Author
John E. Huber
Other affiliations: University of Cambridge
Bio: John E. Huber is an academic researcher from University of Oxford. The author has contributed to research in topics: Ferroelectricity & Electric field. The author has an hindex of 20, co-authored 75 publications receiving 2290 citations. Previous affiliations of John E. Huber include University of Cambridge.
Papers published on a yearly basis
Papers
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TL;DR: In this paper, a method is presented for selecting the type of actuator best suited to a given task, in the early stages of engineering design, based on matching performance characteristics of the actuator, such as force and displacement, to the requirements of the given task.
Abstract: A method is presented for selecting the type of actuator best suited to a given task, in the early stages of engineering design. The selection is based on matching performance characteristics of the actuator, such as force and displacement, to the requirements of the given task. The performance characteristics are estimated from manufacturers9 data and from simple models of performance limitation such as heat generation and resonance. Characteristics are presented in a graphical form which allows for a direct and systematic comparison of widely different systems of actuation. The actuators considered include man-made actuators (such as hydraulic, solenoid and shape memory alloy) and naturally occurring actuators (such as the muscles of animals and plants).
514 citations
TL;DR: In this paper, a constitutive model for the non-linear switching of ferroelectric polycrystals under a combination of mechanical stress and electric field is developed for nonlinear switching, where the switching event, which converts one crystal variant into another, gives rise to a progressive change in remanent strain and polarisation.
Abstract: A constitutive model is developed for the non-linear switching of ferroelectric polycrystals under a combination of mechanical stress and electric field. It is envisaged that the polycrystal consists of a set of bonded crystals and that each crystal comprises a set of distinct crystal variants. Within each crystal the switching event, which converts one crystal variant into another, gives rise to a progressive change in remanent strain and polarisation and to a change in the average linear electromechanical properties. It is further assumed that switching is resisted by the dissipative motion of domain walls. The constitutive model for the progressive switching of each crystal draws upon elastic–plastic crystal plasticity theory, and a prescription is given for the tangent moduli of the crystal, for any assumed set of potentially active transformation systems. A self-consistent analysis is used to estimate the macroscopic response of tetragonal crystals (representative of lead titanate) under a variety of loading paths. Also, the evolution of the switching surface in stress-electric field space is calculated. Many of the qualitative features of ferroelectric switching, such as butterfly hysteresis loops, are predicted by the analysis.
388 citations
TL;DR: In this article, a self-consistent polycrystalline ferroelectric ceramic PZT-5H was poled by applying an electric field at room temperature, and the measured non-linear responses in electric displacement were used to construct yield surfaces.
Abstract: Samples of the polycrystalline ferroelectric ceramic PZT-5H were poled by applying an electric field at room temperature. Subsequently, an electric field was applied to the samples at a range of angles to the poling direction. The measured non-linear responses in electric displacement are used to construct “yield surfaces” in electric field space corresponding to the onset of ferroelectric switching. The results are compared with predictions from three models: (i) a previous self-consistent polycrystal calculation with rate-independent, non-hardening crystal plasticity; (ii) a simplified crystal plasticity model with viscoplastic (rate-dependent) behaviour and a sufficient number of transformation systems to reproduce the polycrystalline behaviour; (iii) a phenomenological model based on rate-independent flow theory, using kinematic hardening and a quadratic yield surface in electric field and stress space. The experiments suggest that the self-consistent crystal plasticity formulation is most able to reproduce the multi-axial electrical response and yield surface of the polycrystal. The phenomenological model is able to reproduce the uniaxial response accurately, but gives relatively poor performance for multi-axial loading paths, in its present form. A tolerable compromise in multi-axial modelling is the simplified crystal plasticity approach. This is able to reproduce multi-axial constitutive behaviour with reasonable accuracy, whilst offering computational simplicity and speed similar to that of the phenomenological model.
246 citations
TL;DR: In this paper, a polarization switching model for polycrystalline ferroelectric ceramics was developed, in which a single ferro-electric crystallite in a ceramic, which is subjected to an electric field and/or a stress, undergoes a complete polarization change and a corresponding strain change if the resulting reduction in potential energy exceeds a critical value per unit volume of switching material.
Abstract: A polarization switching model for polycrystalline ferroelectric ceramics has been developed. It is assumed that a single ferroelectric crystallite in a ceramic, which is subjected to an electric field and/or a stress, undergoes a complete polarization change and a corresponding strain change if the resulting reduction in potential energy exceeds a critical value per unit volume of switching material. The crystallite’s switch causes a change in the interaction of its field and stress with the surrounding crystallites, which is modeled by the Eshelby inclusion method to provide a mean field estimate of the effect. Thus the model accounts for the effects of the mean electric and stress fields arising from the constraints presented by surrounding crystallites as well as the externally applied mechanical and electrical loads. The switching response of the ceramic polycrystal is obtained by averaging over the behavior of a large number of randomly oriented crystallites. The model, along with the linear dielect...
191 citations
TL;DR: In this article, a systematic method is developed to select the most appropriate sensor for a particular application, based on a wide range of candidate sensors exist, and many are based on coupled electrical and mechanical phenomena such as the piezoelectric, magnetostrictive and pyroelectric effects.
Abstract: A systematic method is developed to select the most appropriate sensor for a particular application. A wide range of candidate sensors exist, and many are based on coupled electrical and mechanical phenomena, such as the piezoelectric, magnetostrictive and the pyro-electric effects. Performance charts for sensors are constructed from suppliers data for commercially available devices. The selection of an appropriate sensor is based on matching the operating characteristics of sensors to the requirements of an application. The final selection is aided by additional considerations such as cost, and impedance matching. Case studies illustrate the selection procedure.
126 citations
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TL;DR: A number of materials have been explored for their use as artificial muscles, but dielectric elastomers appear to provide the best combination of properties for true muscle-like actuation, and widespread adoption of DEs has been hindered by premature breakdown and the requirement for high voltages and bulky support frames.
Abstract: A number of materials have been explored for their use as artificial muscles Among these, dielectric elastomers (DEs) appear to provide the best combination of properties for true muscle-like actuation DEs behave as compliant capacitors, expanding in area and shrinking in thickness when a voltage is applied Materials combining very high energy densities, strains, and efficiencies have been known for some time To date, however, the widespread adoption of DEs has been hindered by premature breakdown and the requirement for high voltages and bulky support frames Recent advances seem poised to remove these restrictions and allow for the production of highly reliable, high-performance transducers for artificial muscle applications
1,299 citations
TL;DR: π-Conjugated polymers that are electrochemically cycled in ionic liquids have enhanced lifetimes without failure and fast cycle switching speeds and anions such as tetrafluoroborate or hexafluorophosphate showed negligible loss in electroactivity.
Abstract: π-Conjugated polymers that are electrochemically cycled in ionic liquids have enhanced lifetimes without failure (up to 1 million cycles) and fast cycle switching speeds (100 ms). We report results for electrochemical mechanical actuators, electrochromic windows, and numeric displays made from three types of π-conjugated polymers: polyaniline, polypyrrole, and polythiophene. Experiments were performed under ambient conditions, yet the polymers showed negligible loss in electroactivity. These performance advantages were obtained by using environmentally stable, room-temperature ionic liquids composed of 1-butyl-3-methyl imidazolium cations together with anions such as tetrafluoroborate or hexafluorophosphate.
1,092 citations
TL;DR: A new class of all-organic field-type EAP composites is reported, which can exhibit high elastic energy densities induced by an electric field of only 13 V µm-1, and could find applications as artificial muscles, ‘smart skins’ for drag reduction, and in microfluidic systems for drug delivery.
Abstract: Electroactive polymers (EAPs) can behave as actuators, changing their shape in response to electrical stimulation. EAPs that are controlled by external electric fields--referred to here as field-type EAPs--include ferroelectric polymers, electrostrictive polymers, dielectric elastomers and liquid crystal polymers. Field-type EAPs can exhibit fast response speeds, low hysteresis and strain levels far above those of traditional piezoelectric materials, with elastic energy densities even higher than those of piezoceramics. However, these polymers also require a high field (>70 V micro m(-1)) to generate such high elastic energy densities (>0.1 J cm(-3); refs 4, 5, 9, 10). Here we report a new class of all-organic field-type EAP composites, which can exhibit high elastic energy densities induced by an electric field of only 13 V micro m(-1). The composites are fabricated from an organic filler material possessing very high dielectric constant dispersed in an electrostrictive polymer matrix. The composites can exhibit high net dielectric constants while retaining the flexibility of the matrix. These all-organic actuators could find applications as artificial muscles, 'smart skins' for drag reduction, and in microfluidic systems for drug delivery.
992 citations
TL;DR: In this article, high-strength polymer fibers used for fishing line and sewing thread can be easily transformed by twist insertion to provide fast, scalable, nonhysteretic, long-life tensile and torsional muscles.
Abstract: The high cost of powerful, large-stroke, high-stress artificial muscles has combined with performance limitations such as low cycle life, hysteresis, and low efficiency to restrict applications. We demonstrated that inexpensive high-strength polymer fibers used for fishing line and sewing thread can be easily transformed by twist insertion to provide fast, scalable, nonhysteretic, long-life tensile and torsional muscles. Extreme twisting produces coiled muscles that can contract by 49%, lift loads over 100 times heavier than can human muscle of the same length and weight, and generate 5.3 kilowatts of mechanical work per kilogram of muscle weight, similar to that produced by a jet engine. Woven textiles that change porosity in response to temperature and actuating window shutters that could help conserve energy were also demonstrated. Large-stroke tensile actuation was theoretically and experimentally shown to result from torsional actuation.
880 citations
TL;DR: In this paper, the status and perspectives of this new class of actuator ceramics are presented, aiming at covering a wide spectrum of topics, i.e., from fundamentals to practice, and a recent discovery has greatly extended our tool box for material design by furnishing (Bi 1/2Na1/2)TiO3-based (PZT) with a reversible phase transition between an ergodic relaxor state and a ferroelectric with the application of electric field.
Abstract: In response to the current environmental regulations against the use of lead in daily electronic devices, a number of investigations have been performed worldwide in search for alternative piezoelectric ceramics that can replace the market-dominating lead-based ones, representatively Pb(Zr
x
Ti1-x
)O3 (PZT)-based solid solutions. Selected systems of potential importance such as chemically modified and/or crystallographically textured (K, Na)NbO3 and (Bi1/2Na1/2)TiO3-based solid solutions have been developed. Nevertheless, only few achievements have so far been introduced to the marketplace. A recent discovery has greatly extended our tool box for material design by furnishing (Bi1/2Na1/2)TiO3-based ceramics with a reversible phase transition between an ergodic relaxor state and a ferroelectric with the application of electric field. This paired the piezoelectric effect with a strain-generating phase transition and extended opportunities for actuator applications in a completely new manner. In this contribution, we will present the status and perspectives of this new class of actuator ceramics, aiming at covering a wide spectrum of topics, i.e., from fundamentals to practice.
778 citations