Kai Sun

Bio: Kai Sun is an academic researcher from Tsinghua University. The author has contributed to research in topics: Materials science & AC power. The author has an hindex of 66, co-authored 476 publications receiving 16720 citations. Previous affiliations of Kai Sun include Michigan Technological University & Princeton University.

An Improved Droop Control Method for DC Microgrids Based on Low Bandwidth Communication With DC Bus Voltage Restoration and Enhanced Current Sharing Accuracy

Abstract: Droop control is the basic control method for load current sharing in dc microgrid applications. The conventional dc droop control method is realized by linearly reducing the dc output voltage as the output current increases. This method has two limitations. First, with the consideration of line resistance in a droop-controlled dc microgrid, since the output voltage of each converter cannot be exactly the same, the output current sharing accuracy is degraded. Second, the dc-bus voltage deviation increases with the load due to the droop action. In this paper, in order to improve the performance of the dc microgrid operation, a low-bandwidth communication (LBC)-based improved droop control method is proposed. In contrast with the conventional approach, the control system does not require a centralized secondary controller. Instead, it uses local controllers and the LBC network to exchange information between converter units. The droop controller is employed to achieve independent operation, and the average voltage and current controllers are used in each converter to simultaneously enhance the current sharing accuracy and restore the dc bus voltage. All of the controllers are realized locally, and the LBC system is only used for changing the values of the dc voltage and current. Hence, a decentralized control scheme is accomplished. The simulation test based on MATLAB/Simulink and the experimental validation based on a 2 × 2.2 kW prototype were implemented to demonstrate the proposed approach.

State-of-Charge Balance Using Adaptive Droop Control for Distributed Energy Storage Systems in DC Microgrid Applications

Abstract: This paper presents the coordinated control of distributed energy storage systems in dc microgrids. In order to balance the state-of-charge (SoC) of each energy storage unit (ESU), an SoC-based adaptive droop control method is proposed. In this decentralized control method, the droop coefficient is inversely proportional to the nth order of SoC. By using a SoC-based droop method, the ESUs with higher SoC deliver more power, whereas the ones with lower SoC deliver less power. Therefore, the energy stored in the ESU with higher SoC decreases faster than that with lower SoC. The SoC difference between each ESU gradually becomes smaller, and finally, the load power is equally shared between the distributed ESUs. Meanwhile, the load sharing speed can be adjusted by changing the exponent of SoC in the adaptive droop control. The model of the SoC-based adaptive droop control system is established, and the system stability is thereby analyzed by using this model. Simulation and experimental results from a 2 × 2.2 kW parallel converter system are presented in order to validate the proposed approach.

A Distributed Control Strategy Based on DC Bus Signaling for Modular Photovoltaic Generation Systems With Battery Energy Storage

Abstract: Modular generation system, which consists of modular power conditioning converters, is an effective solution to integrate renewable energy sources with conventional utility grid to improve reliability and efficiency, especially for photovoltaic generation. A distributed control strategy based on improved dc bus signaling is proposed for a modular photovoltaic (PV) generation system with battery energy storage elements. In this paper, the modular PV generation system is composed of three modular dc/dc converters for PV arrays, two grid-connected dc/ac converters, and one dc/dc converter for battery charging/discharging and local loads, which is available of either grid-connected operation or islanding operation. By using the proposed control strategy, the operations of a modular PV generation system are categorized into four modes: islanding with battery discharging, grid-connected rectification, grid-connected inversion, and islanding with constant voltage (CV) generation. The power balance of the system under extreme conditions such as the islanding operation with a full-charged battery is taken into account in this control strategy. The dc bus voltage level is employed as an information carrier to distinguish different modes and determine mode switching. Control methods of modular dc/dc converters, battery converter, and grid-connected converter are addressed. An autonomous control method for modular dc/dc converters is proposed to realize smooth switching between CV operation and maximum power point tracking operation, which enables the dc bus voltage regulation capability of modular dc/dc converters. Seamless switching of a battery converter between charging and discharging and that of a grid-connected converter between rectification and inversion are ensured by the proposed control methods. Experiments verify the practical feasibility and the effectiveness of the proposed control strategies.

Solution-Based Evolution and Enhanced Methanol Oxidation Activity of Monodisperse Platinum-Copper Nanocubes**

Abstract: Shape-controlled catalysis: High-quality Pt-Cu nanocubes with an average size of about 8 nm (see picture, scale bar = 20 nm) were synthesized from a high-temperature organic solution system in the presence of various capping ligands. These cubic Pt-Cu nanocrystals terminated with {100} facets demonstrated a superior catalytic activity towards methanol oxidation compared to similar sized Pt-Cu and Pt nanospheres.

3D Honeycomb‐Like Structured Graphene and Its High Efficiency as a Counter‐Electrode Catalyst for Dye‐Sensitized Solar Cells

Abstract: Graphene, a two-dimensional carbon sheet, has attracted great interest due to its unique properties. To explore its practical applications, large-scale synthesis with controllable integration of individual graphene sheets is essential. To date, numerous approaches have been developed for graphene synthesis, including mechanical cleavage, epitaxial growth, and chemical vapor deposition. All of those techniques are used to prepare flat graphene sheets on a substrate. Chemical exfoliation of graphite has been applied to prepare graphene oxide solutions and graphene-based composite materials. Recently, tuning graphene shapes is attracting much attention. Cheng and co-workers synthesized graphene foam using porous Ni foam as a template for the CVD growth of graphene, followed by etching away the Ni skeleton. The graphene foam consists of an interconnected flexible network of graphene as the fast transport channel of charge carriers for high electrical conductivity. Ruoff et al. prepared porous graphene paper from microwave exfoliated graphene oxide by KOH activation. The porous graphene, which has an ultra-high surface area and a high electrical conductivity, was exploited for supercapacitor cells, leading to high values of gravimetric capacitance and energy density. Feng, M llen, and co-workers synthesized hierarchical macroand mesoporous graphene frameworks (GFs). The GFs exhibited excellent performance for electrochemical capacitive energy storage. Yu et al. and Qu et al. fabricated graphene tubes that could be selectively functionalized for desirable applications. Choi et al. synthesized macroporous graphene using polystyrene colloidal particles as sacrificial templates in graphene oxide suspension, and the pore sizes can be tuned by controlling template particle size. These important results represent a significant topic—tuning the properties of graphene sheets by controlling their shapes. However, it is still a challenge to synthesize three-dimensional graphene (3D) with a desirable shape. Herein, we develop a novel strategy for the synthesis of a new type of graphene sheet with a 3D honeycomb-like structure by a simple reaction between Li2O and CO. Furthermore, these graphene sheets exhibited excellent catalytic performance as a counter electrode for dye-sensitized solar cells (DSSCs) with an energy conversion efficiency as high as 7.8%, which is comparable to that of an expensive platinum electrode. Li2O is widely exploited as a promoter in catalysts to inhibit carbon formation. However, this general principle is challenged by this work, in which Li2O is used to react with CO to form graphene-structured carbon [Eq. (1)]

疟原虫var基因转换速率变化导致抗原变异[英]／Paul H, Robert P, Christodoulou Z, et al//Proc Natl Acad Sci U S A

Abstract: 抗原变异可使得多种致病微生物易于逃避宿主免疫应答。表达在感染红细胞表面的恶性疟原虫红细胞表面蛋白1（PfPMP1）与感染红细胞、内皮细胞、树突状细胞以及胎盘的单个或多个受体作用，在黏附及免疫逃避中起关键的作用。每个单倍体基因组var基因家族编码约60种成员，通过启动转录不同的var基因变异体为抗原变异提供了分子基础。

Recent Advances in Ultrathin Two-Dimensional Nanomaterials

Abstract: Since the discovery of mechanically exfoliated graphene in 2004, research on ultrathin two-dimensional (2D) nanomaterials has grown exponentially in the fields of condensed matter physics, material science, chemistry, and nanotechnology. Highlighting their compelling physical, chemical, electronic, and optical properties, as well as their various potential applications, in this Review, we summarize the state-of-art progress on the ultrathin 2D nanomaterials with a particular emphasis on their recent advances. First, we introduce the unique advances on ultrathin 2D nanomaterials, followed by the description of their composition and crystal structures. The assortments of their synthetic methods are then summarized, including insights on their advantages and limitations, alongside some recommendations on suitable characterization techniques. We also discuss in detail the utilization of these ultrathin 2D nanomaterials for wide ranges of potential applications among the electronics/optoelectronics, electrocat...

Weyl and Dirac semimetals in three-dimensional solids

Abstract: Weyl and Dirac semimetals are three-dimensional phases of matter with gapless electronic excitations that are protected by topology and symmetry. As three-dimensional analogs of graphene, they have generated much recent interest. Deep connections exist with particle physics models of relativistic chiral fermions, and, despite their gaplessness, to solid-state topological and Chern insulators. Their characteristic electronic properties lead to protected surface states and novel responses to applied electric and magnetic fields. The theoretical foundations of these phases, their proposed realizations in solid-state systems, and recent experiments on candidate materials as well as their relation to other states of matter are reviewed.

Nano‐photocatalytic Materials: Possibilities and Challenges

Abstract: Semiconductor photocatalysis has received much attention as a potential solution to the worldwide energy shortage and for counteracting environmental degradation. This article reviews state-of-the-art research activities in the field, focusing on the scientific and technological possibilities offered by photocatalytic materials. We begin with a survey of efforts to explore suitable materials and to optimize their energy band configurations for specific applications. We then examine the design and fabrication of advanced photocatalytic materials in the framework of nanotechnology. Many of the most recent advances in photocatalysis have been realized by selective control of the morphology of nanomaterials or by utilizing the collective properties of nano-assembly systems. Finally, we discuss the current theoretical understanding of key aspects of photocatalytic materials. This review also highlights crucial issues that should be addressed in future research activities.