Department of Materials Science, University of Patras, 26504 Rio Patras, Greece, Theoretical and Physical Chemistry Institute, National Hellenic Research Foundation, 48 Vass. Constantinou Avenue, 116 35 Athens, Greece, Institut de Biologie Moleculaire et Cellulaire, UPR9021 CNRS, Immunologie et Chimie Therapeutiques, 67084 Strasbourg, France, and Dipartimento di Scienze Farmaceutiche, Universita di Trieste, Piazzale Europa 1, 34127 Trieste, Italy

Chemistry of Carbon Nanotubes

Carbon nanotube–polymer composites: Chemistry, processing, mechanical and electrical properties

Ultrathin, uniform single-walled carbon nanotube networks of varying densities have been fabricated at room temperature by a vacuum filtration method. Measurements of the sheet conductance as a function of nanotube network density show 2D percolation behavior. In addition, the network transparency in the visible spectral range was examined and the results are in agreement with a standard thin-film model: fits to the standard theory indicate U ac ) Udc for transmission measurements at 550 nm. Transmission measurements also indicate the usefulness of nanotube network films as a transparent, conductive coating. Avenues for improvement of the network conductance are discussed.

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Percolation in transparent and conducting carbon nanotube networks

Nanocomposites, a high performance material exhibit unusual property combinations and unique design possibilities. With an estimated annual growth rate of about 25% and fastest demand to be in engineering plastics and elastomers, their potential is so striking that they are useful in several areas ranging from packaging to biomedical applications. In this unified overview the three types of matrix nanocomposites are presented underlining the need for these materials, their processing methods and some recent results on structure, properties and potential applications, perspectives including need for such materials in future space mission and other interesting applications together with market and safety aspects. Possible uses of natural materials such as clay based minerals, chrysotile and lignocellulosic fibers are highlighted. Being environmentally friendly, applications of nanocomposites offer new technology and business opportunities for several sectors of the aerospace, automotive, electronics and biotechnology industries.

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Nanocomposites: synthesis, structure, properties and new application opportunities

Sensors and actuators based on carbon nanotubes and their composites: A review

The design and development of a compact wireless gas sensor with a surface modified multiwalled carbon nanotube (f-CNT) chemiresistor as the sensing element is presented in this paper. f-CNT/polymer composite sensing film is patterned on a printed circuit board and is integrated to the wireless system. The change in resistance of the CNT/polymer composite film due to exposure of different gases is utilized as the principle of this gas sensor. The response for different organic vapors are evaluated and it is observed that the f-CNT/PMMA composite film shows fast response and change in resistance of the order of 102–103 due to its surface modification.

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A compact wireless gas sensor using a carbon nanotube/PMMA thin film chemiresistor

The design and development of composite thin films of polymethylmethacrylate (PMMA) with multiwalled carbon nanotubes (CNTs) and surface-modified multiwalled carbon nanotubes (f-CNTs) for gas-sensing applications are presented in this paper. The responses of these composites for different organic vapors were evaluated by monitoring the change in the resistance of thin films of composite when exposed to gases like dichloromethane, chloroform, acetone, methanol, ethyl acetate, toluene and hexane. It was observed that the f-CNT/PMMA composite showed a higher response. There was an increase in resistance of the order of 102–103, due to surface modification, when exposed to dichloromethane, chloroform and acetone. The sensing mechanism is explained on the basis of volume expansion and polar interaction of various vapors on the CNT surface.

https://iopscience.iop.org/article/10.1088/0964-1726/12/6/010/pdf

Carbon nanotube/PMMA composite thin films for gas-sensing applications

This paper relates for the first time, multiple resonant frequencies of fractal element antennas using Koch curves to their fractal dimension. Dipole and monopole antennas based fractal Koch curves studied so far have generally been limited to certain standard configurations of the geometry. It is possible to generalize the geometry by changing its indentation angle, to vary its fractal similarity dimension. This variation results in self-similar geometry which can be generated by a recursive algorithm. Such a variation is found to have a direct influence on the input characteristics of dipole antennas. The primary resonant frequency, the input resistance at this resonance, and the ratio of first two resonant frequencies, have all been directly related to the fractal dimension. Curve-fit expressions can also be obtained for the performance of antennas at their primary resonance, in terms of fractal iteration and fractal dimension. The antenna characteristics have been studied using extensive numerical simulations and are experimentally verified. These findings underscore the significance of fractal dimension as an important mathematical property of fractals that can be used as a design parameter for antennas. The use of these ideas would not only reduce the computational intensity of optimization approaches for design of fractal shaped antennas, but also help antenna designers approach the problem systematically. Design formulation for antennas based on other fractal geometries can be similarly obtained after identifying suitable parameters of variation. This would therefore help analytical design of multiband and multifunctional antennas using fractal geometries.

On the relationship between fractal dimension and the performance of multi-resonant dipole antennas using Koch curves

Composites of carbon a nanotube with polymers are a developing and interesting area of research. The dispersion of the nanotube in polymer matrices is an important factor while making its nanocomposites. Even though in-situ polymerization approach offers a better approach for synthesizing homogeneous polymer nanotube composites, the dispersion of the nanotubes in the monomer solution is a problem. In this article we report a new chemical method for dispersing nanotubes in monomer and the preparation of uniform tubular composite of polyaniline (PANI) and multiwalled carbon nanotube (MWNT). For this the oxidized multiwalled nanotube (o-MWNT) was functionalized with p-phenylenediamine, which gave phenylamine functional groups on the surface. This functionalization helped to disperse the nanotubes in acidic solution. The in-situ polymerization of aniline in the presence of these well dispersed nanotubes gave a new tubular composite of carbon nanotube having an ordered uniform encapsulation of doped polyaniline. The phenylamine functional groups on the surface were grown into polyaniline chain so that the composite contains polyaniline functionalized CNT and they were no more an “impurity” in the final nanocomposite. The microscopic and structural properties of this composite were compared with that of a composite prepared under identical condition using o-MWNT.

Polyaniline / carbon nanotube composites: starting with phenylamino functionalized carbon nanotubes

A nanocomposite of a multiwalled carbon nanotube and polythiophene was prepared by functionalizing the nanotube surface with a polythiophene, poly[3-(2-hydroxyethyl)-2,5-thienylene], containing pendant hydroxyl groups. The composite was characterized by IR, high resolution TEM and conductivity measurements. The poly[3-(2-hydroxyethyl)-2,5-thienylene] (PHET) was synthesized by the oxidation polymerization of 2-(3-thienylethanol) using FeCl3 and CHCl3. Multiwalled carbon nanotubes were synthesized by a microwave CVD method and oxidized with potassium permanganate using a phase transfer catalyst in mild conditions. The COOH groups formed on the nanotube surface were converted to COCl using thionyl chloride and it was then condensed with the polythiophene at high temperature in anhydrous DMF. High resolution TEM images showed that the functionalization provided a firm coating of the conducting polymer on nanotube walls. This nanocomposite with PHET grafted to CNT showed higher conductivity than a nanocomposite of PHET and CNT in the same percentage weight composition prepared by ultrasonic mixing of the two. Such a material was designed and synthesized with a view to electronic and sensor applications.

https://iopscience.iop.org/article/10.1088/0964-1726/13/2/007/pdf

Jose K. Abraham

Papers

A compact wireless gas sensor using a carbon nanotube/PMMA thin film chemiresistor

Carbon nanotube/PMMA composite thin films for gas-sensing applications

On the relationship between fractal dimension and the performance of multi-resonant dipole antennas using Koch curves

Polyaniline / carbon nanotube composites: starting with phenylamino functionalized carbon nanotubes

A novel nanocomposite from multiwalled carbon nanotubes functionalized with a conducting polymer