Jay D. Bass

Bio: Jay D. Bass is an academic researcher from University of Illinois at Urbana–Champaign. The author has contributed to research in topics: Elastic modulus & Bulk modulus. The author has an hindex of 50, co-authored 159 publications receiving 7449 citations. Previous affiliations of Jay D. Bass include École normale supérieure de Lyon.

The Melting Curve of Iron to 250 Gigapascals: A Constraint on the Temperature at Earth's Center

Abstract: The melting curve of iron, the primary constituent of Earth's core, has been measured to pressures of 250 gigapascals with a combination of static and dynamic techniques. The melting temperature of iron at the pressure of the core-mantle boundary (136 gigapascals) is 4800 ± 200 K. whereas at the inner core-outer core boundary (330 gigapascals), it is 7600 ± 500 K. Corrected for melting point depression resulting from the presence of impurities, a melting temperature for iron-rich alloy of 6600 K at the inner core-outer core boundary and a maximum temperature of 6900 K at Earth's center are inferred. This latter value is the first experimental upper bound on the temperature at Earth's center, and these results imply that the temperature of the lower mantle is significantly less than that of the outer core.

Mineralogy and composition of the upper mantle

Abstract: Seismic velocities are calculated for two petrological models of the upper mantle, an olivine-rich assemblage, pyrolite, and a garnet-clinopyroxene rich, olivine bearing, assemblage, piclogite. These are compared with recent seismic profiles for various tectonic provinces. The shield data is most consistent with a cold olivine and orthopyroxene-rich LID (the seismic lithosphere) extending to 150 km followed by a high temperature gradient and/or a change in mineralogy that serves to decrease the velocity. From 200 to 400 km the velocities follow a 1400°C adiabat. The rise-tectonic mantle is much slower, presumably hotter and is likely to be above the solidus to depths of at least 300 km. The high V_p/V_s ratio of the lower oceanic lithosphere in the western Pacific is most consistent with eclogite.

Transition region of the Earth's upper mantle

Abstract: The Earth's mantle is conventionally divided into three major subdivisions: the shallow mantle, the transition region and the lower mantle. High seismic velocity gradients extend from 400 km, the top of the transition region, to ~800 km. The relatively homogeneous part of the lower mantle starts near 800 km and extends to within several hundred kilometres of the core-mantle boundary. Major changes in mantle mineralogy occur near 400 and 650 km (refs 2-6). The question of whether these represent equilibrium phase boundaries in a homogeneous mantle or changes in chemistry is fundamental to many problems in earth sciences. There is abundant evidence that the Earth as a whole is a differentiated body and is inhomogeneous on many scales. For example, the extreme concentration of trace elements in the continental crust requires efficient extraction of these elements from all or most of the mantle. Nonetheless, the chemistry of the mantle remains a controversial issue which can be reduced to three basic questions: (1) is the mantle homogeneous in composition or is it chemically stratified? (2) Is the major-element chemistry of the mantle more similar to upper mantle peridotites or to chondrites? (3) What is the composition of the source region of basalts erupted at mid-ocean ridges? We address each of these questions using data from cosmochemistry, geochemistry, petrology, seismology and mineral physics.

An internally consistent thermodynamic data set for phases of petrological interest

Abstract: The thermodynamic properties of 154 mineral end-members, 13 silicate liquid end-members and 22 aqueous fluid species are presented in a revised and updated data set. The use of a temperature-dependent thermal expansion and bulk modulus, and the use of high-pressure equations of state for solids and fluids, allows calculation of mineral–fluid equilibria to 100 kbar pressure or higher. A pressure-dependent Landau model for order–disorder permits extension of disordering transitions to high pressures, and, in particular, allows the alpha–beta quartz transition to be handled more satisfactorily. Several melt end-members have been included to enable calculation of simple phase equilibria and as a first stage in developing melt mixing models in NCKFMASH. The simple aqueous species density model has been extended to enable speciation calculations and mineral solubility determination involving minerals and aqueous species at high temperatures and pressures. The data set has also been improved by incorporation of many new phase equilibrium constraints, calorimetric studies and new measurements of molar volume, thermal expansion and compressibility. This has led to a significant improvement in the level of agreement with the available experimental phase equilibria, and to greater flexibility in calculation of complex mineral equilibria. It is also shown that there is very good agreement between the data set and the most recent available calorimetric data.

An internally consistent thermodynamic data set for phases of petrological interest

Abstract: The thermodynamic properties of 154 mineral end-members, 13 silicate liquid end-members and 22 aqueous fluid species are presented in a revised and updated data set. The use of a temperature-dependent thermal expansion and bulk modulus, and the use of high-pressure equations of state for solids and fluids, allows calculation of mineral-fluid equilibria to 100 kbar pressure or higher. A pressure-dependent Landau model for order-disorder permits extension of disordering transitions to high pressures, and, in particular, allows the alpha-beta quartz transition to be handled more satisfactorily. Several melt end- members have been included to enable calculation of simple phase equilibria and as a first stage in developing melt mixing models in NCKFMASH. The simple aqueous species density model has been extended to enable speciation calculations and mineral solubility determination involving minerals and aqueous species at high temperatures and pressures. The data set has also been improved by incorporation of many new phase equilibrium constraints, calorimetric studies and new measurements of molar volume, thermal expansion and compressibility. This has led to a significant improvement in the level of agreement with the available experimental phase equilibria, and to greater flexibility in calculation of complex mineral equilibria. It is also shown that there is very good agreement between the data set and the most recent available calorimetric data. kinetics which apply to determining directly the greatest majority of such equilibria in the laboratory, for forming solid solutions, and inclusion of aqueous and silicate melt species), and provides uncertainties especially at lower temperatures, as well as the diYculty of establishing reversals of reactions involving solid allowing the likely uncertainties on the results of thermodynamic calculations to be estimated. This is a solutions. The levels of precision and accuracy required of thermodynamic data in order to be able to forward- critical issue in that calculations using data sets should always involve uncertainty propagation to help evalu- model synthetic and natural mineral assemblages mean that the continuing upgrading and expansion of the ate the results. Because the experimental phase equilib- ria involve overlapping subsets of compositional space, data set by incorporation of new phase equilibrium constraints, calorimetry and new measurements of the derived thermodynamic data are highly correlated, and it is only the inclusion of the correlations which molar volume, thermal expansion and compressibility are more than justified. enables the reliable calculation of uncertainties on mineral reactions to be performed. Earlier work on mineral thermodynamic data sets for rock-forming minerals includes compilations of The thermodynamic data extraction involves using weighted least squares on the diVerent types of data

The Rock Physics Handbook: Tools for Seismic Analysis of Porous Media

Abstract: Preface 1. Basic tools 2. Elasticity and Hooke's law 3. Seismic wave propagation 4. Effective media 5. Granular media 6. Fluid effects on wave propagation 7. Empirical relations 8. Flow and diffusion 9. Electrical properties Appendices.

An improved and extended internally consistent thermodynamic dataset for phases of petrological interest, involving a new equation of state for solids

Abstract: The thermodynamic properties of 254 end-members, including 210 mineral end-members, 18 silicate liquid end-members and 26 aqueous fluid species are presented in a revised and updated internally consistent thermodynamic data set. The PVT properties of the data set phases are now based on a modified Tait equation of state (EOS) for the solids and the Pitzer & Sterner (1995) equation for gaseous components. Thermal expansion and compressibility are linked within the modified Tait EOS (TEOS) by a thermal pressure formulation using an Einstein temperature to model the temperature dependence of both the thermal expansion and bulk modulus in a consistent way. The new EOS has led to improved fitting of the phase equilibrium experiments. Many new end-members have been added, including several deep mantle phases and, for the first time, sulphur-bearing minerals. Silicate liquid end-members are in good agreement with both phase equilibrium experiments and measured heat of melting. The new dataset considerably enhances the capabilities for thermodynamic calculation on rocks, melts and aqueous fluids under crustal to deep mantle conditions. Implementations are already available in thermocalc to take advantage of the new data set and its methodologies, as illustrated by example calculations on sapphirine-bearing equilibria, sulphur-bearing equilibria and calculations to 300 kbar and 2000 °C to extend to lower mantle conditions.