H
Hiroyuki Terai
Researcher at Osaka University
Publications - 8
Citations - 946
Hiroyuki Terai is an academic researcher from Osaka University. The author has contributed to research in topics: Cyanation & Ruthenium. The author has an hindex of 4, co-authored 7 publications receiving 899 citations. Previous affiliations of Hiroyuki Terai include Okayama University of Science.
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Aerobic Ruthenium-Catalyzed Oxidative Cyanation of Tertiary Amines with Sodium Cyanide
TL;DR: RuCl3-catalyzed oxidative cyanation of tertiary amines with sodium cyanide under molecular oxygen (1 atm) at 60 degrees C gives the corresponding alpha-aminonitriles, which are versatile synthetic intermediates of various compounds such as amino acids and unsymmetrical 1,2-diamines in excellent yields.
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Ruthenium-catalyzed oxidative cyanation of tertiary amines with molecular oxygen or hydrogen peroxide and sodium cyanide: sp3 C-H bond activation and carbon-carbon bond formation.
TL;DR: A new type of ruthenium-catalyzed oxidative cyanation of tertiary amines with H2O2 to give alpha-aminonitriles was established, which can be readily converted to alpha-amino acids, diamines, and various nitrogen-containing heterocyclic compounds.
Journal ArticleDOI
Ruthenium-catalyzed oxidative cyanation of tertiary amines with hydrogen peroxide and sodium cyanide.
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Ruthenium‐Catalyzed Oxidative Cyanation of Tertiary Amines with Molecular Oxygen or Hydrogen Peroxide and Sodium Cyanide: sp3 C—H Bond Activation and Carbon—Carbon Bond Formation.
TL;DR: In this paper, a ruthenium-catalyzed oxidative cyanation of tertiary amines with molecular oxygen in the presence of sodium cyanide and acetic acid gives the corresponding α-aminonitriles, which are highly useful intermediates for organic synthesis.