K
Kalpattu K. Balasubramanian
Researcher at Indian Institute of Technology Madras
Publications - 141
Citations - 1311
Kalpattu K. Balasubramanian is an academic researcher from Indian Institute of Technology Madras. The author has contributed to research in topics: Aryl & Claisen rearrangement. The author has an hindex of 20, co-authored 139 publications receiving 1234 citations. Previous affiliations of Kalpattu K. Balasubramanian include University of Madras & Madurai Kamaraj University.
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Montmorillonite K-10 clay-catalyzed Ferrier rearrangement of 2-C-hydroxymethyl-d-glycals, 3,4,6-tri-O-alkyl-d-glycals, and 3,4-(dihydro-2H-pyran-5-yl)methanol: a few unexpected domino transformations.
Elumalai Kumaran,Meenakshisundaram Santhi,Kalpattu K. Balasubramanian,Shanmugasundaram Bhagavathy +3 more
TL;DR: Reaction of 2-C-hydroxymethyl-d-galactal with 2,6-dimethylphenol in the presence of montmorillonite K-10 led to a novel domino transformation affording 4-(5',6'-dihydro-4H-pyran-3'-ylmethyl)-2, 6-dimmethylphenol, which led to totally unexpected transformations.
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Synthesis and chemistry of 4-amino-4,6-dideoxy sugars. V. Synthesis of 4-amino-4,6-dideoxy-D-allose derivatives
Calvin L. Stevens,Kalpattu K. Balasubramanian,Charles P. Bryant,Jean B. Filippi,P Madhavan Pillai +4 more
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Formal [1,3] rearrangement of 2-furylmethyl and 2-thienylmethyl vinyl ethers
TL;DR: For example, 2-furyl and 2-thicnylmelhyl vinyl ethers undergo formal [1,3] rearrangement in LPDE medium as discussed by the authors.
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Thermal rearrangement of α-(aryloxy)methylacrylic acids: a facile synthesis of 3-methylcoumarins
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Cation radical-induced Claisen rearrangement of aryl allenylmethyl ethers
TL;DR: In this article, aryl allenylmethyl ethers with tris(4-bromophenyl)aminium hexachloroantimonate in acetonitrile at room temperature were treated with a facile cation radical induced Claisen rearrangement to yield 2-(o-hydroxyaryl)buta-1,3-dienes.