H
Hao Xu
Researcher at Chinese Academy of Sciences
Publications - 13
Citations - 854
Hao Xu is an academic researcher from Chinese Academy of Sciences. The author has contributed to research in topics: Enantioselective synthesis & Cycloaddition. The author has an hindex of 8, co-authored 13 publications receiving 748 citations. Previous affiliations of Hao Xu include Max Planck Society.
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Journal ArticleDOI
Copper-catalyzed highly enantioselective cyclopentannulation of indoles with donor-acceptor cyclopropanes.
TL;DR: A highly diastereo- and enantioselective BOX/Cu(II)-catalyzed C2,C3-cyclopentannulation of indoles with donor-acceptor cyclopropanes with asymmetric formal [3 + 2] cycloaddition of indole products has been developed.
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Asymmetric Annulation of Donor–Acceptor Cyclopropanes with Dienes
TL;DR: An efficient [4 + 3] cycloaddition reaction of D-A cyclopropanes with dienes has been successfully developed, delivering a variety of cycloheptenes and [n,5,0]carbobicycles with excellent stereoselectivity.
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Highly Enantioselective [3+2] Annulation of Cyclic Enol Silyl Ethers with Donor–Acceptor Cyclopropanes: Accessing 3a‐Hydroxy [n.3.0]Carbobicycles
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Highly diastereoselective and enantioselective formal [4 + 3] cycloaddition of donor-acceptor cyclobutanes with nitrones.
TL;DR: The first highly diastereoselective and enantioselectives catalytic formal [4 + 3] cycloaddition of 1,1-cyclobutane diester with nitrone has been developed.
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Highly Diastereoselective Construction of Fused Carbocycles from Cyclopropane-1,1-dicarboxylates and Cyclic Enol Silyl Ethers: Scope, Mechanism, and Origin of Diastereoselectivity
TL;DR: F fused cyclopentane derivatives with multiple contiguous stereocenters can be synthesized with excellent diastereoselectivity through Cu(II)/bisoxazoline-catalyzed intermolecular cycloaddition reactions of cyclopropane-1,1-dicarboxylates and cyclic enol silyl ethers.