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Showing papers by "Jacques E. Guerchais published in 1995"

Journal Article•DOI•
Radical cation-radical anion salts: Molybdenum complexes containing the [TCNQ]•− or [TCNE]•− radical anions. X-ray crystal structure of [Mo(Et2NCS2)4](TCNQ)

[...]

Marc Decoster1, Françoise Conan1, Jacques E. Guerchais1, Y. Le Mest1, J. Sala Pala1, John C. Jeffery2, Eric Faulques, A. Leblanc, P. Molinie •
University of Western Brittany1, University of Bristol2
01 Jul 1995-Polyhedron
TL;DR: In this article, cyclic voltammetry and ESR studies revealed the presence for all types of complexes of the molybdenum(V) radical cation [Mo(dtc) 4 ] •− which is associated with the radical anion TCNX •− in 2 (X = Q) and 4(X = E) and with a 1:1 mixture of neutral and anionic TCNQ species in 3.

26 citations

Journal Article•DOI•
Determination of charge transfer in molybdenum complexes of 7,7,8,8-tetracyano-p-quinodimethane with vibrational spectroscopy

[...]

Eric Faulques1, A. Leblanc, P. Molinie1, Marc Decoster2, Françoise Conan2, Jacques E. Guerchais2, Jean Sala-Pala2 •
University of Nantes1, University of Western Brittany2
01 May 1995-Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy
TL;DR: In this article, the influence of charge transfer on the vibrational lines of three molybdenum TCNQ complexes [MoO(dtc)3](TCNQ) 1a, [Mo O(t2NCS2) 2a, and [Mo(ttc)4](tccnQ)2 3a) is reported.

19 citations