J. E. Graebner

Bio: J. E. Graebner is an academic researcher from Alcatel-Lucent. The author has contributed to research in topics: Dielectric & Perovskite (structure). The author has an hindex of 1, co-authored 1 publications receiving 28 citations.

Growth and measurements of ferroelectric lead zirconate titanate on diamond by pulsed laser deposition

Abstract: Pb(Zr0.53Ti0.47)O3 (PZT) on diamond is a potentially robust structure for surface acoustic wave (SAW) device applications. We have studied the growth and physical characteristics of PZT on diamond and other substrates by pulsed laser deposition. Under a broad range of processing conditions we explored, PZT deposited directly on diamond is almost exclusively pyrochlore-type, which is nonferroelectric. Growth of ferroelectric perovskite PZT is promoted via the use of a PbTiO3 buffer layer within a narrow window of processing parameters [i.e., P(O2)=100–200 mTorr, T=550–650 °C, 1–2 J/cm2]. Similar results were also obtained for deposition of PZT on Si, Pt-coated Si, and Pt-coated diamond substrates. The dielectric constants of the perovskite PZT films are 500–650 at 1 V and 100 kHz. The piezoelectric coefficients of these films are in the range of 50×10−12–350×10−12 m/V. The SAW velocity of perovskite PZT films is similar to that of highly oriented sputter deposited ZnO films. The acoustic attenuation in per...

Processing, Structure, Properties, and Applications of PZT Thin Films

Abstract: There has been a resurgence of complex oxides of late owing to their ferroelectric and ferromagnetic properties. Although these properties had been recognized decades ago, the renewed interest stems from modern deposition techniques that can produce high quality materials and attractive proposed device concepts. In addition to their use on their own, the interest is building on the use of these materials in a stack also. Ferroelectrics are dielectric materials that have spontaneous polarization in certain temperature range and show nonlinear polarization–electric field dependence called a hysteresis loop. The outstanding properties of the ferroelectrics are due to non-centro-symmetric crystal structure resulting from slight distortion of the cubic perovskite structure. The ferroelectric materials are ferroelastic also in that a change in shape results in a change in the electric polarization (thus electric field) developed in the crystal and vice versa. Therefore they can be used to transform acoustic wav...

Optical Generation and Characterization of Acoustic Waves in Thin Films: Fundamentals and Applications

Abstract: ▪ Abstract The mechanical and acoustic properties of thin films and multilayer assemblies are important both for technological applications of these materials and for basic scientific studies of their physical behavior. Techniques that use optical methods to monitor acoustic waves stimulated in thin films with short pulsed lasers are useful for accurately and nondestructively characterizing the high frequency acoustic physics of these systems. This review briefly summarizes some of these techniques and focuses on a method known as impulsive stimulated thermal scattering or transient grating photoacoustics. It describes the most advanced experimental techniques for performing this measurement and outlines its application to the study of acoustic waveguide modes in a variety of thin films. These measurements, coupled with models for the physics of the modes, can be used to determine intrinsic mechanical properties of materials and structures that occur, for example, in microelectronics and high-frequency ac...

Oxides, Oxides, and More Oxides: High-κ Oxides, Ferroelectrics, Ferromagnetics, and Multiferroics

Abstract: We review and critique the recent developments on multifunctional oxide materials, which are gaining a good deal of interest. Recongnizing that this is a vast area, the focus of this treatment is mainly on high-κ dielectric, ferroelectric, magnetic, and multiferroic materials. Also, we consider ferrimagnetic oxides in the context of the new, rapidly developing field of negative-index metamaterials. This review is motivated by the recent resurgence of interest in complex oxides owing to their coupling of electrical, magnetic, thermal, mechanical, and optical properties, which make them suitable for a wide variety of applications, including heat, motion, electric, and magnetic sensors; tunable and compact microwave passive components; surface acoustic wave devices; nonlinear optics; and nonvolatile memory, and pave the way for designing multifunctional devices and unique applications in spintronics and negative refraction-index media. For most of the materials treated here, structural and physical propertie...

Structural, ferroelectric and optical properties of PZT thin films

Abstract: We report on the structural, ferroelectric and optical properties of lead zirconate titanate (PZT) thin films (with a molar ratio of Zr:Ti::65:35) deposited by sol–gel technique on ITO-coated corning 7059 glass substrates. A seed layer of PbTiO3 (0.1mm) was coated by sol–gel on the substrates before depositing PZT. A metal/ferroelectric/metal (MFM) structure was used for electrical property measurements, formed by depositing gold electrodes on top of the film. The films were characterized for C–V, I–V, P–E and optical transmission. Relatively low remnant polarization (Pr ¼ 3:6mC=cm 2 ) was observed for the films. Value of optical band gap was found to be 3.4 eV. The results are discussed.

Piezoelectric/ultrananocrystalline diamond heterostructures for high-performance multifunctional micro/nanoelectromechanical systems

Abstract: Most current micro/nanoelectromechanical systems (MEMS/NEMS) are based on silicon. However, silicon exhibits relatively poor mechanical/tribological properties, compromising applications to some devices. Diamond films with superior mechanical/tribological properties provide an excellent alternative platform material. Ultrananocrystalline diamond (UNCD®) in film form with 2–5nm grains exhibits excellent properties for high-performance MEMS/NEMS devices. Concurrently, piezoelectric Pb(ZrxTi1−x)O3 (PZT) films provide high sensitivity/low electrical noise for sensing/high-force actuation at relatively low voltages. Therefore, integration of PZT and UNCD films provides a high-performance platform for advanced MEMS/NEMS devices. This letter describes the bases of such integration and demonstration of low voltage piezoactuated hybrid PZT/UNCD cantilevers.