J
James S. Vrentas
Researcher at Pennsylvania State University
Publications - 164
Citations - 5674
James S. Vrentas is an academic researcher from Pennsylvania State University. The author has contributed to research in topics: Diffusion (business) & Diffusion. The author has an hindex of 37, co-authored 164 publications receiving 5434 citations. Previous affiliations of James S. Vrentas include Illinois Institute of Technology & Dow Chemical Company.
Papers
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Diffusion in polymer—solvent systems. I. Reexamination of the free-volume theory
James S. Vrentas,J. L. Duda +1 more
TL;DR: In this paper, the free-volume theory describing diffusion in polymer-solvent systems is reexamined and conditions under which the mutual diffusion coefficient can be deduced solely from free volume considerations are clarified, and a more general version of the free volume diffusion theory proposed by Fujita is presented.
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Diffusion in polymer-solvent systems. II. A predictive theory for the dependence of diffusion coefficients on temperature, concentration, and molecular weight
James S. Vrentas,J. L. Duda +1 more
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A Deborah number for diffusion in polymer‐solvent systems
TL;DR: In this article, a Deborah number is introduced as a means of characterizing diffusional transport in amorphous polymer-solvent systems, and two types of temperature-penetrant concentration diagrams are constructed, and the various regions on these figures are identified by their Deborah number values.
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Prediction of diffusion coefficients for polymer‐solvent systems
TL;DR: In this article, a free-volume theory of polymer-solvent diffusion coefficients is proposed and evaluated using experimental diffusivity data collected over wide temperature and concentration ranges, showing that the theory accurately predicts the large temperature variations typically observed for polymer solvents diffusion coefficients.
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Molecular diffusion in polymer solutions
James S. Vrentas,J. Larry Duda +1 more
TL;DR: In this paper, methods for estimating mutual diffusion coefficients for polymer-solvent systems are reviewed and procedures are recommended for the determination of the temperature, concentration, and molecular weight dependences of diffusivities both for dilute and concentrated solutions.