K. Sumathy

Bio: K. Sumathy is an academic researcher from University of Hong Kong. The author has contributed to research in topics: Air conditioning & Solar air conditioning. The author has an hindex of 17, co-authored 20 publications receiving 4489 citations.

A review and recent developments in photocatalytic water-splitting using TiO2 for hydrogen production

Abstract: Nano-sized TiO 2 photocatalytic water-splitting technology has great potential for low-cost, environmentally friendly solar-hydrogen production to support the future hydrogen economy. Presently, the solar-to-hydrogen energy conversion efficiency is too low for the technology to be economically sound. The main barriers are the rapid recombination of photo-generated electron/hole pairs as well as backward reaction and the poor activation of TiO 2 by visible light. In response to these deficiencies, many investigators have been conducting research with an emphasis on effective remediation methods. Some investigators studied the effects of addition of sacrificial reagents and carbonate salts to prohibit rapid recombination of electron/hole pairs and backward reactions. Other research focused on the enhancement of photocatalysis by modification of TiO 2 by means of metal loading, metal ion doping, dye sensitization, composite semiconductor, anion doping and metal ion-implantation. This paper aims to review the up-to-date development of the above-mentioned technologies applied to TiO 2 photocatalytic hydrogen production. Based on the studies reported in the literature, metal ion-implantation and dye sensitization are very effective methods to extend the activating spectrum to the visible range. Therefore, they play an important role in the development of efficient photocatalytic hydrogen production.

Technology development in the solar absorption air-conditioning systems

Abstract: An environmental control system utilizing solar energy would generally be more cost-effective if it were used to provide both heating and cooling requirements in the building it serves. Various solar powered heating systems have been tested extensively, but solar powered air-conditioners have received little more than short-term demonstration attention. This paper reviews past efforts in the field of solar powered air-conditioning systems with the absorption pair of lithium bromide and water. A number of attempts have been made by researchers to improve the performance of the solar applied air-conditioning (chiller) subsystems. It is seen that the generator inlet temperature of the chiller is the most important parameter in the design and fabrication of a solar powered air-conditioning system. While collector choice, system design and arrangement are other impacting factors for the system operation.

Solar transparent insulation materials: a review

Abstract: This paper presents a status report on solar transparent insulation materials (TIM). It covers a survey of the literature, various physical and other properties of TIM devices, their classifications, applications, fabrication procedures, availability and cost trends. The global resurgence of research is clarified. Subsequently, the development of TIM cover systems (often referred to as advanced glazing) from such products as polymer sheets, capillaries and cellular profiles, is discussed. Their design and performance characteristics are investigated; results corresponding to experimental measurements, as well as computational models, are presented. An explicit comparative study of absorber parallel and absorber perpendicular configurations of TIM cover systems is presented. The TIM covers with black end cover plates, and cellular walls of high emissivity, as well as those with selective cover plates and cellular walls fully transparent to IR radiations, have relatively lower heat loss coefficients.

Study on a direct-expansion solar-assisted heat pump water heating system

Abstract: Analytical and experimental studies were performed on a direct-expansion solar-assisted heat pump (DX-SAHP) water heating system, in which a 2 m2 bare flat collector acts as a source as well as an evaporator for the refrigerant. A simulation model was developed to predict the long-term thermal performance of the system approximately. The monthly averaged COP was found to vary between 4 and 6, while the collector efficiency ranged from 40 to 60%. The simulated results were used to obtain an optimum design of the system and to determinate a proper strategy for system operating control. The effect of various parameters, including solar insolation, ambient temperature, collector area, storage volume and speed of compressor, had been investigated on the thermal performance of the DX-SAHP system, and the results had indicated that the system performance is governed strongly by the change of solar insolation, collector area and speed of compressor. The experimental results obtained under winter climate conditions were shown to agree reasonably with the computer simulation. Copyright © 2003 John Wiley & Sons, Ltd.

Semiconductor-based Photocatalytic Hydrogen Generation

Abstract: 2.3. Evaluation of Photocatalytic Water Splitting 6507 2.3.1. Photocatalytic Activity 6507 2.3.2. Photocatalytic Stability 6507 3. UV-Active Photocatalysts for Water Splitting 6507 3.1. d0 Metal Oxide Photocatalyts 6507 3.1.1. Ti-, Zr-Based Oxides 6507 3.1.2. Nb-, Ta-Based Oxides 6514 3.1.3. W-, Mo-Based Oxides 6517 3.1.4. Other d0 Metal Oxides 6518 3.2. d10 Metal Oxide Photocatalyts 6518 3.3. f0 Metal Oxide Photocatalysts 6518 3.4. Nonoxide Photocatalysts 6518 4. Approaches to Modifying the Electronic Band Structure for Visible-Light Harvesting 6519

Review of the anatase to rutile phase transformation

Abstract: Titanium dioxide, TiO2, is an important photocatalytic material that exists as two main polymorphs, anatase and rutile. The presence of either or both of these phases impacts on the photocatalytic performance of the material. The present work reviews the anatase to rutile phase transformation. The synthesis and properties of anatase and rutile are examined, followed by a discussion of the thermodynamics of the phase transformation and the factors affecting its observation. A comprehensive analysis of the reported effects of dopants on the anatase to rutile phase transformation and the mechanisms by which these effects are brought about is presented in this review, yielding a plot of the cationic radius versus the valence characterised by a distinct boundary between inhibitors and promoters of the phase transformation. Further, the likely effects of dopant elements, including those for which experimental data are unavailable, on the phase transformation are deduced and presented on the basis of this analysis.

Science and technology roadmap for graphene, related two-dimensional crystals, and hybrid systems

Abstract: We present the science and technology roadmap for graphene, related two-dimensional crystals, and hybrid systems, targeting an evolution in technology, that might lead to impacts and benefits reaching into most areas of society. This roadmap was developed within the framework of the European Graphene Flagship and outlines the main targets and research areas as best understood at the start of this ambitious project. We provide an overview of the key aspects of graphene and related materials (GRMs), ranging from fundamental research challenges to a variety of applications in a large number of sectors, highlighting the steps necessary to take GRMs from a state of raw potential to a point where they might revolutionize multiple industries. We also define an extensive list of acronyms in an effort to standardize the nomenclature in this emerging field.