Preface to the Princeton Landmarks in Biology Edition vii Preface xi Symbols Used xiii 1. The Importance of Islands 3 2. Area and Number of Speicies 8 3. Further Explanations of the Area-Diversity Pattern 19 4. The Strategy of Colonization 68 5. Invasibility and the Variable Niche 94 6. Stepping Stones and Biotic Exchange 123 7. Evolutionary Changes Following Colonization 145 8. Prospect 181 Glossary 185 References 193 Index 201

The Theory of Island Biogeography

https://cmapspublic3.ihmc.us/rid=1N3976C22-12M3P49-9V/Holladay%20et%20al.%20-%202009%20-%20An%20overview%20of%20hydrogen%20production%20technologies.pdf

An overview of hydrogen production technologies

Since the time of the industrial revolution, the atmospheric CO(2) concentration has risen by nearly 35 % to its current level of 383 ppm. The increased carbon dioxide concentration in the atmosphere has been suggested to be a leading contributor to global climate change. To slow the increase, reductions in anthropogenic CO(2) emissions are necessary. Large emission point sources, such as fossil-fuel-based power generation facilities, are the first targets for these reductions. A benchmark, mature technology for the separation of dilute CO(2) from gas streams is via absorption with aqueous amines. However, the use of solid adsorbents is now being widely considered as an alternative, potentially less-energy-intensive separation technology. This Review describes the CO(2) adsorption behavior of several different classes of solid carbon dioxide adsorbents, including zeolites, activated carbons, calcium oxides, hydrotalcites, organic-inorganic hybrids, and metal-organic frameworks. These adsorbents are evaluated in terms of their equilibrium CO(2) capacities as well as other important parameters such as adsorption-desorption kinetics, operating windows, stability, and regenerability. The scope of currently available CO(2) adsorbents and their critical properties that will ultimately affect their incorporation into large-scale separation processes is presented.

Adsorbent Materials for Carbon Dioxide Capture from Large Anthropogenic Point Sources

Carbon capture and storage (CCS) is broadly recognised as having the potential to play a key role in meeting climate change targets, delivering low carbon heat and power, decarbonising industry and, more recently, its ability to facilitate the net removal of CO2 from the atmosphere. However, despite this broad consensus and its technical maturity, CCS has not yet been deployed on a scale commensurate with the ambitions articulated a decade ago. Thus, in this paper we review the current state-of-the-art of CO2 capture, transport, utilisation and storage from a multi-scale perspective, moving from the global to molecular scales. In light of the COP21 commitments to limit warming to less than 2 °C, we extend the remit of this study to include the key negative emissions technologies (NETs) of bioenergy with CCS (BECCS), and direct air capture (DAC). Cognisant of the non-technical barriers to deploying CCS, we reflect on recent experience from the UK's CCS commercialisation programme and consider the commercial and political barriers to the large-scale deployment of CCS. In all areas, we focus on identifying and clearly articulating the key research challenges that could usefully be addressed in the coming decade.

/pdf/carbon-capture-and-storage-ccs-the-way-forward-11rgsqyer0.pdf

Carbon capture and storage (CCS): the way forward

This article reviews the progress made in CO2 separation and capture research and engineering. Various technologies, such as absorption, adsorption, and membrane separation, are thoroughly discussed. New concepts such as chemical-looping combustion and hydrate-based separation are also introduced briefly. Future directions are suggested. Sequestration methods, such as forestation, ocean fertilization and mineral carbonation techniques are also covered. Underground injection and direct ocean dump are not covered.

Progress in carbon dioxide separation and capture: a review.

This paper presents the results from biomass gasification tests in a pilot-scale (6.5-m tall × 0.1-m diameter) air-blown circulating fluidized bed gasifier, and compares them with model predictions. The operating temperature was maintained in the range 700–850°C, while the sawdust feed rate varied from 16 to 45 kg/h . Temperature, air ratio, suspension density, fly ash re-injection and steam injection were found to influence the composition and heating value of the product gas. Tar yield from the biomass gasification decreased exponentially with increasing operating temperature for the range studied. A non-stoichiometric equilibrium model based on direct minimization of Gibbs free energy was developed to predict the performance of the gasifier. Experimental evidence indicated that the pilot gasifier deviated from chemical equilibrium due to kinetic limitations. A phenomenological model adapted from the pure equilibrium model, incorporating experimental results regarding unconverted carbon and methane to account for non-equilibrium factors, predicts product gas compositions, heating value and cold gas efficiency in good agreement with the experimental data.

/pdf/biomass-gasification-in-a-circulating-fluidized-bed-120fspk3e8.pdf

Biomass gasification in a circulating fluidized bed

Introduction to circulating fluidized beds. Hydrodynamics of circulating fluidized beds. Gas mixing. Solids motion and mixing. Hydrodynamic modelling. Cyclones and separation devices. Standpipes and return systems. Heat transfer. Instrumentation. CFB combustion performance. Design considerations for CFB boilers. Other gas-solid reactions. Catalytic cracking. Design and scale-up of CFB catalytic reactors. Reactor modelling. Novel configurations and variants. Future prospects. References. Index.

Circulating fluidized beds

A State-of-the-Art Review of Gas-Solid Turbulent Fluidization

Equilibrium modeling of gasification: a free energy minimization approach and its application to a circulating fluidized bed coal gasifier

An attempt is made to extend schemes for classifying the behaviour of gas—solid contacting modes and other two-phase systems. The regime diagram approach of Reh (1971) is modified and extended to cover the operating regions of common reactors and contactors where a gas flows upwards through a bed of solids including fixed and moving packed beds, conventional fluidized beds, circulating beds, spouted beds, and pneumatically conveyed suspensions. New boundaries are proposed between groups A and B and between groups B and D of the Geldart (1972, 1973) powder classification scheme. These boundaries reflect more recent data and allow the classification scheme to be used for gases other than air and for temperatures and pressures other than atmospheric.

John R. Grace

Papers

Biomass gasification in a circulating fluidized bed

Circulating fluidized beds

A State-of-the-Art Review of Gas-Solid Turbulent Fluidization

Equilibrium modeling of gasification: a free energy minimization approach and its application to a circulating fluidized bed coal gasifier

Contacting modes and behaviour classification of gas—solid and other two-phase suspensions