Kathleen M. Poss

Bio: Kathleen M. Poss is an academic researcher. The author has contributed to research in topics: Claisen rearrangement & Sigmatropic reaction. The author has an hindex of 1, co-authored 1 publications receiving 28 citations.

Functionalization of Alkanes by Isolated Transition Metal Boryl Complexes

Abstract: We report the photochemical reaction of transition metal boryl complexes of the type Cp*M(CO)nB(OR)2 (M = Fe, Ru, W) with alkanes to form alkylboronate esters in yields as high as 85% for reaction ...

7.2 – Claisen Rearrangements

Abstract: This article surveys variants of the Claisen rearrangement that are of general use in stereoselective organic synthesis. Recent results concerning the influence of steric and electronic parameters on transition state geometries are highlighted. The impact of the Claisen methodology in modern synthetic strategy and its application for the preparation of highly functionalized derivatives is exemplified.

Enantioselective Total Synthesis of (+)-Salvileucalin B

Abstract: An enantioselective total synthesis of the diterpenoid natural product (+)-salvileucalin B is reported. Key findings include a copper-catalyzed arene cyclopropanation reaction to provide the unusual norcaradiene core and a reversible retro-Claisen rearrangement of a highly functionalized norcaradiene intermediate.