Recent advances in graphene based polymer composites

Recently, graphene has attracted both academic and industrial interest because it can produce a dramatic improvement in properties at low filler content. The utilization of graphene-based materials in the fabrication of nanocomposities with different polymer matrixes has been explored. This review article presents and discusses the development of graphene-based polymer composites and their applications in different fields such as electronics devices, energy storage, sensors, ESD and EMI shielding and biomedical applications.

Graphene-Based Polymer Composites and Their Applications

In this paper, an atmospheric-pressure dielectric barrier discharge is used to modify the surface of the epoxy material and enhance the dissipation of surface charge to reduce the accumulation of surface charge. In the experiments, atmospheric-pressure air dielectric barrier discharge is driven by a microsecond pulse generator. Surface properties of epoxy before and after the plasma treatment are characterized by water contact angle, surface potential, and surface/volume conductivity measurements. Atomic force microscope and X-ray photoelectron spectroscopy are used to investigate the changes of the morphology and the chemical composition of the epoxy surface. Experimental results indicate that the surface of epoxy is etched by the plasma and the increase of the surface roughness enhances the surface insulation ability. The O radicals in plasma and the carbonyl groups formed on the surface make the surface charge trap shallower, change the epoxy surface composition then increase the surface conductivity and accelerate surface charge dissipation. When the epoxy is treated for an appropriate time, the epoxy surface insulation performance will be enhanced obviously and the surface charge dissipation will be accelerated.

Surface modification of epoxy using an atmospheric pressure dielectric barrier discharge to accelerate surface charge dissipation

ower transformers are one of the most expensive elements in a power system, and their failure is a very costly event. Power transformers are mainly involved in energy transmission and distribution. Unplanned power transformer outages have considerable economic impact on the operation of electric power networks. To have reliable operation of transformers, it is necessary to identify problems at an early stage before a catastrophic failure occurs. In spite of corrective and predictive maintenance, preventive maintenance is gaining due importance in the modern era, and it must be taken into account to obtain the highest reliability of power apparatus such as power transformers. The well-known preventive maintenance techniques such as dissolved gas analysis (DGA), thermal monitoring, partial discharge measurement, capacitance and tan delta measurements, frequency response analysis, etc. are performed on transformers for a specific type of problem. DGA is a very efficient and reliable tool for the earliest detection of inception faults in transformer and other electrical equipment using insulating oil. Condition monitoring of electrical equipment, such as transformers, helps users in many ways such as planning of maintenance schedule, obtaining knowledge of the health of equipment, estimating the remaining service life of equipment, finding areas of further improvement, refining product specification, etc. Kraft paper (cellulose) immersed in mineral oil is used as the insulation system for the copper windings in large power transformers. As the system ages under load, the paper and oil can degrade, potentially leading to catastrophic failure. Partial discharge (PD) is an important tool for improving the reliability of HV insulation systems. It is a very sensitive and nondestructive method of evaluation of the health of the insulation of any HV equipment. PD always is associated with the degradation of insulation systems in HV equipment. Therefore, PDs need to be detected, measured, located, and reduced to a safe value so that the quality of the insulation system is not affected.

Condition Monitoring of Power Transformers - Bibliography Survey

Hydrophilic modification of polymethyl methacrylate (PMMA) surface is performed by atmospheric pressure plasma jet (APPJ) in Ar gas for improving the PMMA surface flashover performance in vacuum. In the experiments, APPJ is driven by a microsecond-duration pulsed generator, which has voltages of 0-30 kV, a rise time of 300 ns and a full width at half maximum of 2μs. Characteristics of the APPJ are analyzed according to its voltage and current waveform, discharge image and optical emission spectrum. Furthermore, surface properties of the PMMA surface before and after the treatment are characterized by water contact angle measurements and morphology observations. Results show that the main species of the plasma jet are composed of N2, Ar, OH, and O, among which such polar groups as OH and O enhance the hydrophilic property of the PMMA surface. The water contact angle decreases from 68° to a minimum value (16°) after the treatment. In addition, all the surface flashover voltages in vacuum for the PMMA samples treated by APPJ are higher than those for the untreated PMMA samples.

Surface modification of polymethyl-methacrylate using atmospheric pressure argon plasma jets to improve surface flashover performance in vacuum

A series of styrene–butadiene rubber (SBR) composites have been prepared with different weight ratios of polyacetylene based conducting carbon black (CCB) (0–90 phr). The SBR–CCB systems are characterized for dimensional stability which is enhanced by increasing the CCB loading because of enhancement in polymer-filler interaction. The electrical properties such as dielectric constant (er), dissipation factor (tan δ) and dielectric loss (e″) of the composites have been studied. The influence of different loading of CCB (0–90 phr), frequency of ac (100 Hz–30 MHz) and temperature (25–75 °C) on the electrical properties was studied. An increase in dielectric constant and tan δ of the SBR composites was observed with increase in CCB content and ac frequency. This is due to enhancement of filler–filler interaction and the increase in continuity of conducting phase. The surface morphology has been studied using scanning electron microscopy (SEM).

Dielectric properties of carbon black: SBR composites

Polarization and depolarization current measurements are promising on-site, off-line, non-destructive, non-invasive diagnostic tool for condition assessment of paper-oil insulation of transformers. Interpretation of the results of polarization and depolarization current is complex and hence not practiced as a routine diagnostic method for condition monitoring of transformers. This paper discusses various factors affecting polarization and depolarization current measurements with a deeper insight into the theoretical and practical aspects of this technique. Some of the concerns of PDC measurement are explained with support from simulation and experimental studies on paper oil insulation of a laboratory model transformer. Few case studies are discussed to highlight the difficulties in interpretation of results.

Factors affecting polarization and depolarization current measurements on insulation of transformers

The surface discharge injected current were measured by using High Frequency Current Transformer (HFCT). It is observed that the rise time of the current pulse is about 800ps. In addition, the rise time of the current pulses has not altered in copper sulphide (CuS) diffused Oil Impregnated Pressboard (OIP) material, but the width of the current signal has increased with the increase in the amount of copper sulphide diffusion into the pressboard. It is confirmed that the injected current pulse radiates Ultra High Frequency (UHF) signal and the dominant frequency of the UHF signal formed due to the surface discharge injected current is about 0.9 GHz. The characteristic frequency contents of the UHF signal formed due to surface discharge activity is the same with the virgin and copper sulphide diffused pressboard material. The surface discharge inception voltage is high with the virgin specimen compared with copper sulphide diffused oil impregnated paper insulating material and is the same irrespective of the amount of diffusion of copper sulphide to it. The Phase Resolved Partial Discharge (PRPD) analysis indicates that at the point of surface discharge inception, the discharge occurs at the peak of the applied AC voltage and when the applied voltage magnitude is increased, the discharge occurs at the rising portion of the applied AC voltage. The characteristics of the surface discharges formed are the same with the copper sulphide diffused oil impregnated pressboard material. It is noticed that with increase in ageing time, a reduction in partial discharge magnitude is observed. Attenuated total reflectance Fourier transform infra-red spectroscopy (ATR-FTIR) analysis was carried out to understand the characteristic changes that occur in the degraded zone formed due to surface discharges. The measurement of surface charge indicates that ageing of oil impregnated paper material increases the surface charge accumulation. Energy Dispersive Spectroscopy (EDS) confirms the presence of copper and sulphur in the aged Oil Impregnated Pressboard material. The Atomic Absorption Spectroscopy (AAS) results indicate that the amount of copper content in pressboard material have increased with ageing time.

Understanding surface discharge activity in copper sulphide diffused oil impregnated pressboard under AC voltages

High-density polyethylene (HDPE) composites reinforced with multiwalled carbon nanotubes (MWCNTs) and nano-silicon dioxide (SiO2) fillers were evaluated for flame retardancy and thermal properties ...

Evaluation of thermal and flame properties of HDPE-MWCNT-SiO2 nanocomposites

Frequency dependence of the electromagnetic interference shielding effectiveness of carbon fiber epoxy composites have been investigated over the frequency range of 8–18 GHz. The effect of nylon-66 nanofiber interleaving on the shielding effectiveness of the multilayered quasi-isotropic composite has been examined for three different percentages of interleaving of nylon-66 nanofibers. Effect of γ-irradiation on the electromagnetic shielding efficiency has also been investigated. Though attenuation due to absorption is dominant in carbon fiber epoxy composites, it is observed that γ-irradiation helps in improving the attenuation due to reflection of the electromagnetic waves. The observed variations in the EM shielding of the composites are explained on the basis of the measured attenuation of EM radiations by absorption and reflection. The investigation has highlighted the usefulness of the carbon fiber epoxy composites, which are traditionally used in mechanical strength applications, for electromagnetic shielding in the range of microwave frequencies.

J. Sundara Rajan

Papers

Dielectric properties of carbon black: SBR composites

Factors affecting polarization and depolarization current measurements on insulation of transformers

Understanding surface discharge activity in copper sulphide diffused oil impregnated pressboard under AC voltages

Evaluation of thermal and flame properties of HDPE-MWCNT-SiO2 nanocomposites

Electromagnetic Shielding Effectiveness of Nylon-66 Nanofiber Interleaved Carbon Epoxy Composites