Author
Harish C. Barshilia
Other affiliations: Indian Institute of Technology Delhi, Indian Institutes of Technology, City University of New York ...read more
Bio: Harish C. Barshilia is an academic researcher from National Aerospace Laboratories. The author has contributed to research in topics: Coating & Sputter deposition. The author has an hindex of 46, co-authored 236 publications receiving 6825 citations. Previous affiliations of Harish C. Barshilia include Indian Institute of Technology Delhi & Indian Institutes of Technology.
Papers published on a yearly basis
Papers
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TL;DR: In this paper, the state-of-the-art physical vapor deposited solar selective coatings used for solar thermal applications with an emphasis on sputter deposited coatings for high-temperature applications.
543 citations
TL;DR: In this article, the structural and mechanical properties of CrN and CrAlN coatings were characterized using X-ray diffraction (XRD) and nanoindentation techniques, respectively.
Abstract: Approximately 1.5 μm thick CrN and CrAlN coatings were deposited on silicon and mild steel substrates by reactive direct current (DC) magnetron sputtering. The structural and mechanical properties of the coatings were characterized using X-ray diffraction (XRD) and nanoindentation techniques, respectively. The bonding structure of the coatings was characterized by X-ray photoelectron spectroscopy (XPS). The surface morphology of the coatings was studied using scanning electron microscopy (SEM) and atomic force microscopy (AFM). The XRD data showed that the CrN and CrAlN coatings exhibited B1 NaCl structure. Nanoindentation measurements showed that as-deposited CrN and CrAlN coatings exhibited a hardness of 18 and 33 GPa, respectively. Results of the surface analysis of the as-deposited coatings using SEM and AFM showed a more compact and dense microstructure for CrAlN coatings. The thermal stability of the coatings was studied by heating the coatings in air from 400 to 900 °C. The structural changes as a result of heating were studied using micro-Raman spectroscopy. The Raman data revealed that CrN coatings got oxidized at 600 °C, whereas in the case of CrAlN coatings, no detectable oxides were formed even at 800 °C. After annealing up to 700 °C, the CrN coatings displayed a hardness of only about 7.5 GPa as compared to CrAlN coatings, which exhibited hardness as high as 22.5 GPa. The potentiodynamic polarization measurements in 3.5% NaCl solution indicated that the CrAlN coatings exhibited superior corrosion resistance as compared to CrN coatings.
277 citations
TL;DR: In this article, nanolayered TiAlN/CrN multilayer films were deposited on silicon substrates from a TiAl target using a reactive DC magnetron sputtering process in Ar+N 2 plasma.
193 citations
TL;DR: In this paper, the authors used x-ray diffraction (XRD) and micro-Raman spectroscopy to characterize the structural properties of nanolayered multilayer coatings.
Abstract: About 1.5-um-thick single-layer TiN, CrN, TiAlN coatings and nanolayered TiN/CrN, TiAlN/CrN multilayer coatings were deposited on silicon (111) substrates using a13; reactive direct current magnetron sputtering process. Structural characterization of the coatings was done using x-ray diffraction (XRD) and micro-Raman spectroscopy. All13; the coatings exhibited NaCl B1 structure in the XRD data. Raman spectroscopy data of as-deposited coatings exhibited two broad bands centered at 230x2013;250 and 540x2013;630 cmx2212;1.13; These bands have been assigned to acoustical and optical phonon modes, respectively. Thermal stability of the coatings was studied by heating the coatings in air in a13; resistive furnace for 30 min in the temperature range 400x2013;900 xB0;C. Structural changes as a result of heating were characterized using Raman spectroscopy and XRD. Raman13; data showed that TiN, CrN, TiN/CrN, TiAlN, and TiAlN/CrN coatings started to oxidize at 500, 600, 750, 800, and 900 xB0;C, respectively. To isolate the oxidation-induced spectral changes as a result of heating of the coatings in air, samples were also annealed in vacuum at 800 xB0;C under similar conditions. The Raman data of vacuum-annealed coatings showed no phase transformation, and intensity of the optical phonon mode increased and shifted to lower frequencies. The origin of these spectral changes is discussed in terms of defect structure of the coatings. Our results indicate that the thermal stability of nanolayered multilayer coatings is superior to the13; single-layer coatings.
186 citations
TL;DR: In this article, the corrosion behavior of single layer TiN, CrN, TiAlN and multilayer TiN/CrN coatings was studied in 3.5% NaCl solution by potentiodynamic polarization and electrochemical impedance spectroscopy (EIS).
160 citations
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Donostia International Physics Center1, Rovira i Virgili University2, MacDiarmid Institute for Advanced Materials and Nanotechnology3, Victoria University of Wellington4, University of Cambridge5, University of California, Santa Barbara6, Queen's University Belfast7, Technical University of Denmark8, University of Victoria9, Chung-Ang University10, University of Jena11, Leibniz Institute of Photonic Technology12, Rutgers University13, University of Strathclyde14, University of Liverpool15, University of Iowa16, University of Minnesota17, Heidelberg University18, National Institute of Advanced Industrial Science and Technology19, Chalmers University of Technology20, Humboldt University of Berlin21, University of Michigan22, Jiangnan University23, Stanford University24, Xiamen University25, Ludwig Maximilian University of Munich26, Hokkaido University27, Seoul National University28, University of Illinois at Urbana–Champaign29, Kwansei Gakuin University30, University of Vigo31, Free University of Berlin32, Northwestern University33, University of Duisburg-Essen34, National Research Council35, Indian Institute of Science Education and Research, Thiruvananthapuram36, Duke University37, Northeastern University (China)38, Temple University39, Wuhan University40, Japan Advanced Institute of Science and Technology41, Jilin University42, Ikerbasque43
TL;DR: Prominent authors from all over the world joined efforts to summarize the current state-of-the-art in understanding and using SERS, as well as to propose what can be expected in the near future, in terms of research, applications, and technological development.
Abstract: The discovery of the enhancement of Raman scattering by molecules adsorbed on nanostructured metal surfaces is a landmark in the history of spectroscopic and analytical techniques. Significant experimental and theoretical effort has been directed toward understanding the surface-enhanced Raman scattering (SERS) effect and demonstrating its potential in various types of ultrasensitive sensing applications in a wide variety of fields. In the 45 years since its discovery, SERS has blossomed into a rich area of research and technology, but additional efforts are still needed before it can be routinely used analytically and in commercial products. In this Review, prominent authors from around the world joined together to summarize the state of the art in understanding and using SERS and to predict what can be expected in the near future in terms of research, applications, and technological development. This Review is dedicated to SERS pioneer and our coauthor, the late Prof. Richard Van Duyne, whom we lost during the preparation of this article.
1,768 citations
1,033 citations
TL;DR: A comprehensive review of recent synthetic methods along with associated synthesis mechanisms, characterization, fundamental properties, and promising applications of Cupric oxide (CuO) nanostructures is presented in this article.
1,030 citations
01 Jan 2016
TL;DR: The introduction to electrodynamics is universally compatible with any devices to read and is available in the book collection an online access to it is set as public so you can get it instantly.
Abstract: Thank you for downloading introduction to electrodynamics. Maybe you have knowledge that, people have look numerous times for their chosen books like this introduction to electrodynamics, but end up in infectious downloads. Rather than enjoying a good book with a cup of tea in the afternoon, instead they juggled with some malicious bugs inside their computer. introduction to electrodynamics is available in our book collection an online access to it is set as public so you can get it instantly. Our book servers spans in multiple countries, allowing you to get the most less latency time to download any of our books like this one. Merely said, the introduction to electrodynamics is universally compatible with any devices to read.
1,025 citations