Showing papers by "Indrapal Singh Aidhen published in 2002"
TL;DR: A synthetic route using an umpolung strategy led to a versatile intermediate aryl ketone 10, which has paved the way for two important classes of C-glycosides, viz., C-alkyl furanosides 12 and methyl 2-deoxy-C-aryl pyranosides 14.
16 citations
TL;DR: In this paper, various N,N-disubstituted-amino-n-methoxy-N-methylpropanamides 3a-i were prepared which served as an excellent -aminoacyl cation equivalents.
Abstract: Synthesis 2001, No. 15, 12 11 2001. Article Identifier: 1437-210X,E;2001,0,15,2239,2246,ftx,en;T05101SS.pdf. © Georg Thieme Verlag Stuttgart · New York ISSN 0039-7881 Abstract: Various N,N-disubstituted-amino-N-methoxy-N-methylpropanamides 3a–i were prepared which served as an excellent -aminoacyl cation equivalents. These were used to prepare -amino ketones 1, pharmacologically active tertiary 1-(3,3-diarylpropyl)amines 7a–c, and the interesting C-glycoside 8.
4 citations
TL;DR: In this paper, the authors describe a synthetic route using an umpolung strategy, which has not been explored till date, which led to a versatile intermediate aryl ketone 10 which has paved the way for two important classes of C-glycosides, viz., C-alkyl furanosides 12 and methyl 2-deoxy-C-aryl pyranosides 14.
Abstract: 2-Deoxy-C-aryl glycosides are potential synthetic targets as they form a very vital moiety of several biologically active natural products. This paper describes a synthetic route using an umpolung strategy, which has not been explored till date. Our synthetic endeavor led to a versatile intermediate aryl ketone 10, which has paved the way for two important classes of C-glycosides, viz., C-alkyl furanosides 12 and methyl 2-deoxy-C-aryl pyranosides 14.
2 citations