Katarzyna Kluczyk-Korch

Bio: Katarzyna Kluczyk-Korch is an academic researcher from University of Rome Tor Vergata. The author has contributed to research in topics: Microscopy & Microscope. The author has an hindex of 4, co-authored 10 publications receiving 35 citations. Previous affiliations of Katarzyna Kluczyk-Korch include Sapienza University of Rome & Wrocław University of Technology.

Nano illumination microscopy: a technique based on scanning with an array of individually addressable nanoLEDs

Abstract: In lensless microscopy, spatial resolution is usually provided by the pixel density of current digital cameras, which are reaching a hard-to-surpass pixel size / resolution limit over 1 µm. As an alternative, the dependence of the resolving power can be moved from the detector to the light sources, offering a new kind of lensless microscopy setups. The use of continuously scaled-down Light-Emitting Diode (LED) arrays to scan the sample allows resolutions on order of the LED size, giving rise to compact and low-cost microscopes without mechanical scanners or optical accessories. In this paper, we present the operation principle of this new approach to lensless microscopy, with simulations that demonstrate the possibility to use it for super-resolution, as well as a first prototype. This proof-of-concept setup integrates an 8 × 8 array of LEDs, each 5 × 5 μm2 pixel size and 10 μm pitch, and an optical detector. We characterize the system using Electron-Beam Lithography (EBL) pattern. Our prototype validates the imaging principle and opens the way to improve resolution by further miniaturizing the light sources.

Optical design of InGaN/GaN nanoLED arrays on a chip: toward: highly resolved illumination.

Abstract: The physical laws of diffraction limit the spatial resolution of optical systems. In contrary to most superresolution microscopy approaches used today, in our novel idea we are aiming to overcome this limit by developing a spatially resolved illumination source based on semiconductor nanoscale light emitting diode (nanoLED) arrays with individual pixel control. We present and discuss the results of optical simulations performed for such nanoLED emitter arrays and analyze the theoretical limits of this approach. As possible designs we study arrays of GaN nanofins and nanorods (obtained by etching nanofin arrays), with InGaN/GaN multi quantum wells embedded as active regions. We find that a suitable choice of the array dimensions leads to a reasonably directed light output and concentration of the optical power in the near field around an activated pixel. As a consequence, the spatial resolution for this type of microscopy should only be limited by the pixel pitch, and no longer by the optical diffraction. Realization of optimized nanoLED arrays has a potential to open new field of chip based superresolution microscopy, making super-high spatial resolution ubiquitously available.

Mode Splitting Induced by Mesoscopic Electron Dynamics in Strongly Coupled Metal Nanoparticles on Dielectric Substrates

Abstract: We study strong optical coupling of metal nanoparticle arrays with dielectric substrates. Based on the Fermi Golden Rule, the particle-substrate coupling is derived in terms of the photon absorption probability assuming a local dipole field. An increase in photocurrent gain is achieved through the optical coupling. In addition, we describe light-induced, mesoscopic electron dynamics via the nonlocal hydrodynamic theory of charges. At small nanoparticle size (<20 nm), the impact of this type of spatial dispersion becomes sizable. Both absorption and scattering cross sections of the nanoparticle are significantly increased through the contribution of additional nonlocal modes. We observe a splitting of local optical modes spanning several tenths of nanometers. This is a signature of semi-classical, strong optical coupling via the dynamic Stark effect, known as Autler-Townes splitting. The photocurrent generated in this description is increased by up to 2%, which agrees better with recent experiments than compared to identical classical setups with up to 6%. Both, the expressions derived for the particle-substrate coupling and the additional hydrodynamic equation for electrons are integrated into COMSOL for our simulations.

Application of Core–Shell Metallic Nanoparticles in Hybridized Perovskite Solar Cell—Various Channels of Plasmon Photovoltaic Effect

Abstract: We analyze the microscopic mechanism of the improvement of solar cell efficiency by plasmons in metallic components embedded in active optical medium of a cell. We focus on the explanation of the observed new channel of plasmon photovoltaic effect related to the influence of plasmons onto the internal cell electricity beyond the previously known plasmon mediated absorption of photons. The model situation we analyze is the hybrid chemical perovskite solar cell CH 3 NH 3 PbI 3 - α Cl α with inclusion of core-shell Au/Si0 2 nanoparticles filling pores in the Al 2 O 3 or TiO 2 porous bases at the bottom of perovskite layer, application of which improved the cell efficiency from 10.7 to 11.4% and from 8.4 to 9.5%, respectively, as demonstrated experimentally, mostly due to the reduction by plasmons of the exciton binding energy.

Quantum Confined Stark Effect in Single CdSe Nanocrystallite Quantum Dots

Abstract: The quantum-confined Stark effect in single cadmium selenide (CdSe) nanocrystallite quantum dots was studied. The electric field dependence of the single-dot spectrum is characterized by a highly polarizable excited state (∼10 5 cubic angstroms, compared to typical molecular values of order 10 to 100 cubic angstroms), in the presence of randomly oriented local electric fields that change over time. These local fields result in spontaneous spectral diffusion and contribute to ensemble inhomogeneous broadening. Stark shifts of the lowest excited state more than two orders of magnitude larger than the linewidth were observed, suggesting the potential use of these dots in electro-optic modulation devices.

Photon management to reduce energy loss in perovskite solar cells.

Abstract: Despite the rapid development of perovskite solar cells (PSCs) over the past few years, the conversion of solar energy into electricity is not efficient enough or cost-competitive yet. The principal energy loss in the conversion of solar energy to electricity fundamentally originates from the non-absorption of low-energy photons ascribed to Shockley–Queisser limits and thermalization losses of high-energy photons. Enhancing the light-harvesting efficiency of the perovskite photoactive layer by developing efficient photo management strategies with functional materials and arrays remains a long-standing challenge. Here, we briefly review the historical research trials and future research trends to overcome the fundamental loss mechanisms in PSCs, including upconversion, downconversion, scattering, tandem/graded structures, texturing, anti-reflection, and luminescent solar concentrators. We will deeply emphasize the availability and analyze the importance of a fine device structure, fluorescence efficiency, material proportion, and integration position for performance improvement. The unique energy level structure arising from the 4fn inner shell configuration of the trivalent rare-earth ions gives multifarious options for efficient light-harvesting by upconversion and downconversion. Tandem or graded PSCs by combining a series of subcells with varying bandgaps seek to rectify the spectral mismatch. Plasmonic nanostructures function as a secondary light source to augment the light-trapping within the perovskite layer and carrier transporting layer, enabling enhanced carrier generation. Texturing the interior using controllable micro/nanoarrays can realize light–matter interactions. Anti-reflective coatings on the top glass cover of the PSCs bring about better transmission and glare reduction. Photon concentration through perovskite-based luminescent solar concentrators offers a path to increase efficiency at reduced cost and plays a role in building-integrated photovoltaics. Distinct from other published reviews, we here systematically and hierarchically present all of the photon management strategies in PSCs by presenting the theoretical possibilities and summarizing the experimental results, expecting to inspire future research in the field of photovoltaics, phototransistors, photoelectrochemical sensors, photocatalysis, and especially light-emitting diodes. We further assess the overall possibilities of the strategies based on ultimate efficiency prospects, material requirements, and developmental outlook.

Routes for Metallization of Perovskite Solar Cells

Abstract: The application of metallic nanoparticles leads to an increase in the efficiency of solar cells due to the plasmonic effect. We explore various scenarios of the related mechanism in the case of metallized perovskite solar cells, which operate as hybrid chemical cells without p-n junctions, in contrast to conventional cells such as Si, CIGS or thin-layer semiconductor cells. The role of metallic nano-components in perovskite cells is different than in the case of p-n junction solar cells and, in addition, the large forbidden gap and a large effective masses of carriers in the perovskite require different parameters for the metallic nanoparticles than those used in p-n junction cells in order to obtain the increase in efficiency. We discuss the possibility of activating the very poor optical plasmonic photovoltaic effect in perovskite cells via a change in the chemical composition of the perovskite and through special tailoring of metallic admixtures. Here we show that it is possible to increase the absorption of photons (optical plasmonic effect) and simultaneously to decrease the binding energy of excitons (related to the inner electrical plasmonic effect, which is dominant in perovskite cells) in appropriately designed perovskite structures with multishell elongated metallic nanoparticles to achieve an increase in efficiency by means of metallization, which is not accessible in conventional p-n junction cells. We discuss different methods for the metallization of perovskite cells against the background of a review of various attempts to surpass the Shockley-Queisser limit for solar cell efficiency, especially in the case of the perovskite cell family.

Carbon dots/inorganic nanomaterials composites

Abstract: Carbon dots (CDs), a carbon-based 0-Dimensionalfluorescent material with simple preparation method, wide range of raw materials, and excellent physical and chemical properties have attracted the attention of many researchers in...