We report measurements of the mass density, Omega_M, and
cosmological-constant energy density, Omega_Lambda, of the universe based on
the analysis of 42 Type Ia supernovae discovered by the Supernova Cosmology
Project. The magnitude-redshift data for these SNe, at redshifts between 0.18
and 0.83, are fit jointly with a set of SNe from the Calan/Tololo Supernova
Survey, at redshifts below 0.1, to yield values for the cosmological
parameters. All SN peak magnitudes are standardized using a SN Ia lightcurve
width-luminosity relation. The measurement yields a joint probability
distribution of the cosmological parameters that is approximated by the
relation 0.8 Omega_M - 0.6 Omega_Lambda ~= -0.2 +/- 0.1 in the region of
interest (Omega_M <~ 1.5). For a flat (Omega_M + Omega_Lambda = 1) cosmology we
find Omega_M = 0.28{+0.09,-0.08} (1 sigma statistical) {+0.05,-0.04}
(identified systematics). The data are strongly inconsistent with a Lambda = 0
flat cosmology, the simplest inflationary universe model. An open, Lambda = 0
cosmology also does not fit the data well: the data indicate that the
cosmological constant is non-zero and positive, with a confidence of P(Lambda >
0) = 99%, including the identified systematic uncertainties. The best-fit age
of the universe relative to the Hubble time is t_0 = 14.9{+1.4,-1.1} (0.63/h)
Gyr for a flat cosmology. The size of our sample allows us to perform a variety
of statistical tests to check for possible systematic errors and biases. We
find no significant differences in either the host reddening distribution or
Malmquist bias between the low-redshift Calan/Tololo sample and our
high-redshift sample. The conclusions are robust whether or not a
width-luminosity relation is used to standardize the SN peak magnitudes.

/pdf/measurements-of-omega-and-lambda-from-42-high-redshift-z1htxv5kgf.pdf

Measurements of Omega and Lambda from 42 High-Redshift Supernovae

We present spectral and photometric observations of 10 Type Ia supernovae (SNe Ia) in the redshift range 0.16 " z " 0.62. The luminosity distances of these objects are determined by methods that employ relations between SN Ia luminosity and light curve shape. Combined with previous data from our High-z Supernova Search Team and recent results by Riess et al., this expanded set of 16 high-redshift supernovae and a set of 34 nearby supernovae are used to place constraints on the following cosmo- logical parameters: the Hubble constant the mass density the cosmological constant (i.e., the (H 0 ), () M ), vacuum energy density, the deceleration parameter and the dynamical age of the universe ) " ), (q 0 ), ) M \ 1) methods. We estimate the dynamical age of the universe to be 14.2 ^ 1.7 Gyr including systematic uncer- tainties in the current Cepheid distance scale. We estimate the likely e†ect of several sources of system- atic error, including progenitor and metallicity evolution, extinction, sample selection bias, local perturbations in the expansion rate, gravitational lensing, and sample contamination. Presently, none of these e†ects appear to reconcile the data with and ) " \ 0 q 0 " 0.

/pdf/observational-evidence-from-supernovae-for-an-accelerating-2hxji77uix.pdf

Observational Evidence from Supernovae for an Accelerating Universe and a Cosmological Constant

We present spectral and photometric observations of 10 type Ia supernovae (SNe Ia) in the redshift range 0.16 � z � 0.62. The luminosity distances of these objects are determined by methods that employ relations between SN Ia luminosity and light curve shape. Combined with previous data from our High-Z Supernova Search Team (Garnavich et al. 1998; Schmidt et al. 1998) and Riess et al. (1998a), this expanded set of 16 high-redshift supernovae and a set of 34 nearby supernovae are used to place constraints on the following cosmological parameters: the Hubble constant (H0), the mass density (M), the cosmological constant (i.e., the vacuum energy density, �), the deceleration parameter (q0), and the dynamical age of the Universe (t0). The distances of the high-redshift SNe Ia are, on average, 10% to 15% farther than expected in a low mass density (M = 0.2) Universe without a cosmological constant. Different light curve fitting methods, SN Ia subsamples, and prior constraints unanimously favor eternally expanding models with positive cosmological constant (i.e., � > 0) and a current acceleration of the expansion (i.e., q0 < 0). With no prior constraint on mass density other than M � 0, the spectroscopically confirmed SNe Ia are statistically consistent with q0 < 0 at the 2.8�

Observational Evidence from Supernovae for an Accelerating Universe and a Cosmological Constant To Appear in the Astronomical Journal

Pretreatment technologies for an efficient bioethanol production process based on enzymatic hydrolysis: A review

Biofuels produced from various lignocellulosic materials, such as wood, agricultural, or forest residues, have the potential to be a valuable substitute for, or complement to, gasoline. Many physicochemical structural and compositional factors hinder the hydrolysis of cellulose present in biomass to sugars and other organic compounds that can later be converted to fuels. The goal of pretreatment is to make the cellulose accessible to hydrolysis for conversion to fuels. Various pretreatment techniques change the physical and chemical structure of the lignocellulosic biomass and improve hydrolysis rates. During the past few years a large number of pretreatment methods have been developed, including alkali treatment, ammonia explosion, and others. Many methods have been shown to result in high sugar yields, above 90% of the theoretical yield for lignocellulosic biomasses such as woods, grasses, corn, and so on. In this review, we discuss the various pretreatment process methods and the recent literature that...

http://ucce.ucdavis.edu/files/datastore/234-1388.pdf

Methods for Pretreatment of Lignocellulosic Biomass for Efficient Hydrolysis and Biofuel Production

The economic dependency on fossil fuels and the resulting effects on climate and environment have put tremendous focus on utilizing fermentable sugars from lignocellulose, the largest known renewable carbohydrate source. The fermentable sugars in lignocellulose are derived from cellulose and hemicelluloses but these are not readily accessible to enzymatic hydrolysis and require a pretreatment, which causes an extensive modification of the lignocellulosic structure. A number of pretreatment technologies are under development and being tested in pilot scale. Hydrolysis of lignocellulose carbohydrates into fermentable sugars requires a number of different cellulases and hemicellulases. The hydrolysis of cellulose is a sequential breakdown of the linear glucose chains, whereas hemicellulases must be capable of hydrolysing branched chains containing different sugars and functional groups. The technology for pretreatment and hydrolysis has been developed to an extent that is close to a commercially viable level. It has become possible to process lignocellulose at high substrate levels and the enzyme performance has been improved. Also the cost of enzymes has been reduced. Still a number of technical and scientific issues within pretreatment and hydrolysis remain to be solved. However, significant improvements in yield and cost reductions are expected, thus making large-scale fermentation of lignocellulosic substrates possible. © 2007 Society of Chemical Industry and John Wiley & Sons, Ltd

Enzymatic conversion of lignocellulose into fermentable sugars: challenges and opportunities.

Working at high solids (substrate) concentrations is advantageous in enzymatic conversion of lignocellulosic biomass as it increases product concentrations and plant productivity while lowering energy and water input. However, for a number of lignocellulosic substrates it has been shown that at increasing substrate concentration, the corresponding yield decreases in a fashion which can not be explained by current models and knowledge of enzyme-substrate interactions. This decrease in yield is undesirable as it offsets the advantages of working at high solids levels. The cause of the 'solids effect' has so far remained unknown. The decreasing conversion at increasing solids concentrations was found to be a generic or intrinsic effect, describing a linear correlation from 5 to 30% initial total solids content (w/w). Insufficient mixing has previously been shown not to be involved in the effect. Hydrolysis experiments with filter paper showed that neither lignin content nor hemicellulose-derived inhibitors appear to be responsible for the decrease in yields. Product inhibition by glucose and in particular cellobiose (and ethanol in simultaneous saccharification and fermentation) at the increased concentrations at high solids loading plays a role but could not completely account for the decreasing conversion. Adsorption of cellulases was found to decrease at increasing solids concentrations. There was a strong correlation between the decreasing adsorption and conversion, indicating that the inhibition of cellulase adsorption to cellulose is causing the decrease in yield. Inhibition of enzyme adsorption by hydrolysis products appear to be the main cause of the decreasing yields at increasing substrate concentrations in the enzymatic decomposition of cellulosic biomass. In order to facilitate high conversions at high solids concentrations, understanding of the mechanisms involved in high-solids product inhibition and adsorption inhibition must be improved.

/pdf/yield-determining-factors-in-high-solids-enzymatic-1n6ma4j98q.pdf

Yield-determining factors in high-solids enzymatic hydrolysis of lignocellulose

To improve process economics of the lignocellulose to ethanol process a reactor system for enzymatic liquefaction and saccharification at high-solids concentrations was developed. The technology is based on free fall mixing employing a horizontally placed drum with a horizontal rotating shaft mounted with paddlers for mixing. Enzymatic liquefaction and saccharification of pretreated wheat straw was tested with up to 40% (w/w) initial DM. In less than 10 h, the structure of the material was changed from intact straw particles (length 1-5 cm) into a paste/liquid that could be pumped. Tests revealed no significant effect of mixing speed in the range 3.3-11.5 rpm on the glucose conversion after 24 h and ethanol yield after subsequent fermentation for 48 h. Low-power inputs for mixing are therefore possible. Liquefaction and saccharification for 96 h using an enzyme loading of 7 FPU/g.DM and 40% DM resulted in a glucose concentration of 86 g/kg. Experiments conducted at 2%-40% (w/w) initial DM revealed that cellulose and hemicellulose conversion decreased almost linearly with increasing DM. Performing the experiments as simultaneous saccharification and fermentation also revealed a decrease in ethanol yield at increasing initial DM. Saccharomyces cerevisiae was capable of fermenting hydrolysates up to 40% DM. The highest ethanol concentration, 48 g/kg, was obtained using 35% (w/w) DM. Liquefaction of biomass with this reactor system unlocks the possibility of 10% (w/w) ethanol in the fermentation broth in future lignocellulose to ethanol plants.

https://www.onlinelibrary.wiley.com/doi/pdf/10.1002/bit.21115

Liquefaction of Lignocellulose at High-Solids Concentrations

Background
Pretreatment is an essential step in the enzymatic hydrolysis of biomass and subsequent production of bioethanol. Recent results indicate that only a mild pretreatment is necessary in an industrial, economically feasible system. The Integrated Biomass Utilisation System hydrothermal pretreatment process has previously been shown to be effective in preparing wheat straw for these processes without the application of additional chemicals. In the current work, the effect of the pretreatment on the straw cell-wall matrix and its components are characterised microscopically (atomic force microscopy and scanning electron microscopy) and spectroscopically (attenuated total reflectance Fourier transform infrared spectroscopy) in order to understand this increase in digestibility.

/pdf/cell-wall-structural-changes-in-wheat-straw-pretreated-for-36loedrquw.pdf

Henning Jørgensen

Papers

Enzymatic conversion of lignocellulose into fermentable sugars: challenges and opportunities.

Yield-determining factors in high-solids enzymatic hydrolysis of lignocellulose

Liquefaction of Lignocellulose at High-Solids Concentrations

Cell-wall structural changes in wheat straw pretreated for bioethanol production.

Use of surface active additives in enzymatic hydrolysis of wheat straw lignocellulose