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Kent S. Knaebel

Bio: Kent S. Knaebel is an academic researcher from Ohio State University. The author has contributed to research in topics: Pressure swing adsorption & Adsorption. The author has an hindex of 11, co-authored 19 publications receiving 1402 citations.

Papers
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Book
01 Jan 1994
TL;DR: In this paper, a pressure swing adsorption cycle comprised of blowdown, purge, pressurization, feed, pressure equalization and rinse steps provided recovery from an atmospheric air feed, essentially dry and free of carbon dioxide, of a high yield of high purity nitrogen gas and a product gas rich in oxygen.
Abstract: A pressure swing adsorption cycle comprised of blowdown, purge, pressurization, feed, pressure equalization and rinse steps provided recovery from an atmospheric air feed, essentially dry and free of carbon dioxide, of a high yield of high purity nitrogen gas and a high yield of a product gas rich in oxygen as well as recovery of a residual feed byproduct gas for recycle with the air feed.

943 citations

Journal ArticleDOI
TL;DR: In this article, two versions of the pressure swing adsorption process are analyzed as a means for purification of the light component of a binary feed of arbitrary composition, and the results of the analysis show that a critical pressure ratio must be exceeded before complete purification is possible and that this pressure ratio increases as the lightcomponent content of the feed decreases.

111 citations

Journal ArticleDOI
TL;DR: In this paper, a mathematical model was developed to simulate the performance of breakthrough curves of unusual shapes, ranging from the expected sigmoidal shape at low humidity to a curve resembling the tangent function, but symmetric about the stoichiometric breakthrough time.
Abstract: Adsorption of water vapor on silica gel, at influent humidities from 6 to 80% at 25 and 50°C, yielded breakthrough curves of unusual shapes. Breakthrough patterns varied from the expected sigmoidal shape at low humidity to a curve resembling the tangent function, but symmetric about the stoichiometric breakthrough time. Unusual shapes were found to be due to subtle combination of Type-IV isotherm behavior and heat effects. A mathematical model was developed to simulate the performance. The results show that complex breakthrough behavior need not be ascribed to complicated causes (such as diffusion in bidisperse pores), which require multiparameter fitting of experimental data. In fact, the effects may be predicted from properties measured in simple independent experiments, though some care is required to account for the effects accurately.

65 citations

Journal ArticleDOI
TL;DR: In this article, the authors measured pure component equilibrium data for nitrogen, oxygen, and argon, and multicomponent equilibria for air in 20 × 40 mesh 5A molecular sieve.
Abstract: Pure-component equilibrium data for nitrogen, oxygen, and argon, and multicomponent equilibrium data for air in 20 × 40 mesh 5A molecular sieve were measured at 297.15, 233.15, and 203.15 K and up to pressures of 4 bar. The multicomponent data were analyzed by a statistical thermodynamic model, ideal adsorbed solution theory, an extended Langmuir-Sips equation, and an extended Langmuir equation. The multicomponent system exhibited nonideal behavior at 233.15 and 203.15 K. Isotherm parameters determined in this work may be useful in the design and evaluation of molecular sieve air separation systems.

65 citations

Patent
31 Mar 1992
TL;DR: In this article, a pressure swing adsorption (PSA) process for splitting oxygen from a feed gas comprising 95% oxygen and 5% argon to achieve an oxygen purity of at least about 99.7% is provided.
Abstract: A pressure swing adsorption (PSA) process for splitting oxygen from a feed gas comprising 95% oxygen and 5% argon to achieve an oxygen purity of at least about 99.7% is provided. A column used in the PSA process includes therein a bed of silver mordenite, an adsorbent determined to be selective to argon. In a preferred embodiment, the feed gas has a pressure of about 10.7 atm and a flow rate of about 8.8-9.2 vol. per cycle/vol of column.

54 citations


Cited by
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Journal ArticleDOI
TL;DR: This review presents in brief the history of adsorption and highlights the progress in theoretical description of the phenomenon under consideration, as well as presenting some of the latest important results and giving a source of up-to-date literature on it.

1,799 citations

Journal ArticleDOI
TL;DR: This paper explores in detail a number of variations of the original Keller–Segel model of chemotaxis from a biological perspective, contrast their patterning properties, summarise key results on their analytical properties and classify their solution form.
Abstract: Mathematical modelling of chemotaxis (the movement of biological cells or organisms in response to chemical gradients) has developed into a large and diverse discipline, whose aspects include its mechanistic basis, the modelling of specific systems and the mathematical behaviour of the underlying equations. The Keller-Segel model of chemotaxis (Keller and Segel in J Theor Biol 26:399–415, 1970; 30:225–234, 1971) has provided a cornerstone for much of this work, its success being a consequence of its intuitive simplicity, analytical tractability and capacity to replicate key behaviour of chemotactic populations. One such property, the ability to display “auto-aggregation”, has led to its prominence as a mechanism for self-organisation of biological systems. This phenomenon has been shown to lead to finite-time blow-up under certain formulations of the model, and a large body of work has been devoted to determining when blow-up occurs or whether globally existing solutions exist. In this paper, we explore in detail a number of variations of the original Keller–Segel model. We review their formulation from a biological perspective, contrast their patterning properties, summarise key results on their analytical properties and classify their solution form. We conclude with a brief discussion and expand on some of the outstanding issues revealed as a result of this work.

1,532 citations

Journal ArticleDOI
TL;DR: In this paper, the limitations of the Fick's law for describing diffusion are discussed and it is argued that the Maxwell-Stefan formulation provides the most general and convenient approach for describing mass transport which takes proper account of thermodynamic non-idealities and influence of external force fields.

1,323 citations

Book
Ralph T. Yang1
01 May 2003
TL;DR: Sorbent Selection: Equilibrium Isotherms, Diffusion, Cyclic Processes, and Sorbent Selection Criteria as mentioned in this paper is one of the most commonly used metrics in adorbent design.
Abstract: Preface. 1. Introductory Remarks. 2. Fundamental Factors for Designing Adsorbent. 3. Sorbent Selection: Equilibrium Isotherms, Diffusion, Cyclic Processes, and Sorbent Selection Criteria. 4. Pore Size Distribution. 5. Activated Carbon. 6. Silica Gel, MCM, and Activated Alumina. 7. Zeolites and Molecular Sieves. 8. &pi -Complexation Sorbents and Applications. 9. Carbon Nanotubes, Pillared Clays, and Polymeric Resins. 10. Sorbents for Applications. Author Index. Subject Index.

1,303 citations

Journal ArticleDOI
TL;DR: In this paper, the authors review the underlying science and describes the technological advances in the field of solar thermochemical production of hydrogen that uses concentrated solar radiation as the energy source of high-temperature process heat.

1,170 citations