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Showing papers by "Hyun-Chul Kim published in 2016"


Journal ArticleDOI
Georges Aad1, Brad Abbott2, Jalal Abdallah3, Ovsat Abdinov4  +2828 moreInstitutions (191)
TL;DR: In this article, the performance of the ATLAS muon identification and reconstruction using the first LHC dataset recorded at s√ = 13 TeV in 2015 was evaluated using the Monte Carlo simulations.
Abstract: This article documents the performance of the ATLAS muon identification and reconstruction using the first LHC dataset recorded at s√ = 13 TeV in 2015. Using a large sample of J/ψ→μμ and Z→μμ decays from 3.2 fb−1 of pp collision data, measurements of the reconstruction efficiency, as well as of the momentum scale and resolution, are presented and compared to Monte Carlo simulations. The reconstruction efficiency is measured to be close to 99% over most of the covered phase space (|η| 2.2, the pT resolution for muons from Z→μμ decays is 2.9% while the precision of the momentum scale for low-pT muons from J/ψ→μμ decays is about 0.2%.

440 citations


Journal ArticleDOI
Georges Aad1, Brad Abbott2, Jalal Abdallah3, Ovsat Abdinov4  +2812 moreInstitutions (207)
TL;DR: In this paper, an independent b-tagging algorithm based on the reconstruction of muons inside jets as well as the b tagging algorithm used in the online trigger are also presented.
Abstract: The identification of jets containing b hadrons is important for the physics programme of the ATLAS experiment at the Large Hadron Collider. Several algorithms to identify jets containing b hadrons are described, ranging from those based on the reconstruction of an inclusive secondary vertex or the presence of tracks with large impact parameters to combined tagging algorithms making use of multi-variate discriminants. An independent b-tagging algorithm based on the reconstruction of muons inside jets as well as the b-tagging algorithm used in the online trigger are also presented. The b-jet tagging efficiency, the c-jet tagging efficiency and the mistag rate for light flavour jets in data have been measured with a number of complementary methods. The calibration results are presented as scale factors defined as the ratio of the efficiency (or mistag rate) in data to that in simulation. In the case of b jets, where more than one calibration method exists, the results from the various analyses have been combined taking into account the statistical correlation as well as the correlation of the sources of systematic uncertainty.

362 citations


Journal ArticleDOI
Georges Aad1, Brad Abbott2, Jalal Abdallah3, Ovsat Abdinov4  +2862 moreInstitutions (191)
TL;DR: The methods employed in the ATLAS experiment to correct for the impact of pile-up on jet energy and jet shapes, and for the presence of spurious additional jets, are described, with a primary focus on the large 20.3 kg-1 data sample.
Abstract: The large rate of multiple simultaneous protonproton interactions, or pile-up, generated by the Large Hadron Collider in Run 1 required the development of many new techniques to mitigate the advers ...

316 citations


Journal ArticleDOI
Morad Aaboud, Alexander Kupco1, P. Davison2, Samuel Webb3  +2869 moreInstitutions (194)
TL;DR: The luminosity determination for the ATLAS detector at the LHC during pp collisions at s√= 8 TeV in 2012 is presented in this article, where the evaluation of the luminosity scale is performed using several luminometers.
Abstract: The luminosity determination for the ATLAS detector at the LHC during pp collisions at s√= 8 TeV in 2012 is presented. The evaluation of the luminosity scale is performed using several luminometers ...

286 citations


Journal ArticleDOI
TL;DR: FUS sonication of the primary visual cortex in humans is reported, resulting in elicited activation not only from the sonicated brain area, but also from the network of regions involved in visual and higher-order cognitive processes.
Abstract: Transcranial focused ultrasound (FUS) is making progress as a new non-invasive mode of regional brain stimulation. Current evidence of FUS-mediated neurostimulation for humans has been limited to the observation of subjective sensory manifestations and electrophysiological responses, thus warranting the identification of stimulated brain regions. Here, we report FUS sonication of the primary visual cortex (V1) in humans, resulting in elicited activation not only from the sonicated brain area, but also from the network of regions involved in visual and higher-order cognitive processes (as revealed by simultaneous acquisition of blood-oxygenation-level-dependent functional magnetic resonance imaging). Accompanying phosphene perception was also reported. The electroencephalo graphic (EEG) responses showed distinct peaks associated with the stimulation. None of the participants showed any adverse effects from the sonication based on neuroimaging and neurological examinations. Retrospective numerical simulation of the acoustic profile showed the presence of individual variability in terms of the location and intensity of the acoustic focus. With exquisite spatial selectivity and capability for depth penetration, FUS may confer a unique utility in providing non-invasive stimulation of region-specific brain circuits for neuroscientific and therapeutic applications.

285 citations


Journal ArticleDOI
Georges Aad1, Brad Abbott2, Jalal Abdallah3, Ovsat Abdinov4  +2851 moreInstitutions (208)
TL;DR: The results suggest that the ridge in pp collisions arises from the same or similar underlying physics as observed in p+Pb collisions, and that the dynamics responsible for the ridge has no strong sqrt[s] dependence.
Abstract: ATLAS has measured two-particle correlations as a function of relative azimuthal-angle, $\Delta \phi$, and pseudorapidity, $\Delta \eta$, in $\sqrt{s}$=13 and 2.76 TeV $pp$ collisions at the LHC using charged particles measured in the pseudorapidity interval $|\eta|$<2.5. The correlation functions evaluated in different intervals of measured charged-particle multiplicity show a multiplicity-dependent enhancement at $\Delta \phi \sim 0$ that extends over a wide range of $\Delta\eta$, which has been referred to as the "ridge". Per-trigger-particle yields, $Y(\Delta \phi)$, are measured over 2<$|\Delta\eta|$<5. For both collision energies, the $Y(\Delta \phi)$ distribution in all multiplicity intervals is found to be consistent with a linear combination of the per-trigger-particle yields measured in collisions with less than 20 reconstructed tracks, and a constant combinatoric contribution modulated by $\cos{(2\Delta \phi)}$. The fitted Fourier coefficient, $v_{2,2}$, exhibits factorization, suggesting that the ridge results from per-event $\cos{(2\phi)}$ modulation of the single-particle distribution with Fourier coefficients $v_2$. The $v_2$ values are presented as a function of multiplicity and transverse momentum. They are found to be approximately constant as a function of multiplicity and to have a $p_{\mathrm{T}}$ dependence similar to that measured in $p$+Pb and Pb+Pb collisions. The $v_2$ values in the 13 and 2.76 TeV data are consistent within uncertainties. These results suggest that the ridge in $pp$ collisions arises from the same or similar underlying physics as observed in $p$+Pb collisions, and that the dynamics responsible for the ridge has no strong $\sqrt{s}$ dependence.

246 citations


Journal ArticleDOI
Georges Aad1, Brad Abbott2, Jalal Abdallah3, Ovsat Abdinov4  +2838 moreInstitutions (148)
TL;DR: In this article, a search for a high-mass Higgs boson in the,,, and decay modes using the ATLAS detector at the CERN Large Hadron Collider is presented.
Abstract: A search is presented for a high-mass Higgs boson in the , , , and decay modes using the ATLAS detector at the CERN Large Hadron Collider. The search uses proton-proton collision data at a centre-of-mass energy of 8 TeV corresponding to an integrated luminosity of 20.3 fb. The results of the search are interpreted in the scenario of a heavy Higgs boson with a width that is small compared with the experimental mass resolution. The Higgs boson mass range considered extends up to for all four decay modes and down to as low as 140 , depending on the decay mode. No significant excess of events over the Standard Model prediction is found. A simultaneous fit to the four decay modes yields upper limits on the production cross-section of a heavy Higgs boson times the branching ratio to boson pairs. 95 % confidence level upper limits range from 0.53 pb at GeV to 0.008 pb at GeV for the gluon-fusion production mode and from 0.31 pb at GeV to 0.009 pb at GeV for the vector-boson-fusion production mode. The results are also interpreted in the context of Type-I and Type-II two-Higgs-doublet models.

241 citations


Journal ArticleDOI
Jaroslav Adam1, Dagmar Adamová2, Madan M. Aggarwal3, G. Aglieri Rinella4  +976 moreInstitutions (100)
TL;DR: In this article, direct photon spectra down to pT≈1 GeV/c were extracted for the 20−40% and 0−20% centrality classes, respectively.

210 citations


Journal ArticleDOI
Morad Aaboud, Alexander Kupco1, Peter Davison1, Samuel Webb1  +2900 moreInstitutions (67)
TL;DR: In this article, a search for new phenomena in final states with an energetic jet and large missing transverse momentum was performed using proton-proton collision data corresponding to an inte...
Abstract: Results of a search for new phenomena in final states with an energetic jet and large missing transverse momentum are reported. The search uses proton-proton collision data corresponding to an inte ...

203 citations


Journal ArticleDOI
Morad Aaboud, Georges Aad1, Brad Abbott2, Jalal Abdallah3  +2898 moreInstitutions (216)
TL;DR: In this paper, a measurement of the inelastic proton-proton cross section using 60''μb^{-1} of pp collisions at a center-of-mass energy sqrt[s] of 13'TeV with the ATLAS detector at the LHC is presented.
Abstract: This Letter presents a measurement of the inelastic proton-proton cross section using 60 μb^{-1} of pp collisions at a center-of-mass energy sqrt[s] of 13 TeV with the ATLAS detector at the LHC. Inelastic interactions are selected using rings of plastic scintillators in the forward region (2.07 10^{-6}, where M_{X} is the larger invariant mass of the two hadronic systems separated by the largest rapidity gap in the event. In this ξ range the scintillators are highly efficient. For diffractive events this corresponds to cases where at least one proton dissociates to a system with M_{X}>13 GeV. The measured cross section is compared with a range of theoretical predictions. When extrapolated to the full phase space, a cross section of 78.1±2.9 mb is measured, consistent with the inelastic cross section increasing with center-of-mass energy.

191 citations


Journal ArticleDOI
Georges Aad1, Brad Abbott2, Jalal Abdallah3, Ovsat Abdinov4  +2814 moreInstitutions (212)
TL;DR: In this article, the authors describe a model-agnostic search for pairs of jets (dijets) produced by resonant and non-resonant phenomena beyond the Standard Model.

Journal ArticleDOI
Georges Aad1, Brad Abbott2, Jalal Abdallah3, Ovsat Abdinov4  +2858 moreInstitutions (191)
TL;DR: In this article, the authors measured the transverse momentum and the related angular variable of DrellΓCoYan lepton pairs with the ATLAS detector at the LHC and compared their results to predictions from perturbative and resummed QCD calculations.
Abstract: Distributions of transverse momentum [Formula: see text] and the related angular variable [Formula: see text] of DrellΓCoYan lepton pairs are measured in 20.3┬afb[Formula: see text] of protonΓCoproton collisions at [Formula: see text]┬aTeV with the ATLAS detector at the LHC. Measurements in electron-pair and muon-pair final states are corrected for detector effects and combined. Compared to previous measurements in protonΓCoproton collisions at [Formula: see text]┬aTeV, these new measurements benefit from a larger data sample and improved control of systematic uncertainties. Measurements are performed in bins of lepton-pair mass above, around and below the Z-boson mass peak. The data are compared to predictions from perturbative and resummed QCD calculations. For values of [Formula: see text] the predictions from the Monte Carlo generator ResBos are generally consistent with the data within the theoretical uncertainties. However, at larger values of [Formula: see text] this is not the case. Monte Carlo generators based on the parton-shower approach are unable to describe the data over the full range of [Formula: see text] while the fixed-order prediction of Dynnlo falls below the data at high values of [Formula: see text]. ResBos and the parton-shower Monte Carlo generators provide a much better description of the evolution of the [Formula: see text] and [Formula: see text] distributions as a function of lepton-pair mass and rapidity than the basic shape of the data.

Journal ArticleDOI
Georges Aad1, Brad Abbott2, Jalal Abdallah3, Ovsat Abdinov4  +2844 moreInstitutions (190)
TL;DR: In this article, a search for strongly produced supersymmetric particles is conducted using signatures involving multiple energetic jets and either two isolated leptons (e or μ) with the same electric charge or at the same location.
Abstract: A search for strongly produced supersymmetric particles is conducted using signatures involving multiple energetic jets and either two isolated leptons (e or μ) with the same electric charge or at ...

Journal ArticleDOI
Jaroslav Adam1, Dagmar Adamová2, Madan M. Aggarwal3, G. Aglieri Rinella4  +1020 moreInstitutions (95)
TL;DR: In this article, the ALICE experiment was used to measure the production rate of hadron species in high multiplicity p-Pb collisions at a center-of-mass energy of 5.02 TeV.

Journal ArticleDOI
Morad Aaboud, Georges Aad1, Brad Abbott2, Jalal Abdallah3  +2907 moreInstitutions (217)
TL;DR: Searches for new resonances decaying into two photons in the ATLAS experiment at the CERN Large Hadron Collider are described in this article, based on protonproton collision data corresponding to two photons.
Abstract: Searches for new resonances decaying into two photons in the ATLAS experiment at the CERN Large Hadron Collider are described. The analysis is based on protonproton collision data corresponding to ...

Journal ArticleDOI
Jaroslav Adam1, Dagmar Adamová2, Madan M. Aggarwal3, G. Aglieri Rinella4  +1008 moreInstitutions (100)
TL;DR: The production of the hypertriton nuclei H Λ 3 and H ‾ Λ ¯ 3 has been measured for the first time in Pb-Pb collisions at s NN = 2.76 ÂTeV with the ALICE experiment at LHC.

Journal ArticleDOI
Khachatryan1, Albert M. Sirunyan1, Armen Tumasyan1, Wolfgang Adam2  +2255 moreInstitutions (183)
TL;DR: In this paper, the results on two-particle angular correlations for charged particles produced in pp collisions at a center-of-mass energy of 13 TeV were presented, and the data were taken with the CMS detector at the LHC.
Abstract: Results on two-particle angular correlations for charged particles produced in pp collisions at a center-of-mass energy of 13 TeV are presented. The data were taken with the CMS detector at the LHC and correspond to an integrated luminosity of about 270 nb^(−1). The correlations are studied over a broad range of pseudorapidity (|η| 2.0), near-side (Δϕ≈0) structure emerges in the two-particle Δη–Δϕ correlation functions. The magnitude of the correlation exhibits a pronounced maximum in the range 1.0

Journal ArticleDOI
Morad Aaboud, Alexander Kupco1, Peter Davison2, Samuel Webb3  +2914 moreInstitutions (219)
TL;DR: In this article, an inclusive search for a new-physics signature of lepton-jet resonances has been performed by the ATLAS experiment, where first and second generation leptoquarks were sought in events with two electrons (muons) and two or more jets.
Abstract: An inclusive search for a new-physics signature of lepton-jet resonances has been performed by the ATLAS experiment. Scalar leptoquarks, pair-produced in pp collisions at √s = 13 TeV at the large hadron collider, have been considered. An integrated luminosity of 3.2 fb−1, corresponding to the full 2015 dataset was used. First (second) generation leptoquarks were sought in events with two electrons (muons) and two or more jets. The observed event yield in each channel is consistent with Standard Model background expectations. The observed (expected) lower limits on the leptoquark mass at 95% confidence level are 1100 and 1050 GeV (1160 and 1040 GeV) for first and second generation leptoquarks, respectively, assuming a branching ratio into a charged lepton and a quark of 100%. Upper limits on the aforementioned branching ratio are also given as a function of leptoquark mass. Compared with the results of earlier ATLAS searches, the sensitivity is increased for leptoquark masses above 860 GeV, and the observed exclusion limits confirm and extend the published results.

Journal ArticleDOI
Vardan Khachatryan1, Albert M. Sirunyan1, Armen Tumasyan1, Wolfgang Adam2  +2287 moreInstitutions (178)
TL;DR: In this article, the angular distribution and the differential branching fraction of the decay B0 to K*0(892) mu mu are studied using data corresponding to an integrated luminosity of 20.5 inverse femtobarns collected with the CMS detector at the LHC in pp collisions at sqrt(s) = 8 TeV.

Journal ArticleDOI
Georges Aad1, Brad Abbott1, Jalal Abdallah1, Ovsat Abdinov2  +2829 moreInstitutions (39)
TL;DR: In this paper, measurements of the W-+/- = e(+/-) v and Z = l(+)l(-) production cross sections in proton-proton collisions at root s = 13 TeV are presented.

Journal ArticleDOI
Georges Aad1, Brad Abbott2, Jalal Abdallah3, Ovsat Abdinov4  +2904 moreInstitutions (211)
TL;DR: In this paper, a search for a Higgs boson produced via vector-boson fusion and decaying into invisible particles is presented, using 20.3 fb−1 of proton-proton collision data at a centre-of-mass energy of 8 TeV recorded by the ATLAS detector at the LHC.
Abstract: A search for a Higgs boson produced via vector-boson fusion and decaying into invisible particles is presented, using 20.3 fb−1 of proton-proton collision data at a centre-of-mass energy of 8 TeV recorded by the ATLAS detector at the LHC. For a Higgs boson with a mass of 125 GeV, assuming the Standard Model production cross section, an upper bound of 0.28 is set on the branching fraction of H → invisible at 95% confidence level, where the expected upper limit is 0.31. The results are interpreted in models of Higgs-portal dark matter where the branching fraction limit is converted into upper bounds on the dark-matter-nucleon scattering cross section as a function of the dark-matter particle mass, and compared to results from the direct dark-matter detection experiments.

Journal ArticleDOI
Georges Aad1, Brad Abbott2, Jalal Abdallah3, Ovsat Abdinov4  +2898 moreInstitutions (215)
TL;DR: In this paper, measurements of W(+/-)Z production in pp collisions at a center-of-mass energy of 8 TeV were presented, where the gauge bosons were reconstructed using their leptonic decay modes into electrons and m...
Abstract: This paper presents measurements of W(+/-)Z production in pp collisions at a center-of-mass energy of 8 TeV. The gauge bosons are reconstructed using their leptonic decay modes into electrons and m ...

Journal ArticleDOI
Georges Aad1, Brad Abbott2, Jalal Abdallah3, Ovsat Abdinov4  +2873 moreInstitutions (191)
TL;DR: In this paper, the authors present a survey of NSF projects in the European Union and the United States of America, including the following countries: Austria, Australia, Germany, Austria, Belgium, Canada, Czech Republic, Denmark, Netherlands, Norway, Portugal, Slovenia, Spain, Sweden, Switzerland, Turkey, United Kingdom, United States, Netherlands and Switzerland.
Abstract: ANPCyT, Argentina; YerPhI, Armenia; ARC, Australia; BMWF, Austria; FWF, Austria; ANAS, Azerbaijan; SSTC, Belarus; CNPq, Brazil; FAPESP, Brazil; NSERC, Canada; NRC, Canada; CFI, Canada; CERN; CONICYT, Chile; CAS, China; MOST, China; NSFC, China; COLCIEN-CIAS, Colombia; MSMT CR, Czech Republic; MPO CR, Czech Republic; VSC CR, Czech Republic; DNRF, Denmark; DNSRC, Denmark; Lundbeck Foundation, Denmark; EPLANET; ERC; NSRF; European Union; IN2P3-CNRS, France; CEA-DSM/IRFU, France; GNSF, Georgia; BMBF, Germany; DFG, Germany; HGF, Germany; MPG, Germany; AvH Foundation, Germany; GSRT, Greece; NSRF, Greece; ISF, Israel; MINERVA, Israel; GIF, Israel; DIP, Israel; Benoziyo Center, Israel; INFN, Italy; MEXT, Japan; JSPS, Japan; CNRST, Morocco; FOM, Netherlands; NWO, Netherlands; BRF, Norway; RCN, Norway; MNiSW, Poland; GRICES, Portugal; FCT, Portugal; MERYS (MECTS), Romania; MES of Russia; ROSATOM, Russian Federation; JINR; MSTD, Serbia; MSSR, Slovakia; ARRS, Slovenia; MIZS, Slovenia; DST/NRF, South Africa; MICINN, Spain; SRC, Sweden; Wallenberg Foundation, Sweden; SER, Switzerland; SNSF, Switzerland; Canton of Bern, Switzerland; Canton of Geneva, Switzerland; NSC, Taiwan; TAEK, Turkey; STFC, United Kingdom; Royal Society, United Kingdom; Leverhulme Trust, United Kingdom; DOE, United States of America; NSF, United States of America

Journal ArticleDOI
TL;DR: In this article, a search for fermionic top quark partners T of charge 2/3 was carried out in proton-proton collisions corresponding to an integrated luminosity of 19.7 inverse femtobarns collected at a center-of-mass energy of sqrt(s) = 8 TeV with the CMS detector at the LHC.
Abstract: A search for fermionic top quark partners T of charge 2/3 is presented. The search is carried out in proton-proton collisions corresponding to an integrated luminosity of 19.7 inverse femtobarns collected at a center-of-mass energy of sqrt(s) = 8 TeV with the CMS detector at the LHC. The T quarks are assumed to be produced strongly in pairs and can decay into tH, tZ, and bW. The search is performed in five exclusive channels: a single-lepton channel, a multilepton channel, two all-hadronic channels optimized either for the bW or the tH decay, and one channel in which the Higgs boson decays into two photons. The results are found to be compatible with the standard model expectations in all the investigated final states. A statistical combination of these results is performed and lower limits on the T quark mass are set. Depending on the branching fractions, lower mass limits between 720 and 920 GeV at 95% confidence level are found. These are among the strongest limits on vector-like T quarks obtained to date.

Journal ArticleDOI
TL;DR: In this paper, the authors describe the algorithms used by the CMS experiment to reconstruct and identify tau to hadrons + tau neutrino decays during Run 1 of the LHC.
Abstract: This paper describes the algorithms used by the CMS experiment to reconstruct and identify tau to hadrons + tau neutrino decays during Run 1 of the LHC. The performance of the algorithms is studied in proton-proton collisions recorded at a centre-of-mass energy of 8 TeV, corresponding to an integrated luminosity of 19.7 inverse femtobarns. The algorithms achieve an identification efficiency of 50-60%, with misidentification rates for quark and gluon jets, electrons, and muons between per mille and per cent levels.

Journal ArticleDOI
Sera Shin1, Jungmok Seo1, Heetak Han1, Subin Kang1, Hyun-Chul Kim1, Taeyoon Lee1 
TL;DR: The engineering of surface wettability by manipulating chemical properties and structure opens emerging biomedical applications ranging from high-throughput cell culture platforms to biomedical devices.
Abstract: Biological creatures with unique surface wettability have long served as a source of inspiration for scientists and engineers. More specifically, materials exhibiting extreme wetting properties, such as superhydrophilic and superhydrophobic surfaces, have attracted considerable attention because of their potential use in various applications, such as self-cleaning fabrics, anti-fog windows, anti-corrosive coatings, drag-reduction systems, and efficient water transportation. In particular, the engineering of surface wettability by manipulating chemical properties and structure opens emerging biomedical applications ranging from high-throughput cell culture platforms to biomedical devices. This review describes design and fabrication methods for artificial extreme wetting surfaces. Next, we introduce some of the newer and emerging biomedical applications using extreme wetting surfaces. Current challenges and future prospects of the surfaces for potential biomedical applications are also addressed.

Journal ArticleDOI
Georges Aad1, Brad Abbott2, Jalal Abdallah3, Ovsat Abdinov4  +2854 moreInstitutions (191)
TL;DR: Results of a search for new phenomena in events with at least three photons are reported, with limits at the 95 % confidence level on new phenomena presented based on the rate of events in an inclusive signal region and a restricted signal region targeting the rare decay of the Higgs boson.
Abstract: Results of a search for new phenomena in events with at least three photons are reported. Data from proton-proton collisions at a centre-of-mass energy of 8 TeV, corresponding to an integrated lumi ...

Journal ArticleDOI
Vardan Khachatryan1, Albert M. Sirunyan1, Armen Tumasyan1, Wolfgang Adam  +2311 moreInstitutions (180)
TL;DR: In this article, a search for a heavy scalar boson H decaying into a pair of lighter standard-model-like 125 GeV Higgs bosons h and an h boson decaying into an H boson was performed on a dataset corresponding to an integrated luminosity of 19.7 inverse femtobarns of pp collision data at a centre-of-mass energy of 8 TeV.

Journal ArticleDOI
Morad Aaboud, Georges Aad1, Brad Abbott2, Jalal Abdallah3  +2837 moreInstitutions (193)
TL;DR: In this paper, a search for squarks and gluinos in final states containing hadronic jets, missing transverse momentum but no electrons or muons is presented; the data were recorded in 2015 by the ATLAS experiment.
Abstract: A search for squarks and gluinos in final states containing hadronic jets, missing transverse momentum but no electrons or muons is presented. The data were recorded in 2015 by the ATLAS experiment ...

Journal ArticleDOI
TL;DR: In this article, a sulfur-embedded polybenzoxazine (S-BOP) with a high sulfur content of 72 wt % was achieved via thermal ring-opening polymerization of benzoxazine in the presence of elemental sulfur, and the covalent attachment of sulfur to the polymer was rationally directed through the thiol group.
Abstract: A variety of advanced electrode structures have been developed lately to address the intrinsic drawbacks of lithium–sulfur batteries, such as polysulfide shuttling and low electrical conductivity of elemental sulfur. Nevertheless, it is still desired to find electrode structures that address those issues through an easy synthesis while securing large sulfur contents (i.e., > 70 wt %). Here, we report an orthogonal, “one-pot” synthetic approach to prepare a sulfur-embedded polybenzoxazine (S-BOP) with a high sulfur content of 72 wt %. This sulfur-embedded polymer was achieved via thermal ring-opening polymerization of benzoxazine in the presence of elemental sulfur, and the covalent attachment of sulfur to the polymer was rationally directed through the thiol group of benzoxazine. Also, the resulting S-BOP bears a homogeneous distribution of sulfur due to in situ formation of the polymer backbone. This unique internal structure endows S-BOP with high initial Coulombic efficiency (96.6%) and robust cyclabil...