scispace - formally typeset
Search or ask a question
Author

Haixiao Huang

Bio: Haixiao Huang is an academic researcher from Zhejiang University. The author has contributed to research in topics: High-resolution transmission electron microscopy. The author has an hindex of 1, co-authored 1 publications receiving 293 citations.

Papers
More filters
Journal ArticleDOI
TL;DR: In this paper, a large-scale and highly pure ultrathin SnO2 nanosheets (NSs) were synthesized, with a minimum thickness in the regime of ca. 2.1 nm.
Abstract: We successfully synthesized large-scale and highly pure ultrathin SnO2 nanosheets (NSs), with a minimum thickness in the regime of ca. 2.1 nm as determined by HRTEM and in good agreement with XRD refinements and AFM height profiles. Through TEM and HRTEM observations on time-dependent samples, we found that the as-prepared SnO2 NSs were assembled by “oriented attachment” of preformed SnO2 nanoparticles (NPs). Systematic trials showed that well-defined ultrathin SnO2 NSs could only be obtained under appropriate reaction time, solvent, additive, precursor concentration, and cooling rate. A certain degree of nonstoichiometry appears inevitable in the well-defined SnO2 NSs sample. However, deviations from the optimal synthetic parameters give rise to severe nonstoichiometry in the products, resulting in the formation of Sn3O4 or SnO. This finding may open new accesses to the fundamental investigations of tin oxides as well as their intertransition processes. Finally, we investigated the lithium-ion storage of...

313 citations


Cited by
More filters
Journal ArticleDOI
TL;DR: The unique advances on ultrathin 2D nanomaterials are introduced, followed by the description of their composition and crystal structures, and the assortments of their synthetic methods are summarized.
Abstract: Since the discovery of mechanically exfoliated graphene in 2004, research on ultrathin two-dimensional (2D) nanomaterials has grown exponentially in the fields of condensed matter physics, material science, chemistry, and nanotechnology. Highlighting their compelling physical, chemical, electronic, and optical properties, as well as their various potential applications, in this Review, we summarize the state-of-art progress on the ultrathin 2D nanomaterials with a particular emphasis on their recent advances. First, we introduce the unique advances on ultrathin 2D nanomaterials, followed by the description of their composition and crystal structures. The assortments of their synthetic methods are then summarized, including insights on their advantages and limitations, alongside some recommendations on suitable characterization techniques. We also discuss in detail the utilization of these ultrathin 2D nanomaterials for wide ranges of potential applications among the electronics/optoelectronics, electrocat...

3,628 citations

Journal ArticleDOI
TL;DR: In this paper, a review of the state-of-the-art work on nanostructures of metal oxides is presented, focusing on the physical and chemical properties of low-dimensional oxide materials.

843 citations

Journal ArticleDOI
10 Jun 2013-Small
TL;DR: The aim of this review is to provide an in-depth and rational understanding such that the electrochemical properties of SnO₂-based anodes can be effectively enhanced by making proper nanostructures with optimized chemical composition.
Abstract: The development of new electrode materials for lithium-ion batteries (LIBs) has always been a focal area of materials science, as the current technology may not be able to meet the high energy demands for electronic devices with better performance. Among all the metal oxides, tin dioxide (SnO₂) is regarded as a promising candidate to serve as the anode material for LIBs due to its high theoretical capacity. Here, a thorough survey is provided of the synthesis of SnO₂-based nanomaterials with various structures and chemical compositions, and their application as negative electrodes for LIBs. It covers SnO₂ with different morphologies ranging from 1D nanorods/nanowires/nanotubes, to 2D nanosheets, to 3D hollow nanostructures. Nanocomposites consisting of SnO₂ and different carbonaceous supports, e.g., amorphous carbon, carbon nanotubes, graphene, are also investigated. The use of Sn-based nanomaterials as the anode material for LIBs will be briefly discussed as well. The aim of this review is to provide an in-depth and rational understanding such that the electrochemical properties of SnO₂-based anodes can be effectively enhanced by making proper nanostructures with optimized chemical composition. By focusing on SnO₂, the hope is that such concepts and strategies can be extended to other potential metal oxides, such as titanium dioxide or iron oxides, thus shedding some light on the future development of high-performance metal-oxide based negative electrodes for LIBs.

703 citations

Journal ArticleDOI
TL;DR: A general route is reported to simple self-assembly of transition metal oxide (TMO) nanostructures on MXene (Ti3 C2 ) nanosheets through van der Waals interactions, making them promising high-power and high-energy anode materials for lithium-ion batteries.
Abstract: Recently, a new class of 2D materials, i.e., transition metal carbides, nitrides, and carbonitrides known as MXenes, is unveiled with more than 20 types reported one after another. Since they are flexible and conductive, MXenes are expected to compete with graphene and other 2D materials in many applications. Here, a general route is reported to simple self-assembly of transition metal oxide (TMO) nanostructures, including TiO2 nanorods and SnO2 nanowires, on MXene (Ti3 C2 ) nanosheets through van der Waals interactions. The MXene nanosheets, acting as the underlying substrate, not only enable reversible electron and ion transport at the interface but also prevent the TMO nanostructures from aggregation during lithiation/delithiation. The TMO nanostructures, in turn, serve as the spacer to prevent the MXene nanosheets from restacking, thus preserving the active areas from being lost. More importantly, they can contribute extraordinary electrochemical properties, offering short lithium diffusion pathways and additional active sites. The resulting TiO2 /MXene and SnO2 /MXene heterostructures exhibit superior high-rate performance, making them promising high-power and high-energy anode materials for lithium-ion batteries.

497 citations