The development of optical gain in chemically synthesized semiconductor nanoparticles (nanocrystal quantum dots) has been intensely studied as the first step toward nanocrystal quantum dot lasers. We examined the competing dynamical processes involved in optical amplification and lasing in nanocrystal quantum dots and found that, despite a highly efficient intrinsic nonradiative Auger recombination, large optical gain can be developed at the wavelength of the emitting transition for close-packed solids of these dots. Narrowband stimulated emission with a pronounced gain threshold at wavelengths tunable with the size of the nanocrystal was observed, as expected from quantum confinement effects. These results unambiguously demonstrate the feasibility of nanocrystal quantum dot lasers.

http://science.sciencemag.org/content/sci/290/5490/314.full.pdf

Optical gain and stimulated emission in nanocrystal quantum dots.

Optical gain and stimulated emission in nanocrystal quantum dots

The fabrication methods of the microelectronics industry have been refined to produce ever smaller devices, but will soon reach their fundamental limits. A promising alternative route to even smaller functional systems with nanometre dimensions is the autonomous ordering and assembly of atoms and molecules on atomically well-defined surfaces. This approach combines ease of fabrication with exquisite control over the shape, composition and mesoscale organization of the surface structures formed. Once the mechanisms controlling the self-ordering phenomena are fully understood, the self-assembly and growth processes can be steered to create a wide range of surface nanostructures from metallic, semiconducting and molecular materials.

/pdf/engineering-atomic-and-molecular-nanostructures-at-surfaces-2sqr7sjd15.pdf

Engineering atomic and molecular nanostructures at surfaces

http://antonirogalski.com/wp-content/uploads/2011/12/Infrared-detectors-Status-and-trends.pdf

Infrared detectors: status and trends

Gain and threshold current density are analyzed for quantum-box lasers where electrons are confined in quantum well three-dimensionally, based on the density-matrix theory of semiconductor lasers with relaxation broadening. The electronic dipole moment and its polarization dependence are first analyzed, and it is shown that the gain becomes maximum when the electric field of light is parallel to the longest side of the quantum box. Calculated gain is about 10 times that of bulk crystal for 100 A × 100 A × 100 A GaAs/Ga 0.8 Al 0.2 As quantum box, and 15 times for Ga 0.47 In 0.53 As/InP quantum box with the same size, respectively. The threshold current density are 45 A/cm2and 62 A/cm2for GRINSCH GaAs/(Ga 0.8 Al 0.2 As-Ga 0.4 Al 0.6 As) and Ga 0.47 In 0.53 As/(Ga 0.28 In 0.72 As 0.6 P 0.4 -InP), respectively, where for the GaInAs/ GaInAsP/InP system the intervalence band absorption and nonradiative recombinations have been assumed to be the same as those obtained for bulk crystals experimentally. These results show the possibility of remarkable reduction in the laser threshold by the quantum-box structures.

Gain and the threshold of three-dimensional quantum-box lasers

A new type of semiconductor laser is studied, in which injected carriers in the active region are quantum mechanically confined in two or three dimensions (2D or 3D). Effects of such confinements on the lasing characteristics are analyzed. Most important, the threshold current of such laser is predicted to be far less temperature sensitive than that of conventional lasers, reflecting the reduced dimensionality of electronic state. In the case of 3D‐QW laser, the temperature dependence is virtually eliminated. An experiment on 2D quantum well lasers is performed by placing a conventional laser in a strong magnetic field (30 T) and has demonstrated the predicted increase of T0 value from 144 to 313 °C.

H. Sakaki

Papers

Multidimensional quantum well laser and temperature dependence of its threshold current