Author
Ian A. Franchi
Other affiliations: Leiden University, Max Planck Society, Planetary Science Institute
Bio: Ian A. Franchi is an academic researcher from Open University. The author has contributed to research in topics: Chondrite & Meteorite. The author has an hindex of 55, co-authored 388 publications receiving 11190 citations. Previous affiliations of Ian A. Franchi include Leiden University & Max Planck Society.
Topics: Chondrite, Meteorite, Parent body, Chondrule, Basalt
Papers published on a yearly basis
Papers
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George Washington University1, Colgate University2, St. John's University3, University of Wisconsin-Madison4, Swedish Museum of Natural History5, University of Göttingen6, National Institute of Advanced Industrial Science and Technology7, University of Mainz8, University of Lausanne9, Open University10, University of Edinburgh11, Utrecht University12, University of Tasmania13, University of Maryland, College Park14, Hiroshima University15, University of Tübingen16, University of Saskatchewan17, University of Science and Technology of China18
TL;DR: In this article, the results from a second characterisation of the 91500 zircon, including data from electron probe microanalysis, laser ablation inductively coupled plasma-mass spectrometer (LA-ICP-MS), secondary ion mass spectrometry (SIMS), and laser fluorination analyses, were reported.
Abstract: This paper reports the results from a second characterisation of the 91500 zircon, including data from electron probe microanalysis, laser ablation inductively coupled plasma-mass spectrometry (LA-ICP-MS), secondary ion mass spectrometry (SIMS) and laser fluorination analyses. The focus of this initiative was to establish the suitability of this large single zircon crystal for calibrating in situ analyses of the rare earth elements and oxygen isotopes, as well as to provide working values for key geochemical systems. In addition to extensive testing of the chemical and structural homogeneity of this sample, the occurrence of banding in 91500 in both backscattered electron and cathodoluminescence images is described in detail. Blind intercomparison data reported by both LA-ICP-MS and SIMS laboratories indicate that only small systematic differences exist between the data sets provided by these two techniques. Furthermore, the use of NIST SRM 610 glass as the calibrant for SIMS analyses was found to introduce little or no systematic error into the results for zircon. Based on both laser fluorination and SIMS data, zircon 91500 seems to be very well suited for calibrating in situ oxygen isotopic analyses.
1,131 citations
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Donald E. Brownlee1, Peter Tsou2, Jérôme Aléon3, Conel M. O'd. Alexander4 +182 more•Institutions (57)
TL;DR: The Stardust spacecraft collected thousands of particles from comet 81P/Wild 2 and returned them to Earth for laboratory study, and preliminary examination shows that the nonvolatile portion of the comet is an unequilibrated assortment of materials that have both presolar and solar system origin.
Abstract: The Stardust spacecraft collected thousands of particles from comet 81P/Wild 2 and returned them to Earth for laboratory study. The preliminary examination of these samples shows that the nonvolatile portion of the comet is an unequilibrated assortment of materials that have both presolar and solar system origin. The comet contains an abundance of silicate grains that are much larger than predictions of interstellar grain models, and many of these are high-temperature minerals that appear to have formed in the inner regions of the solar nebula. Their presence in a comet proves that the formation of the solar system included mixing on the grandest scales.
886 citations
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Ames Research Center1, Lawrence Livermore National Laboratory2, Carnegie Institution for Science3, North Carolina State University4, University of Paris-Sud5, University of Washington6, University of Kent7, University of California, Berkeley8, Goddard Space Flight Center9, Stony Brook University10, University at Albany, SUNY11, Open University12, Lawrence Berkeley National Laboratory13, University of Münster14, California Institute of Technology15, Parthenope University of Naples16, Stanford University17, Washington University in St. Louis18
TL;DR: The presence of deuterium and nitrogen-15 excesses suggest that some organics have an interstellar/protostellar heritage and a diverse suite of organic compounds is present and identifiable within the returned samples.
Abstract: Organics found in comet 81P/Wild 2 samples show a heterogeneous and unequilibrated distribution in abundance and composition. Some organics are similar, but not identical, to those in interplanetary dust particles and carbonaceous meteorites. A class of aromatic-poor organic material is also present. The organics are rich in oxygen and nitrogen compared with meteoritic organics. Aromatic compounds are present, but the samples tend to be relatively poorer in aromatics than are meteorites and interplanetary dust particles. The presence of deuterium and nitrogen-15 excesses suggest that some organics have an interstellar/protostellar heritage. Although the variable extent of modification of these materials by impact capture is not yet fully constrained, a diverse suite of organic compounds is present and identifiable within the returned samples.
547 citations
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TL;DR: It is shown that magma oceans were present on all the differentiated Solar System bodies so far sampled, and the modification of such bodies before incorporation into larger objects can explain some anomalous planetary features, such as Earth's high Mg/Si ratio.
Abstract: Our Solar System formed about 4.6 billion years ago, and within 4 million years small planetary bodies had formed, some melting to form volcanic and related rocks. Two families of meteorites (the HEDs and angrites) are thought to have originated from asteroids that melted at this time. New oxygen isotope measurements confirm that these meteorites are from two distinct asteroids that underwent large-scale melting in the early Solar System. These new results show that early, global-scale melting was a feature of all the differentiated planets (Earth, Moon and Mars) and asteroids so far sampled. Immediately following the formation of the Solar System, small planetary bodies accreted1, some of which melted to produce igneous rocks2,3. Over a longer timescale (15–33 Myr), the inner planets grew by incorporation of these smaller objects4,5 through collisions. Processes operating on such asteroids strongly influenced the final composition of these planets4, including Earth5. Currently there is little agreement about the nature of asteroidal igneous activity: proposals range from small-scale melting, to near total fusion and the formation of deep magma oceans2. Here we report a study of oxygen isotopes in two basaltic meteorite suites, the HEDs (howardites, eucrites and diogenites, which are thought to sample the asteroid 4 Vesta6) and the angrites (from an unidentified asteroidal source). Our results demonstrate that these meteorite suites formed during early, global-scale melting (≥ 50 per cent) events. We show that magma oceans were present on all the differentiated Solar System bodies so far sampled. Magma oceans produced compositionally layered planetesimals; the modification of such bodies before incorporation into larger objects can explain some anomalous planetary features, such as Earth's high Mg/Si ratio.
314 citations
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Lawrence Livermore National Laboratory1, Open University2, University of Washington3, University of Kent4, University of California, San Diego5, University of Chicago6, Washington University in St. Louis7, Max Planck Society8, Natural History Museum9, Lille University of Science and Technology10, University of California, Berkeley11, University of Münster12, United States Naval Research Laboratory13, Spanish National Research Council14, California Institute of Technology15
TL;DR: Particles emanating from comet 81P/Wild 2 collided with the Stardust spacecraft at 6.1 kilometers per second, producing hypervelocity impact features on the collector surfaces that were returned to Earth.
Abstract: Particles emanating from comet 81P/Wild 2 collided with the Stardust spacecraft at 6.1 kilometers per second, producing hypervelocity impact features on the collector surfaces that were returned to Earth. The morphologies of these surprisingly diverse features were created by particles varying from dense mineral grains to loosely bound, polymineralic aggregates ranging from tens of nanometers to hundreds of micrometers in size. The cumulative size distribution of Wild 2 dust is shallower than that of comet Halley, yet steeper than that of comet Grigg-Skjellerup.
308 citations
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Academy of Sciences of the Czech Republic1, Charles University in Prague2, University of Bergen3, University of Nottingham4, Boise State University5, Goethe University Frankfurt6, Memorial University of Newfoundland7, Stockholm University8, University of Vienna9, University of Geneva10, Swedish Museum of Natural History11
TL;DR: The Plesovice zircon as discussed by the authors has a concordant U-Pb age with a weighted mean Pb-206/U-238 date of 337.13 +/- 0.37 Ma (ID-TIMS, 95% confidence limits, including tracer calibration uncertainty).
3,694 citations
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TL;DR: In this article, the first finding of continental crust-derived Precambrian zircons in garnet/spinel pyroxenite veins within mantle xenoliths carried by the Neogene Hannuoba basalt in the central zone of the North China Craton (NCC).
Abstract: We present the first finding of continental crust-derived Precambrian zircons in garnet/spinel pyroxenite veins within mantle xenoliths carried by the Neogene Hannuoba basalt in the central zone of the North China Craton (NCC). Petrological and geochemical features indicate that these mantle-derived composite xenoliths were formed by silicic melt^lherzolite interaction. The Precambrian zircon ages can be classified into three age groups of 2·4^2·5 Ga, 1·6^2·2 Ga and 0·6^1·2 Ga, coinciding with major geological events in the NCC. These Precambrian zircons fall in the field of continental granitoid rocks in plots of U/Yb vs Hf and Y. Their igneous-type REE patterns and metamorphic zircon type CL images indicate that they were not crystallized during melt^peridotite interaction and subsequent high-pressure metamorphism.The 2·5 Ga zircons have positive eHf(t) values (2·9^10·6), whereas the younger Precambrian zircons are dominated by negative eHf(t) values, indicating an ancient continental crustal origin.These observations suggest that the Precambrian zircons were xenocrysts that survived melting of recycled continental crustal rocks and were then injected with silicate melt into the host peridotite. In addition to the Precambrian zircons, igneous zircons of 315 3 Ma (2 ), 80^170 Ma and 48^64 Ma were separated from the garnet/spinel pyroxenite veins; these provide evidence for lower continental crust and oceanic crust recycling-induced multi-episodic melt^peridotite interactions in the central zone of the NCC. The combination of the positive eHf(t) values (2·91^24·6) of the 315 Ma zircons with the rare occurrence of 302^324 Ma subduction-related diorite^granite plutons in the northern margin of the NCC implies that the 315 Ma igneous zircons might record melt^peridotite interactions in the lithospheric mantle induced by Palaeo-Asian oceanic crust subduction. Igneous zircons of age 80^170 Ma generally coexist with the Precambrian metamorphic zircons and have lower Ce/Yb and Th/U ratios, higher U/Yb ratios and greater negative Eu anomalies.The eHf(t) values of these zircons vary greatly from ^47·6 to 24·6.The 170^110 Ma zircons are generally characterized by negative eHf(t) values, whereas the 110^100 Ma zircons have positive eHf(t) values.These observations suggest that melt^peridotite interactions at 80^170 Ma were induced by partial melting of recycled continental crust. The 48^64 Ma igneous zircons are characterized by negligible Ce anomalies, unusually high REE, U and Th contents, and positive eHf(t) values.These features imply that the melt^peridotite interactions at 48^64 Ma could be associated with a depleted mantle-derived carbonate melt or fluid.
2,753 citations
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TL;DR: In this article, the mean β Yb value of the individual spot and newly published Yb isotopic abundance data, six standard zircons and two standard baddeleyites, have been investigated using a Neptune MC-ICPMS, with 193 mm laser.
2,161 citations
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TL;DR: A general approach to EDLC design leading to the maximum energy density is suggested, which has been now proved for both solvated organic salts and solvent-free liquid electrolytes.
Abstract: The research on electrochemical double layer capacitors (EDLC), also known as supercapacitors or ultracapacitors, is quickly expanding because their power delivery performance fills the gap between dielectric capacitors and traditional batteries. However, many fundamental questions, such as the relations between the pore size of carbon electrodes, ion size of the electrolyte, and the capacitance have not yet been fully answered. We show that the pore size leading to the maximum double-layer capacitance of a TiC-derived carbon electrode in a solvent-free ethyl-methylimmidazolium-bis(trifluoro-methane-sulfonyl)imide (EMI-TFSI) ionic liquid is roughly equal to the ion size (∼0.7 nm). The capacitance values of TiC−CDC produced at 500 °C are more than 160 F/g and 85 F/cm3 at 60 °C, while standard activated carbons with larger pores and a broader pore size distribution present capacitance values lower than 100 F/g and 50 F/cm3 in ionic liquids. A significant drop in capacitance has been observed in pores that w...
1,913 citations
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TL;DR: In this paper, a protocol was established for simultaneous measurements of zircon U-Pb ages and trace elements by LA-ICP-MS at spot sizes of 16-32?m.
Abstract: A protocol was established for simultaneous measurements of zircon U-Pb ages and trace elements by LA-ICP-MS at spot sizes of 16–32 ?m. This was accomplished by introducing N2 into ICP to increase the sensitivity. The obtained U-Pb ages for zircon standards GJ-1, TEMORA and SK10-2 are consistent with the preferred values within about 1% uncertainty (2 σ ) by simple external calibration against zircon standard 91500. Different data reduction softwares could yield different uncertainties for calculation of U-Pb ages. The commercially available program GLITTER4.4 could apply an improper uncertainty calculation strategy, but it may yield artificial high precisions for single analyses. Our trace element analyses indicate that Si is not an ideal internal standard for zircon when calibrated against the NIST glasses. Calibration against the NIST glasses using Si as an internal standard, a systematic deviation of 10%–30% was found for most trace elements including Zr. However, the trace element compositions of zircon can be accurately measured by calibration against multiple reference materials with natural compositions (e.g., BCR-2G, BHVO-2G and BIR-1G), or calibration against NIST SRM 610 and using Zr as an internal standard. Analyses of two pieces of GJ-1 demonstrate that it is relatively homogenous for most trace elements (except for Ti).
1,227 citations