Author
Jia-Yi Chen
Bio: Jia-Yi Chen is an academic researcher from Shantou University. The author has co-authored 1 publications.
Papers
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TL;DR: In this paper, an electrochemically driven, Rh(III)-catalyzed regioselective annulations of arenes with alkynes have been established, combining the use of a rhodium catalyst with electricity, not only avoiding the need for using a stoichiometric amount of external oxidant, but also enabling broad functional group compatibility with a variety of substrates, including drugs and pharmaceutical motifs.
9 citations
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TL;DR: An electrochemical protocol for the synthesis of 2,3 disubstituted quinolines by reacting benzoxazinones with arylsulfonyl hydrazides was established under simple and mild conditions (room temperature and an undivided cell) as discussed by the authors .
8 citations
TL;DR: In this paper , an electrochemical protocol for the selective oxidation of sulfides to sulfoxides has been developed in which NaCl plays a dual role: (1) as an electrolyte for the electrochemical transformations and (2) as a redox mediator to avoid oxidation of sensitive functional groups.
5 citations
TL;DR: A rhodium-catalyzed electrochemical regioselective annulation of 6-phenylpurines and 7-deazapurinium with alkynes has been developed in this paper .
5 citations
TL;DR: In this paper , an approach for the synthesis of benzothiophene motifs under electrochemical conditions by the reaction of sulfonhydrazides with internal alkynes was reported.
Abstract: We report an approach for the synthesis of benzothiophene motifs under electrochemical conditions by the reaction of sulfonhydrazides with internal alkynes. Upon the formation of a quaternary spirocyclization intermediate by the selective ipso-addition instead of an ortho-attack, the S-migration process was rationalized to lead to the products. Computational studies revealed the selectivity and the compatibility of drug molecules showcased the potential application of the protocols.
4 citations
TL;DR: In this paper , an electrochemical protocol for the synthesis of α-thiocyanato-α-carbonyl sulfoxonium ylides via C H thIocyanation by reacting sulfoxide compounds with potassium thIOCyanate was established under simple and mild conditions.
1 citations