Author
Jean Sala-Pala
Other affiliations: University of Barcelona
Bio: Jean Sala-Pala is an academic researcher from University of Western Brittany. The author has contributed to research in topics: Cyclopentadienyl complex & Denticity. The author has an hindex of 18, co-authored 50 publications receiving 923 citations. Previous affiliations of Jean Sala-Pala include University of Barcelona.
Topics: Cyclopentadienyl complex, Denticity, Ligand, Annulene, Niobium
Papers
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TL;DR: In this paper, neutral cationic complexes were formed from [Nb(η-C5H5)2(Bu)[η2-CS2]-(1) and RX (R = Me, Et, i-Pr, CH2COOEt; X = I).
12 citations
10 citations
TL;DR: In this article, the infrared spectra of the three compounds {VO2F(AA) and {VOF3L2} showed two strong absorptions (in the 800-950 cm−1 region) which are likely to arise from vs and vas(VO2).
10 citations
TL;DR: Several aspects of the chemistry of the previously reported dinuclear molybdenum(II) complexes, in which the substituted dibenzotetraaza[14] annulene ligand adopts its usual tetradentate coordination mode, have been developed as mentioned in this paper.
Abstract: Several aspects of the chemistry of the previously reported dinuclear molybdenum(II) complexes ([{Mo(R 2 C 22 H 20 N 4 )} 2 ]), in which the substituted dibenzotetraaza[14] annulene ligand adopts its usual tetradentate coordination mode, have been developed
10 citations
TL;DR: In this paper, the spin Hamiltonian parameters of paramagnetic niobium complexes are compared with the atomic orbital coefficients in the ground state molecular orbital involved in bonding, showing that the unpaired electron lies essentially in the 4dx2−y2 metal ion orbital mixed with a small amount of the corresponding metal ion 4dz2 orbital, the z axis coinciding with the C2 axis of the compound.
9 citations
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TL;DR: Metal Oxides Generated in Situ 2461 4.1.
Abstract: 3. Soluble Metal Oxides 2459 3.1. Polyoxometalates 2459 3.2. Peroxotungstates 2459 3.3. Peroxomolybdates 2460 3.4. Methyltrioxorhenium 2461 3.5. Other Metal Oxides 2461 4. Metal Oxides Generated in Situ 2461 4.1. Selenium and Arsenic Compounds 2461 4.2. Simple Metal Salts 2462 5. Coordination Complexes 2463 5.1. Manganese Porphyrins 2463 5.2. Iron Porphyrins 2464 5.3. Manganese Salen Complexes 2466 5.4. 1,4,7-Triazacyclononane (TACN) Complexes 2466 5.5. Iron and Manganese Pyridyl-Amine Complexes 2468
984 citations
722 citations
TL;DR: The factor that controls the activity of these chelates is not fully understood but parameters such as redox potentials of the metal and electronic structure appear to be crucial as discussed by the authors.
499 citations
TL;DR: The reaction chemistry of nitriles with transition metal complexes is reviewed in this paper, where the authors survey data published during the period 1977-early 1994 on new reaction processes such as insertion into metal-hydrogen and carbon bonds, coupling between one nitrile and an unsaturated metal fragment, reduction to amines, attack by protic and aprotic nucleophiles and electrophilic attack as well as some catalytic transformations.
427 citations
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425 citations