This critical review provides a processing-structure-property perspective on recent advances in cellulose nanoparticles and composites produced from them. It summarizes cellulose nanoparticles in terms of particle morphology, crystal structure, and properties. Also described are the self-assembly and rheological properties of cellulose nanoparticle suspensions. The methodology of composite processing and resulting properties are fully covered, with an emphasis on neat and high fraction cellulose composites. Additionally, advances in predictive modeling from molecular dynamic simulations of crystalline cellulose to the continuum modeling of composites made with such particles are reviewed (392 references).

/pdf/cellulose-nanomaterials-review-structure-properties-and-2z8x922p3v.pdf

Cellulose nanomaterials review: structure, properties and nanocomposites

This work presents the analytic and experimental development of piezoelectric actuators as elements of intelligent structures, i.e., structures with highly distributed actuators, sensors, and processing networks. Static and dynamic analytic models are derived for segmented piezoelectric actuators that are either bonded to an elastic substructure or embedded in a laminated composite. These models lead to the ability to predict, a priori, the response of the structural member to a command voltage applied to the piezoelectric and give guidance as to the optimal location for actuator placement. A scaling analysis is performed to demonstrate that the effectiveness of piezoelectric actuators is independent of the size of the structure and to evaluate various piezoelectric materials based on their effectiveness in transmitting strain to the substructure. Three test specimens of cantilevered beams were constructed: an aluminum beam with surface-bonded actuators, a glass/epoxy beam with embedded actuators, and a graphite/epoxy beam with embedded actuators. The actuators were used to excite steady-state resonant vibrations in the cantilevered beams. The response of the specimens compared well with those predicted by the analytic models. Static tensile tests performed on glass/epoxy laminates indicated that the embedded actuator reduced the ultimate strength of the laminate by 20%, while not significantly affecting the global elastic modulus of the specimen.

Use of piezoelectric actuators as elements of intelligent structures

This paper provides an overview of recent progress made in the area of cellulose nanofibre-based nanocomposites. An introduction into the methods used to isolate cellulose nanofibres (nanowhiskers, nanofibrils) is given, with details of their structure. Following this, the article is split into sections dealing with processing and characterisation of cellulose nanocomposites and new developments in the area, with particular emphasis on applications. The types of cellulose nanofibres covered are those extracted from plants by acid hydrolysis (nanowhiskers), mechanical treatment and those that occur naturally (tunicate nanowhiskers) or under culturing conditions (bacterial cellulose nanofibrils). Research highlighted in the article are the use of cellulose nanowhiskers for shape memory nanocomposites, analysis of the interfacial properties of cellulose nanowhisker and nanofibril-based composites using Raman spectroscopy, switchable interfaces that mimic sea cucumbers, polymerisation from the surface of cellulose nanowhiskers by atom transfer radical polymerisation and ring opening polymerisation, and methods to analyse the dispersion of nanowhiskers. The applications and new advances covered in this review are the use of cellulose nanofibres to reinforce adhesives, to make optically transparent paper for electronic displays, to create DNA-hybrid materials, to generate hierarchical composites and for use in foams, aerogels and starch nanocomposites and the use of all-cellulose nanocomposites for enhanced coupling between matrix and fibre. A comprehensive coverage of the literature is given and some suggestions on where the field is likely to advance in the future are discussed.

/pdf/review-current-international-research-into-cellulose-vduhai1vrx.pdf

Review: current international research into cellulose nanofibres and nanocomposites

Hexagonal ferrites: A review of the synthesis, properties and applications of hexaferrite ceramics

The numerical implementation of the model of brittle fracture developed in Francfort and Marigo (1998. J. Mech. Phys. Solids 46 (8), 1319–1342) is presented. Various computational methods based on variational approximations of the original functional are proposed. They are tested on several antiplanar and planar examples that are beyond the reach of the classical computational tools of fracture mechanics.

Numerical experiments in revisited brittle fracture

The bending behavior of unidirectional singly curved sandwich panels with a ‘‘soft’’ core and delaminated (debonded) zones or slipping layers is described herein. The delaminated zone is assumed to exist through the width of the panels, and is in the form of an interfacial debonded zone at one of the face–core interfaces, thus subdividing the length of the panel into three zones, i.e. two fully bonded zones and one that is debonded (delaminated). The formulation uses an interfacial spring description, i.e. distributed shear and radial normal springs at the face–core interfaces, to model the effects of the slipping layers and the various delaminated (debonded) zones. The formulation is based on a closed-form high-order approach (HSAPT) that incorporates the high-order effects of the ‘‘soft’’ core. The variational approach is used to derive the governing equations along with the general explicit boundary and continuity conditions. A typical curved sandwich panel with an inner or an edge delamination, with o...

High-Order Bending Analysis of Unidirectional Curved ‘‘Soft’’ Sandwich Panels with Disbonds and Slipping Layers

Torsional vibrations of layered composite paraboloidal shells

Optimal stacking sequences of composite faces for various sandwich panels and loads to attain minimum weight

A snap-off blade knife having a handle including a proximal portion, a distal portion, and a handle axis extending between the proximal portion and the distal portion is disclosed. The knife also includes a blade slidingly disposed within the handle along the handle axis. The blade comprises a plurality of scored segments. A blade stop fixedly extends from the distal portion of the handle. The blade stop includes a stop arm disposed to engage blade to limit extension of the blade from the handle. A kit comprising the snap-off knife and a blade segment snap-off tool is also disclosed.

Snap-off blade knife with safety stop

Solutions of the governing equations for truncated conical shells are developed for stress couples and transverse shear resultants at each end of the shell. Because of the rapid dissipation of the ...

Jack R. Vinson

Papers

High-Order Bending Analysis of Unidirectional Curved ‘‘Soft’’ Sandwich Panels with Disbonds and Slipping Layers

Torsional vibrations of layered composite paraboloidal shells

Optimal stacking sequences of composite faces for various sandwich panels and loads to attain minimum weight

Snap-off blade knife with safety stop

Edge Load Solutions for Conical Shells