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Author

John M. Andresen

Bio: John M. Andresen is an academic researcher from Heriot-Watt University. The author has contributed to research in topics: Jet fuel & Coke. The author has an hindex of 24, co-authored 116 publications receiving 3263 citations. Previous affiliations of John M. Andresen include University of Edinburgh & Pennsylvania State University.
Topics: Jet fuel, Coke, Adsorption, Pyrolysis, Coal


Papers
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Journal ArticleDOI
TL;DR: In this article, a mesoporous molecular sieve of MCM-41 type (MCM41-PEI) has been used as a CO2 adsorbent.
Abstract: The objective of the work presented here is to develop a nanoporous solid adsorbent which can serve as a “molecular basket” for CO2 in the condensed form Polyethylenimine (PEI)-modified mesoporous molecular sieve of MCM-41 type (MCM-41-PEI) has been prepared and tested as a CO2 adsorbent The physical properties of the adsorbents were characterized by X-ray powder diffraction (XRD), N2 adsorption/desorption, and thermogravimetric analysis (TGA) The characterizations indicated that the structure of the MCM-41 was preserved after loading the PEI, and the PEI was uniformly dispersed into the channels of the molecular sieve The CO2 adsorption/desorption performance was tested in a flow system using a microbalance to track the weight change The mesoporous molecular sieve had a synergetic effect on the adsorption of CO2 by PEI A CO2 adsorption capacity as high as 215 mg-CO2/g-PEI was obtained with MCM-41-PEI-50 at 75 °C, which is 24 times higher than that of the MCM-41 and is even 2 times that of the pure

967 citations

Journal ArticleDOI
TL;DR: In this paper, a mesoporous molecular sieve of MCM-41 type with polyethylenimine (PEI) was used for the preparation of CO2 adsorbents.

713 citations

Journal ArticleDOI
TL;DR: In this article, the surface area of olivine and serpentine can be increased to over 330 m 2 /g through surface activation to the extent that such rigorous reaction conditions were not required.

249 citations

Journal ArticleDOI
01 Nov 2002-Polymer
TL;DR: In this paper, the effect of flame retardant (FR) and blowing agents on the thermal stability of rigid polyurethane foams and their resultant chars was investigated using standard flammability test (ASTM, D-3014), solid-state 13C NMR, TGA and Py-GC/MS.

79 citations

Journal ArticleDOI
TL;DR: In contrast to coal and oil shales, char and oil yields from sunflower pressed bagasse were found to be largely independent of particle size and sweep gas velocity in a Heinze retort with the oil yield of ≈ 40% w/w being the same as that from a well-swept fixed-bed reactor as discussed by the authors.

73 citations


Cited by
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Journal ArticleDOI
TL;DR: Kenji Sumida, David L. Rogow, Jarad A. Mason, Thomas M. McDonald, Eric D. Bloch, Zoey R. Herm, Tae-Hyun Bae, Jeffrey R. Long
Abstract: Kenji Sumida, David L. Rogow, Jarad A. Mason, Thomas M. McDonald, Eric D. Bloch, Zoey R. Herm, Tae-Hyun Bae, Jeffrey R. Long

5,389 citations

Journal ArticleDOI
TL;DR: This critical review describes the state-of-the-art development in the design, synthesis, characterisation, and application of the crystalline porous COF materials.
Abstract: Covalent organic frameworks (COFs) represent an exciting new type of porous organic materials, which are ingeniously constructed with organic building units via strong covalent bonds. The well-defined crystalline porous structures together with tailored functionalities have offered the COF materials superior potential in diverse applications, such as gas storage, adsorption, optoelectricity, and catalysis. Since the seminal work of Yaghi and co-workers in 2005, the rapid development in this research area has attracted intensive interest from researchers with diverse expertise. This critical review describes the state-of-the-art development in the design, synthesis, characterisation, and application of the crystalline porous COF materials. Our own opinions on further development of the COF materials are also presented for discussion (155 references).

2,572 citations

Journal ArticleDOI
TL;DR: The CO(2) adsorption behavior of several different classes of solid carbon dioxide adsorbents, including zeolites, activated carbons, calcium oxides, hydrotalcites, organic-inorganic hybrids, and metal-organic frameworks are described.
Abstract: Since the time of the industrial revolution, the atmospheric CO(2) concentration has risen by nearly 35 % to its current level of 383 ppm. The increased carbon dioxide concentration in the atmosphere has been suggested to be a leading contributor to global climate change. To slow the increase, reductions in anthropogenic CO(2) emissions are necessary. Large emission point sources, such as fossil-fuel-based power generation facilities, are the first targets for these reductions. A benchmark, mature technology for the separation of dilute CO(2) from gas streams is via absorption with aqueous amines. However, the use of solid adsorbents is now being widely considered as an alternative, potentially less-energy-intensive separation technology. This Review describes the CO(2) adsorption behavior of several different classes of solid carbon dioxide adsorbents, including zeolites, activated carbons, calcium oxides, hydrotalcites, organic-inorganic hybrids, and metal-organic frameworks. These adsorbents are evaluated in terms of their equilibrium CO(2) capacities as well as other important parameters such as adsorption-desorption kinetics, operating windows, stability, and regenerability. The scope of currently available CO(2) adsorbents and their critical properties that will ultimately affect their incorporation into large-scale separation processes is presented.

2,149 citations

Journal ArticleDOI
TL;DR: In this paper, the fundamental mechanism of heterogeneous photocatalysis, advantages, challenges and the design considerations of g-C3N4-based photocatalysts are summarized, including their crystal structural, surface phisicochemical, stability, optical, adsorption, electrochemical, photoelectrochemical and electronic properties.

2,132 citations