Guoqiang Li

Bio: Guoqiang Li is an academic researcher from Louisiana State University. The author has contributed to research in topics: Shape-memory polymer & Catalysis. The author has an hindex of 65, co-authored 528 publications receiving 16890 citations. Previous affiliations of Guoqiang Li include Henan University & Beijing Institute of Genomics.

A highly efficient flexible dye-sensitized solar cell based on nickel sulfide/platinum/titanium counter electrode

Abstract: A composite film of nickel sulfide/platinum/titanium foil (NiS/Pt/Ti) with low cost and high electrocatalytic activity was synthesized by the use of an in situ electropolymerization route and proposed as a counter electrode (CE) catalyst for flexible dye-sensitized solar cells (FDSSCs). The FDSSC with the NiS/Pt/Ti CE exhibited a comparable power conversion efficiency of 7.20% to the FDSSC with the platinum/titanium (Pt/Ti) CE showing 6.07%. The surface morphology of the NiS/Pt/Ti CE with one-dimensional (1D) structure is characterized by using the scanning electron microscopy (SEM). The NiS/Pt/Ti CE also displayed multiple electrochemical functions of excellent conductivity, great electrocatalytic ability for iodine/triiodine, and low charge transfer resistance of 2.61 ± 0.02 Ω cm2, which were characterized by using the cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS), and Tafel polarization plots. The photocurrent-photovoltage (J-V) character curves were further used to calculate the theoretical optical light performance parameters of the FDSSCs. It may be said that the NiS/Pt/Ti counter electrode is a promising catalytic material to replace the expensive platinum in FDSSCs.

A review of stimuli-responsive polymers for smart textile applications

Abstract: Stimuli-responsive polymers (SRPs) are smart materials which can show noticeable changes in their properties with environmental stimulus variations. Novel functionalities can be delivered to textiles by integrating smart SRPs into them. SRPs inclusive of thermal-responsive polymers, moisture-responsive polymers, thermal-responsive hydrogels, pH-responsive hydrogels, and light-responsive polymers have been applied in textiles to improve or achieve textile smart functionalities. The functionalities include aesthetic appeal, comfort, textile soft display, smart controlled drug release, fantasy design with color changing, wound monitoring, smart wetting properties and protection against extreme variations in environmental conditions. In this review, the applications of SRPs in the textile and clothing sector are elucidated; the associated constraints in fabrication processes for textiles and their potential applications in the near future are discussed.

Broad histone H3K4me3 domains in mouse oocytes modulate maternal-to-zygotic transition

Abstract: Maternal-to-zygotic transition (MZT) is essential for the formation of a new individual, but is still poorly understood despite recent progress in analysis of gene expression and DNA methylation in early embryogenesis. Dynamic histone modifications may have important roles in MZT, but direct measurements of chromatin states have been hindered by technical difficulties in profiling histone modifications from small quantities of cells. Recent improvements allow for 500 cell-equivalents of chromatin per reaction, but require 10,000 cells for initial steps or require a highly specialized microfluidics device that is not readily available. We developed a micro-scale chromatin immunoprecipitation and sequencing (μChIP-seq) method, which we used to profile genome-wide histone H3 lysine methylation (H3K4me3) and acetylation (H3K27ac) in mouse immature and metaphase II oocytes and in 2-cell and 8-cell embryos. Notably, we show that ~22% of the oocyte genome is associated with broad H3K4me3 domains that are anti-correlated with DNA methylation. The H3K4me3 signal becomes confined to transcriptional-start-site regions in 2-cell embryos, concomitant with the onset of major zygotic genome activation. Active removal of broad H3K4me3 domains by the lysine demethylases KDM5A and KDM5B is required for normal zygotic genome activation and is essential for early embryo development. Our results provide insight into the onset of the developmental program in mouse embryos and demonstrate a role for broad H3K4me3 domains in MZT.

I and i

Abstract: There is, I think, something ethereal about i —the square root of minus one. I remember first hearing about it at school. It seemed an odd beast at that time—an intruder hovering on the edge of reality. Usually familiarity dulls this sense of the bizarre, but in the case of i it was the reverse: over the years the sense of its surreal nature intensified. It seemed that it was impossible to write mathematics that described the real world in …

Fast parallel algorithms for short-range molecular dynamics

Abstract: Three parallel algorithms for classical molecular dynamics are presented. The first assigns each processor a fixed subset of atoms; the second assigns each a fixed subset of inter-atomic forces to compute; the third assigns each a fixed spatial region. The algorithms are suitable for molecular dynamics models which can be difficult to parallelize efficiently—those with short-range forces where the neighbors of each atom change rapidly. They can be implemented on any distributed-memory parallel machine which allows for message-passing of data between independently executing processors. The algorithms are tested on a standard Lennard-Jones benchmark problem for system sizes ranging from 500 to 100,000,000 atoms on several parallel supercomputers--the nCUBE 2, Intel iPSC/860 and Paragon, and Cray T3D. Comparing the results to the fastest reported vectorized Cray Y-MP and C90 algorithm shows that the current generation of parallel machines is competitive with conventional vector supercomputers even for small problems. For large problems, the spatial algorithm achieves parallel efficiencies of 90% and a 1840-node Intel Paragon performs up to 165 faster than a single Cray C9O processor. Trade-offs between the three algorithms and guidelines for adapting them to more complex molecular dynamics simulations are also discussed.

Heterogeneous photocatalyst materials for water splitting

Abstract: This critical review shows the basis of photocatalytic water splitting and experimental points, and surveys heterogeneous photocatalyst materials for water splitting into H2 and O2, and H2 or O2 evolution from an aqueous solution containing a sacrificial reagent Many oxides consisting of metal cations with d0 and d10 configurations, metal (oxy)sulfide and metal (oxy)nitride photocatalysts have been reported, especially during the latest decade The fruitful photocatalyst library gives important information on factors affecting photocatalytic performances and design of new materials Photocatalytic water splitting and H2 evolution using abundant compounds as electron donors are expected to contribute to construction of a clean and simple system for solar hydrogen production, and a solution of global energy and environmental issues in the future (361 references)

Semiconductor-based Photocatalytic Hydrogen Generation

Abstract: 2.3. Evaluation of Photocatalytic Water Splitting 6507 2.3.1. Photocatalytic Activity 6507 2.3.2. Photocatalytic Stability 6507 3. UV-Active Photocatalysts for Water Splitting 6507 3.1. d0 Metal Oxide Photocatalyts 6507 3.1.1. Ti-, Zr-Based Oxides 6507 3.1.2. Nb-, Ta-Based Oxides 6514 3.1.3. W-, Mo-Based Oxides 6517 3.1.4. Other d0 Metal Oxides 6518 3.2. d10 Metal Oxide Photocatalyts 6518 3.3. f0 Metal Oxide Photocatalysts 6518 3.4. Nonoxide Photocatalysts 6518 4. Approaches to Modifying the Electronic Band Structure for Visible-Light Harvesting 6519