J
Joseph J. Gajewski
Researcher at Indiana University
Publications - 142
Citations - 2141
Joseph J. Gajewski is an academic researcher from Indiana University. The author has contributed to research in topics: Kinetic isotope effect & Sigmatropic reaction. The author has an hindex of 25, co-authored 142 publications receiving 2088 citations.
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Journal ArticleDOI
The mechanism of rearrangement of chorismic acid and related compounds
Joseph J. Gajewski,Jurjus Jurayj,Doris R. Kimbrough,Matthew E. Gande,Bruce Ganem,Barry K. Carpenter +5 more
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The Claisen Rearrangement. Response to Solvents and Substituents: The Case for Both Hydrophobic and Hydrogen Bond Acceleration in Water and for a Variable Transition State
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Antiaromaticity of cyclopropenyl anions
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A semitheoretical multiparameter approach to correlate solvent effects on reactions and equilibria
TL;DR: A solvent rate effect equation which uses four physical properties of the solvent for parameters has been applied with good success to solvolysis reactions, solvent E t values, Claisen Rearrangements, Diels-Alder reactions, endo-exo ratios in Dields-Ald reactions, azo-Cope rearrangements, and enol-ketone equilibria of the dimedone and pyridone variety as mentioned in this paper.
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Variable transition state structure in 3,3-sigmatropic shifts from .alpha.-secondary deuterium isotope effects
TL;DR: In this article, the relative values of secondary alpha.. deuterium kinetic isotopic effects at the terminal and central carbons of 1,5-dienes undergoing the 3,3-shifts vary as a function of substitution.