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Klaus Danzer

Bio: Klaus Danzer is an academic researcher. The author has contributed to research in topics: Calibration (statistics). The author has an hindex of 1, co-authored 1 publications receiving 136 citations.

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Journal ArticleDOI
TL;DR: This review is a comprehensive description of the parameters that give rise to the sensing capabilities of CNT-based sensors and the application of C NT-based devices in chemical sensing and their prospects for commercialization.
Abstract: Carbon nanotubes (CNTs) promise to advance a number of real-world technologies. Of these applications, they are particularly attractive for uses in chemical sensors for environmental and health monitoring. However, chemical sensors based on CNTs are often lacking in selectivity, and the elucidation of their sensing mechanisms remains challenging. This review is a comprehensive description of the parameters that give rise to the sensing capabilities of CNT-based sensors and the application of CNT-based devices in chemical sensing. This review begins with the discussion of the sensing mechanisms in CNT-based devices, the chemical methods of CNT functionalization, architectures of sensors, performance parameters, and theoretical models used to describe CNT sensors. It then discusses the expansive applications of CNT-based sensors to multiple areas including environmental monitoring, food and agriculture applications, biological sensors, and national security. The discussion of each analyte focuses on the strategies used to impart selectivity and the molecular interactions between the selector and the analyte. Finally, the review concludes with a brief outlook over future developments in the field of chemical sensors and their prospects for commercialization.

641 citations

Journal ArticleDOI
TL;DR: In this paper, the terms recovery and apparent recovery are recommended to avoid confusion caused by the use of the term recovery to cover two distinct situations: the yield of a preconcentration or extraction stage of an analytical process (where recovery is recommended) and the quantity observed value/reference value, obtained using an analytical procedure that involves a calibration graph.
Abstract: The terms recovery and apparent recovery are recommended to avoid confusion caused by the use of the term recovery to cover two distinct situations. These situations deal with: (a) the yield of a preconcentration or extraction stage of an analytical process (where recovery is recommended) and (b) the quantity observed value/reference value, obtained using an analytical procedure that involves a calibration graph (where apparent recovery is recommended).

297 citations

Journal ArticleDOI
TL;DR: Practical guidelines for reporting analytical calibration results are provided and pertinent subjects here included are the choice of algorithms, the estimation of analytical figures of merit, the use of non-linear models, the consideration of the model regression coefficients for variable selection, and the application of certain mathematical pre-processing procedures such as smoothing.

211 citations

Journal ArticleDOI
TL;DR: The results indicate that active sampling strategies can only improve a random selection of experiments over a wide range of concentration of gasses, however, random or uninformed selection is fairly close.

174 citations

Journal ArticleDOI
TL;DR: In this article, the analytical calibration of an instrumental method is very important, being considered as a key point in method validation, and there are different validation guidelines; showing that analytical calibration process variety prevails in terms of nomenclature, methodology employed and acceptance criteria.
Abstract: The analytical calibration of an instrumental method is very important, being considered as a key point in method validation. There are different validation guidelines; showing that analytical calibration process variety prevails in terms of nomenclature, methodology employed and acceptance criteria. Very common mistakes in the analytical calibration process are the use of correlation and/or determination coefficients as a test for linearity, the negligence in the heteroscedasticity of the experimental data and selection of appropriate weighting factor, misunderstanding about the regression through the origin and using zero-point calibration. Once the calibration function is established, their linearity can be confirmed by using different procedures such as graphical plots, statistical significance tests and numerical parameters. In particular, deviation from back-calculated concentrations expressed in the form of percentage of relative error (%RE) can be considered very useful for unambiguous linearity evaluation. Some case studies were included to explain the linearity assessment from a practical viewpoint.

107 citations