Showing papers by "Kalpattu K. Balasubramanian published in 1995"

TL;DR: In this paper, a simple and convenient method for the synthesis of aryl-3,4,6-tri-O-benzyl-2-deoxy-methylene-hexopyranosides 5,6 and 7, glycosides which are not accessible by the conventional Ferrier rearrangement, has been described based on the Mitsunobu reaction of alcohols 3 and 4 with substituted phenols.

TL;DR: For example, 2-furyl and 2-thicnylmelhyl vinyl ethers undergo formal [1,3] rearrangement in LPDE medium as discussed by the authors.

TL;DR: Linked scans, high-resolution mass spectrometry, collision-activated dissociation-B/E linked-scan spectra, and D-labeling have been employed to support the proposed mechanisms and ion structures.