Author
J. A. Walmsley
Other affiliations: University of North Carolina at Chapel Hill
Bio: J. A. Walmsley is an academic researcher from Florida State University. The author has contributed to research in topics: Coordination sphere & Pyridine. The author has an hindex of 2, co-authored 2 publications receiving 337 citations. Previous affiliations of J. A. Walmsley include University of North Carolina at Chapel Hill.
Papers
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TL;DR: The coordination chemistry of pyridine N-oxide with a variety of acceptors has been investigated in this article, where the new substances Co(ClO4)26L, Co(NO3)24L), CoCl23L and CoCl2LH20, NiClO 4H2O, NiBr26L and NiBr2L H2O have been isolated and characterized by molecular conductance measurements in non-aqueous solvents, magnetic susceptibility measurements, and infrared spectra.
Abstract: : The coordination chemistry of pyridine N-oxide with a variety of acceptors has been investigated The new substances Co(ClO4)26L, Co(NO3)26L, CoCl23L, CoCl2LH20, Ni(ClO4)26L, NiCl2LH2O, NiBr26L, NiI26L, NiBr2L H2O, Cu(ClO4)24L, Cu(NO3)22L, CuCl2L, CuCl22L, Zn(ClO4)26L, ZnCl22L, Zn(NO3)26L, Fe(ClO4)26L, Fe(ClO4)36L, and SnBr42L (where L is pyridine N-oxide) have been isolated and characterized by molecular conductance measurements in non-aqueous solvents, magnetic susceptibility measurements, and infrared spectra All of the perchlorates and some of the nitrates and halides have only the pyridine N-oxide in the first coordination sphere However, in some cases, both nitrates and halides are coordinated to the central ion
176 citations
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TL;DR: In this article, the infra-red spectra of various types of complexes of pyridine Noxide with cobalt(II), nickel, zinc, aluminum, chromium, iron, and tin were measured in the 3-15 μ region.
164 citations
Cited by
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8,264 citations
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416 citations
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TL;DR: In this paper, Darstellung, Eigenschaften, Substituenteneffekte und Donoreigenschalkte werden zusammenfassend behandelt.
226 citations
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TL;DR: Tris-and bis-ligand complexes of nickel with S-benzyldithiocarbazate (SBDTC) have been synthesized and characterized by electronic and IR spectroscopy and magnetic measurements as discussed by the authors.
205 citations
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TL;DR: Chrysotile asbestos hemolyses erythrocytes within 10 minutes and over a wide range of pH, which accords with the suggestion that magnesium is the principal agent in hemolysis by asbestos.
179 citations