Summary Trace-element data for mid-ocean ridge basalts (MORBs) and ocean island basalts (OIB) are used to formulate chemical systematics for oceanic basalts. The data suggest that the order of trace-element incompatibility in oceanic basalts is Cs ≈ Rb ≈ (≈ Tl) ≈ Ba(≈ W) > Th > U ≈ Nb = Ta ≈ K > La > Ce ≈ Pb > Pr (≈ Mo) ≈ Sr > P ≈ Nd (> F) > Zr = Hf ≈ Sm > Eu ≈ Sn (≈ Sb) ≈ Ti > Dy ≈ (Li) > Ho = Y > Yb. This rule works in general and suggests that the overall fractionation processes operating during magma generation and evolution are relatively simple, involving no significant change in the environment of formation for MORBs and OIBs. In detail, minor differences in element ratios correlate with the isotopic characteristics of different types of OIB components (HIMU, EM, MORB). These systematics are interpreted in terms of partial-melting conditions, variations in residual mineralogy, involvement of subducted sediment, recycling of oceanic lithosphere and processes within the low velocity zone. Niobium data indicate that the mantle sources of MORB and OIB are not exact complementary reservoirs to the continental crust. Subduction of oceanic crust or separation of refractory eclogite material from the former oceanic crust into the lower mantle appears to be required. The negative europium anomalies observed in some EM-type OIBs and the systematics of their key element ratios suggest the addition of a small amount (⩽1% or less) of subducted sediment to their mantle sources. However, a general lack of a crustal signature in OIBs indicates that sediment recycling has not been an important process in the convecting mantle, at least not in more recent times (⩽2 Ga). Upward migration of silica-undersaturated melts from the low velocity zone can generate an enriched reservoir in the continental and oceanic lithospheric mantle. We propose that the HIMU type (eg St Helena) OIB component can be generated in this way. This enriched mantle can be re-introduced into the convective mantle by thermal erosion of the continental lithosphere and by the recycling of the enriched oceanic lithosphere back into the mantle.

Chemical and isotopic systematics of oceanic basalt : implications for mantle composition and processes

Chemical and isotopic systematics of oceanic basalts. Implications for Mantle Composition and Processes

The composition of the Earth

The composition of the continental crust

We report here the results of a study to develop natural zircon geochemical standards for calibrating the U-(Th)-Pb geochronometer and Hf isotopic analyses. Additional data were also collected for the major, minor and trace element contents of the three selected sample sets. A total of five large zircon grains (masses between 0.5 and 238 g) were selected for this study, representing three different suites of zircons with ages of 1065 Ma, 2.5 Ma and 0.9 Ma. Geochemical laboratories can obtain these materials by contacting Geostandards Newsletter.

Three natural zircon standards for u‐th‐pb, lu‐hf, trace element and ree analyses

Archean granulite terrains are generally dominated by charnockite-enderbite suites. These rocks are geochemically similar to the tonalite-trondhjemite-granodiorite (TTG) gneisses of Archean cratons. Following an open-system fractional crystallization model for formation of TTG crust through solidification from a shallow-level tonalitic magma ocean, we propose that such granulites could have formed by crystallization at depth at the base of the same magma layer, which is undergoing convection. Increasing solubilities with depth of fluids in a magma mean that the base of a thick convecting magma layer will be undersaturated with respect to H 2 O and CO 2 . This allows the formation of charnockitic assemblages. Crystallization at depth can involve the reverse of dehydration-melting reactions; e.g., producing biotite and quartz at the expense of K-feldspar orthopyroxene, and liquid. Such reactions buffer the activity of water but not of CO 2 during crystallization; hence, fluids exsolved during progressive solidification are likely to be CO 2 -rich.

Can Archean granulites be direct crystallization products from a sialic magma layer

Intracrustal radioactivity as an important heat source for Neoarchean metamorphism in the Central Zone of the Limpopo Complex

Sub-orbital sea-level change in early MIS 5e: New evidence from the Gulf of Corinth Greece

A Mid-Pleistocene in situ fossil brown hyaena (Parahyaena brunnea) latrine from Gladysvale Cave, South Africa

In situ cosmogenic nuclides are an important tool for quantifying landscape evolution and dating fossil-bearing deposits in the Cradle of Humankind (CoH), South Africa. This technique mainly employs cosmogenic 10-Beryllium (Be-10) in river sediments to estimate denudation rates and the ratio of 26-Aluminium (Al-26) to Be-10 (Al-26/Be-10), to constrain ages of sediment burial. Here, we use Be-10 and Al-26 concentrations in bedrock and soil above the Rising Star Cave (the discovery site of Homo naledi) to constrain the denudation rate and the exposure history of soil on the surface. Apparent Be-10-derived denudation rates obtained from pebble- to cobble-sized clasts and coarse-sand in soil (on average 3.59 +/- 0.27 m/Ma and 3.05 +/- 0.25 m/Ma, respectively) are 2-3 times lower than the bedrock denudation rates (on average 9.46 +/- 0.68 m/Ma). In addition, soil samples yield an average Al-26/Be-10 ratio (5.12 +/- 0.27) that is significantly lower than the surface production ratio of 6.75, which suggests complex exposure histories. These results are consistent with prolonged surface residence of up to 1.5 Ma in vertically mixed soils that are up to 3 m thick. We conclude that the Be-10 concentrations accumulated in soils during the long near-surface residence times can potentially cause underestimation of single-nuclide (Be-10) catchment-wide denudation rates in the CoH. Further, burial ages of cave sediment samples that consist of an amalgamation of sand-size quartz grains could be overestimated if a pre-burial Al-26/Be-10 ratio calculated from the surface production is assumed.

Jan Kramers

Papers

Can Archean granulites be direct crystallization products from a sialic magma layer

Intracrustal radioactivity as an important heat source for Neoarchean metamorphism in the Central Zone of the Limpopo Complex

Sub-orbital sea-level change in early MIS 5e: New evidence from the Gulf of Corinth Greece

A Mid-Pleistocene in situ fossil brown hyaena (Parahyaena brunnea) latrine from Gladysvale Cave, South Africa

Effects of long soil surface residence times on apparent cosmogenic nuclide denudation rates and burial ages in the Cradle of Humankind, South Africa