A comprehensive review of spatiotemporal pattern formation in systems driven away from equilibrium is presented, with emphasis on comparisons between theory and quantitative experiments. Examples include patterns in hydrodynamic systems such as thermal convection in pure fluids and binary mixtures, Taylor-Couette flow, parametric-wave instabilities, as well as patterns in solidification fronts, nonlinear optics, oscillatory chemical reactions and excitable biological media. The theoretical starting point is usually a set of deterministic equations of motion, typically in the form of nonlinear partial differential equations. These are sometimes supplemented by stochastic terms representing thermal or instrumental noise, but for macroscopic systems and carefully designed experiments the stochastic forces are often negligible. An aim of theory is to describe solutions of the deterministic equations that are likely to be reached starting from typical initial conditions and to persist at long times. A unified description is developed, based on the linear instabilities of a homogeneous state, which leads naturally to a classification of patterns in terms of the characteristic wave vector q0 and frequency ω0 of the instability. Type Is systems (ω0=0, q0≠0) are stationary in time and periodic in space; type IIIo systems (ω0≠0, q0=0) are periodic in time and uniform in space; and type Io systems (ω0≠0, q0≠0) are periodic in both space and time. Near a continuous (or supercritical) instability, the dynamics may be accurately described via "amplitude equations," whose form is universal for each type of instability. The specifics of each system enter only through the nonuniversal coefficients. Far from the instability threshold a different universal description known as the "phase equation" may be derived, but it is restricted to slow distortions of an ideal pattern. For many systems appropriate starting equations are either not known or too complicated to analyze conveniently. It is thus useful to introduce phenomenological order-parameter models, which lead to the correct amplitude equations near threshold, and which may be solved analytically or numerically in the nonlinear regime away from the instability. The above theoretical methods are useful in analyzing "real pattern effects" such as the influence of external boundaries, or the formation and dynamics of defects in ideal structures. An important element in nonequilibrium systems is the appearance of deterministic chaos. A greal deal is known about systems with a small number of degrees of freedom displaying "temporal chaos," where the structure of the phase space can be analyzed in detail. For spatially extended systems with many degrees of freedom, on the other hand, one is dealing with spatiotemporal chaos and appropriate methods of analysis need to be developed. In addition to the general features of nonequilibrium pattern formation discussed above, detailed reviews of theoretical and experimental work on many specific systems are presented. These include Rayleigh-Benard convection in a pure fluid, convection in binary-fluid mixtures, electrohydrodynamic convection in nematic liquid crystals, Taylor-Couette flow between rotating cylinders, parametric surface waves, patterns in certain open flow systems, oscillatory chemical reactions, static and dynamic patterns in biological media, crystallization fronts, and patterns in nonlinear optics. A concluding section summarizes what has and has not been accomplished, and attempts to assess the prospects for the future.

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Pattern formation outside of equilibrium

In this note we use the method of multiple scales to derive the two coupled nonlinear partial differential equations which describe the evolution of a three-dimensional wave-packet of wavenumber k on water of finite depth. The equations are used to study the stability of the uniform Stokes wavetrain to small disturbances whose length scale is large compared with 2π/ k . The stability criterion obtained is identical with that derived by Hayes under the more restrictive requirement that the disturbances are oblique plane waves in which the amplitude variation is much smaller than the phase variation.

On three-dimensional packets of surface waves

Slow modulation of gravity waves on water layer with uniform depth is investigated by using singular perturbation methods. It is found, to the lowest order of perturbation, that the complicated system of equations governing such modulation can be reduced to a simple nonlinear Schrodinger equation. A nonlinear plane wave solution to this equation is found to correspond to the so-called Stokes wave. The linear stability of this plane wave solution is essentially determined by the sign of the product of two coefficients in this equation, yielding Benjamin and Whitham's criterion. The same equation is found to give a weak cnoidal wave derived from the Korteweg-de Vries equation in the shallow-water limit.

Nonlinear Modulation of Gravity Waves

The development of a small three-dimensional disturbance in plane Poiseuille flow is considered. Its kinetic energy is expressed in terms of the velocity and vorticity components normal to the wall. The normal vorticity develops according to the mechanism of vortex stretching and is described by an inhomogeneous equation, where the spanwise variation of the normal velocity acts as forcing. To study specifically the effect of the forcing, the initial normal vorticity is set to zero and the energy density in the wavenumber plane, induced by the normal velocity, is determined. In particular, the response from individual (and damped) Orr–Sommerfeld modes is calculated, on the basis of a formal solution to the initial-value problem. The relevant timescale for the development of the perturbation is identified as a viscous one. Even so, the induced energy density can greatly exceed that associated with the initial normal velocity, before decay sets in. Initial conditions corresponding to the least-damped Orr–Sommerfeld mode induce the largest energy density and a maximum is obtained for structures infinitely elongated in the streamwise direction. In this limit, the asymptotic solution is derived and it shows that the spanwise wavenumbers at which the largest amplification occurs are 2.60 and 1.98, for symmetric and antisymmetric normal vorticity, respectively. The asymptotic analysis also shows that the propagation speed for induced symmetric vorticity is confined to a narrower range than that for antisymmetric vorticity. From a consideration of the neglected nonlinear terms it is found that the normal velocity component cannot be nonlinearly affected by the normal vorticity growth for structures with no streamwise dependence.

https://www.cambridge.org/core/services/aop-cambridge-core/content/view/S0022112081000384

Energy growth of three-dimensional disturbances in plane poiseuille flow

Interaction of slightly overlapping solitary pulses (SP's) is considered in the cubic nonlinear Schrodinger equation with small pumping and dissipation terms, and in the quintic Ginzburg-Landau equation with small dispersion terms In both cases, the small perturbing terms render the asymptotic wave form of a SP spatially oscillating Using the description of the interaction of SP's in terms of an effective potential, it is demonstrated that this fact may give way to formation of two pulse and multi-pulse bound states, which are weakly stable

Bound solitons in the nonlinear Schrödinger-Ginzburg-Landau equation.

The initial-value problem for linearized perturbations is discussed, and the asymptotic solution for large time is given. For values of the Reynolds number slightly greater than the critical value, above which perturbations may grow, the asymptotic solution is used as a guide in the choice of appropriate length and time scales for slow variations in the amplitude A of a non-linear two-dimensional perturbation wave. It is found that suitable time and space variables are et and e½(x+a1rt), where t is the time, x the distance in the direction of flow, e the growth rate of linearized theory and (−a1r) the group velocity. By the method of multiple scales, A is found to satisfy a non-linear parabolic differential equation, a generalization of the time-dependent equation of earlier work. Initial conditions are given by the asymptotic solution of linearized theory.

J. T. Stuart

Papers

A non-linear instability theory for a wave system in plane Poiseuille flow