finite time, the role of measurement-based feedback processes and the relation between dissipation and irreversibility. Efficiency and, in particular, efficiency at maximum power can be discussed systematically beyond the linear response regime for two classes of molecular machines, isothermal ones such as molecular motors, and heat engines such as thermoelectric devices, using a common framework based on a cycle decomposition of entropy production. (Some figures may appear in colour only in the online journal) This article was invited by Erwin Frey.

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Stochastic thermodynamics, fluctuation theorems and molecular machines

It is demonstrated that an isolated generic quantum many-body system does relax to a state well described by the standard statistical mechanical prescription The thermalization happens at the level of individual eigenstates, allowing the computation of thermal averages from knowledge of any eigenstate in the microcanonical energy window An understanding of the temporal evolution of isolated many-body quantum systems has long been elusive Recently, meaningful experimental studies1,2 of the problem have become possible, stimulating theoretical interest3,4,5,6,7 In generic isolated systems, non-equilibrium dynamics is expected8,9 to result in thermalization: a relaxation to states in which the values of macroscopic quantities are stationary, universal with respect to widely differing initial conditions, and predictable using statistical mechanics However, it is not obvious what feature of many-body quantum mechanics makes quantum thermalization possible in a sense analogous to that in which dynamical chaos makes classical thermalization possible10 For example, dynamical chaos itself cannot occur in an isolated quantum system, in which the time evolution is linear and the spectrum is discrete11 Some recent studies4,5 even suggest that statistical mechanics may give incorrect predictions for the outcomes of relaxation in such systems Here we demonstrate that a generic isolated quantum many-body system does relax to a state well described by the standard statistical-mechanical prescription Moreover, we show that time evolution itself plays a merely auxiliary role in relaxation, and that thermalization instead happens at the level of individual eigenstates, as first proposed by Deutsch12 and Srednicki13 A striking consequence of this eigenstate-thermalization scenario, confirmed for our system, is that knowledge of a single many-body eigenstate is sufficient to compute thermal averages—any eigenstate in the microcanonical energy window will do, because they all give the same result

Thermalization and its mechanism for generic isolated quantum systems

Annals of physics

We extend the work of Kurchan on the Gallavotti–Cohen fluctuation theorem, which yields a symmetry property of the large deviation function, to general Markov processes. These include jump processes describing the evolution of stochastic lattice gases driven in the bulk or through particle reservoirs, general diffusive processes in physical and/or velocity space, as well as Hamiltonian systems with stochastic boundary conditions. For dynamics satisfying local detailed balance we establish a link between the average of the action functional in the fluctuation theorem and the macroscopic entropy production. This gives, in the linear regime, an alternative derivation of the Green–Kubo formula and the Onsager reciprocity relations. In the nonlinear regime consequences of the new symmetry are harder to come by and the large deviation functional difficult to compute. For the asymmetric simple exclusion process the latter is determined explicitly using the Bethe ansatz in the limit of large N.

A gallavotti-cohen-type symmetry in the large deviation functional for stochastic dynamics

Ruelle`s principle for turbulence leading to what is usually called the Sinai-Ruelle-Bowen (SRB) distribution is applied to the statistical mechanics of many particle systems in nonequilibrium stationary states. A specific prediction, obtained without the need to construct explicitly the SRB itself, is shown to be in agreement with a recent computer experiment on a strongly sheared fluid. This presents the first test of the principle on a many particle system far from equilibrium. A possible application to fluid mechanics is also discussed.

Dynamical Ensembles in Nonequilibrium Statistical Mechanics.

We propose, as a generalization of an idea of Ruelle's to describe turbulent fluid flow, a chaotic hypothesis for reversible dissipative many-particle systems in nonequilibrium stationary states in general. This implies an extension of the zeroth law of thermodynamics to nonequilibrium states and it leads to the identification of a unique distribution μ describing the asymptotic properties of the time evolution of the system for initial data randomly chosen with respect to a uniform distribution on phase space. For conservative systems in thermal equilibrium the chaotic hypothesis implies the ergodic hypothesis. We outline a procedure to obtain the distribution μ: it leads to a new unifying point of view for the phase space behavior of dissipative and conservative systems. The chaotic hypothesis is confirmed in a nontrivial, parameter-free, way by a recent computer experiment on the entropy production fluctuations in a shearing fluid far from equilibrium. Similar applications to other models are proposed, in particular to a model for the Kolmogorov-Obuchov theory for turbulent flow.

Dynamical ensembles in stationary states

1. Classical Statistical Mechanics.- 2. Statistical Ensembles.- 3. Equipartition and Critique.- 4. Thermodynamic Limit and Stability.- 5. Phase Transitions.- 6. Coexistence of Phases.- 7. Exactly Soluble Models.- 8. Brownian Motion.- 9. Coarse Graining and Nonequilibrium.- Name Index.

https://physicstoday.scitation.org/doi/pdf/10.1063/1.1381111

Statistical Mechanics: A Short Treatise

Aspects of the modern dynamical systems approach to thermodynamics of stationary states out of equilibrium with attention to the original conceptions which arose at the beginnings of Statistical Mechanics

Nonequilibrium thermodynamics

We show that the ``fluctuation theorem,'' a consequence of the chaotic hypothesis of G. Gallavotti and E. G. D. Cohen [Phys. Rev. Lett. 74, 2694\char21{}2697 (1995); J. Stat. Phys. 80, 931\char21{}970 (1995)] can be interpreted as extending to arbitrary forcing fields Green-Kubo's formulas, hence Onsager's reciprocity, in a class of reversible nonequilibrium statistical mechanical systems.

Giovanni Gallavotti

Papers

Dynamical Ensembles in Nonequilibrium Statistical Mechanics.

Dynamical ensembles in stationary states

Statistical Mechanics: A Short Treatise

Nonequilibrium thermodynamics

Extension of Onsager's Reciprocity to Large Fields and the Chaotic Hypothesis.