Author
Jean Sala-Pala
Other affiliations: University of Barcelona
Bio: Jean Sala-Pala is an academic researcher from University of Western Brittany. The author has contributed to research in topics: Cyclopentadienyl complex & Denticity. The author has an hindex of 18, co-authored 50 publications receiving 923 citations. Previous affiliations of Jean Sala-Pala include University of Barcelona.
Topics: Cyclopentadienyl complex, Denticity, Ligand, Annulene, Niobium
Papers
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TL;DR: The authors derives thiamolybdatricyclodecatriene a partir de bis-trifluoromethyl-4,5 di-η 5 -cyclopentadienyl-3,3 thioxo-2 thia-1molybda-3 cyclopentene-4 dicarboxylate 4,5 de dimethyle et d'iodomethane
2 citations
TL;DR: Auteurs etudient as discussed by the authors propose a formule simplificatrice for le calcul des coefficients des divers monomes lors du developpement des indices de cycle.
2 citations
TL;DR: Alkynes react with [Mo(η5-C5H5)2 (η2-CS2)](1) to afford heterocycle derivatives as discussed by the authors, while treatment of (1) with HCC-CN gives an unprecedented metallacycle.
Abstract: Alkynes react with [Mo(η5-C5H5)2(η2-CS2)](1) to afford heterocycle derivatives [(η5-C5H5)2[graphic omitted]R][(2) R = CF3; (3) R = CO2Me] and [(η5-C5H5)2[graphic omitted]R][(4) R = CO2Me], and both (2) and (3) react with HCC–CN to yield [(η5-C5H5)[graphic omitted]R}][(5) R = CO2Me; (6) R = CF3], while treatment of (1) with HCC–CN gives an unprecedented metallacycle [(η5-C5H5)2Mo(C10H3N3S2)](7), corresponding to the addition of three alkynes to CS2; the structures of (4), (5), and (7) have been established by X-ray crystallography.
1 citations
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TL;DR: Metal Oxides Generated in Situ 2461 4.1.
Abstract: 3. Soluble Metal Oxides 2459 3.1. Polyoxometalates 2459 3.2. Peroxotungstates 2459 3.3. Peroxomolybdates 2460 3.4. Methyltrioxorhenium 2461 3.5. Other Metal Oxides 2461 4. Metal Oxides Generated in Situ 2461 4.1. Selenium and Arsenic Compounds 2461 4.2. Simple Metal Salts 2462 5. Coordination Complexes 2463 5.1. Manganese Porphyrins 2463 5.2. Iron Porphyrins 2464 5.3. Manganese Salen Complexes 2466 5.4. 1,4,7-Triazacyclononane (TACN) Complexes 2466 5.5. Iron and Manganese Pyridyl-Amine Complexes 2468
984 citations
722 citations
TL;DR: The factor that controls the activity of these chelates is not fully understood but parameters such as redox potentials of the metal and electronic structure appear to be crucial as discussed by the authors.
499 citations
TL;DR: The reaction chemistry of nitriles with transition metal complexes is reviewed in this paper, where the authors survey data published during the period 1977-early 1994 on new reaction processes such as insertion into metal-hydrogen and carbon bonds, coupling between one nitrile and an unsaturated metal fragment, reduction to amines, attack by protic and aprotic nucleophiles and electrophilic attack as well as some catalytic transformations.
427 citations
TL;DR: In case of a legitimate complaint, the Library will make the material inaccessible and/or remove it from the website as discussed by the authors, in case of legitimate complaints the material will be removed.
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425 citations