Photoluminescent carbon nanoparticles, or carbon dots, are an emerging class of materials that has recently attracted considerable attention for biomedical and energy applications. They are defined by characteristic sizes of <10 nm, a carbon-based core and the possibility to add various functional groups at their surface for targeted applications. These nanomaterials possess many interesting physicochemical and optical properties, which include tunable light emission, dispersibility and low toxicity. In this Review, we categorize how chemical tools impact the properties of carbon dots. We look for pre- and postsynthetic approaches for the preparation of carbon dots and their derivatives or composites. We then showcase examples to correlate structure, composition and function and use them to discuss the future development of this class of nanomaterials. This Review discusses synthetic strategies to functionalize photoluminescent carbon nanomaterials, or carbon dots, for targeted applications. 

https://zenodo.org/record/6961902/files/NatNanotechnol_Zenodo.pdf

A multifunctional chemical toolbox to engineer carbon dots for biomedical and energy applications

The light of carbon dots: From mechanism to applications

Multicolor bandgap fluorescent carbon quantum dots (MCBF-CQDs) from blue to red with quantum yield up to 75% are synthesized using a solvothermal method. For the first time, monochrome electroluminescent light-emitting diodes (LEDs) with MCBF-CQDs directly as an active emission layer are fabricated. The maximum luminance of blue LEDs reaches 136 cd m-2 , which is the best performance for CQD-based monochrome electroluminescent LEDs.

Bright Multicolor Bandgap Fluorescent Carbon Quantum Dots for Electroluminescent Light-Emitting Diodes

Light-emitting chiral carbonized polymer dots (Ch-CPDs) are attracting great interest because of their extraordinary photonic properties, but modulating their band-gap emission, especially at long wavelength, and maintaining their chiral structure to achieve multicolor, high-emission Ch-CPDs remains challenging. Reported here for the first time is the synthesis of red- and multicolor-emitting Ch-CPDs using the common precursors L-/D-tryptophan and o-phenylenediamine, and a solvothermal approach at one temperature. The quantum yield of the Ch-CPDs was between 31 % and 54 %. Supramolecular self-assembly provided multicolor-emitting Ch-CPDs showing novel circularly polarized luminescence, with the highest dissymmetric factor (glum ) of 1×10-2 . Importantly, circularly polarized white-emitting CPDs were fabricated for the first time by tuning the mixing ratio of the three colored Ch-CPDs in a gel. This strategy affords exciting opportunities for designing functional chiroptical materials.

Rational Design of Multicolor-Emitting Chiral Carbonized Polymer Dots for Full-Color and White Circularly Polarized Luminescence

The synthetic strategies, photoluminescence mechanisms and promising applications of carbon dots: Current state and future perspective

As an emerging building unit, carbon dots (CDs) have been igniting the revolutionaries in the fields of optoelectronics, biomedicine, and bioimaging. However, the difficulty of synthesizing CDs in aqueous solution with full-spectrum emission severely hinders further investigation of their emission mechanism and their extensive applications in white light emitting diodes (LEDs). Here, the full-color-emission CDs with a unique structure consisting of sp3-hybridized carbon cores with small domains of partially sp2-hybridized carbon atoms are reported. First-principle calculations are initially used to predict that the transformation from sp3 to sp2 hybridization redshifts the emission of CDs. Guided by the theoretical predictions, a simple, convenient, and controllable route to hydrothermally prepare CDs in a single reaction system is developed. The prepared CDs have full-spectrum emission with an unprecedented two-photon emission across the whole visible color range. These full-color-emission CDs can be further nurtured by slight modifications of the reaction conditions (e.g., temperature, pH) to generate the emission color from blue to red. Finally a flexible LEDs with full-color emission by using epoxy CDs films is developed, indicating that the strategy affords an industry translational potential over traditional fluorophores.

https://onlinelibrary.wiley.com/doi/pdf/10.1002/advs.202001453

Rational Design of Multi-Color-Emissive Carbon Dots in a Single Reaction System by Hydrothermal.

Carbon dots (CDs) have excellent luminescence characteristics, such as good light stability, high quantum yield (QY), long phosphorescence lifetime, and a wide emission wavelength range, resulting in CDs' great success in optical applications. Understanding the structure-property relationships in CDs is essential for their use in optoelectronic applications. However, because of the complex nature of CD structures and synthesis processes, understanding the luminescence mechanism and structure-property relationships of CDs is a big challenge. This Perspective reviews the theoretical efforts toward the understanding of structure-property relationships and discusses the challenges that need to be overcome in future development of CDs.

Theoretical Understanding of Structure-Property Relationships in Luminescence of Carbon Dots.

Miniaturized solid-state lasers with a single longitudinal mode are vital for various photonic applications. Here we prepare red-emissive carbon dots (CDs) with a photoluminescence quantum yield (PLQY) of 65.5 % by combining graphitic nitrogen doping and surface modification. High-concentration doping alters the CDs' emission from blue to red, while the electron-donating groups and polymer coating on their surfaces improve the PLQY and photostability. The CDs exhibit excellent stimulated emission characteristics, with a low threshold of amplified spontaneous emission (ASE) and long gain lifetime. A planar microcavity with only one resonant mode, which fitted with the CDs' ASE peak, was constructed. Combining the CDs and microcavity produced a solid-state laser with a single longitudinal mode, a linewidth of 0.14 nm and a signal-to-noise ratio of 14.8 dB (Q∼4600). Our results will aid the development of colorful solid-state micro/nano lasers with potential use in practical photonics.

Solid-State Red Laser with a Single Longitudinal Mode from Carbon Dots

Tunable emission carbonized polymer dots (CPDs) are highly desirable for the preparation of optoelectronic devices, especially white light-emitting diodes (WLEDs). In most available studies, polychromatic CPDs are synthesized using aromatic molecules as precursors. However, few studies report the successful synthesis of polychromatic CPDs using two or more unconjugated precursors. In this work, we prepare multicolor fluorescent CPDs from a single unconjugated precursor, glucose, via a hydrothermal reaction. By controlling the particle size and degree of graphitization of the synthesized CPDs, their emission wavelength can be tuned in the range 440-625 nm (i.e., almost the entire visible region). Furthermore, the CPDs can be used to construct LEDs of varying colors, including WLEDs (CIE coordinates: 0.34, 0.36) with the correlated color temperature and color rendering index of 4997 K and 92.69, respectively. In brief, the strategy proposed in this study successfully converts unconjugated glucose into high-performance LEDs with great application potential.

Facile Synthesis of Water-Stable Multicolor Carbonized Polymer Dots from a Single Unconjugated Glucose for Engineering White Light-Emitting Diodes with a High Color Rendering Index.

Jingkun Yu

Papers

Rational Design of Multi-Color-Emissive Carbon Dots in a Single Reaction System by Hydrothermal.

Theoretical Understanding of Structure-Property Relationships in Luminescence of Carbon Dots.

Solid-State Red Laser with a Single Longitudinal Mode from Carbon Dots

Facile Synthesis of Water-Stable Multicolor Carbonized Polymer Dots from a Single Unconjugated Glucose for Engineering White Light-Emitting Diodes with a High Color Rendering Index.

Computational Studies on Carbon Dots Electrocatalysis: A Review