A microfluidic sensor is implemented from a single split-ring resonator (SRR), a fundamental building block of electromagnetic metamaterials. At resonance, an SRR establishes an intense electric field confined within a deeply subwavelength region. Liquid flowing in a micro-channel laid on this region can alter the local field distribution and hence affect the SRR resonance behavior. Specifically, the resonance frequency and bandwidth are influenced by the complex dielectric permittivity of the liquid sample. The empirical relation between the sensor resonance and the sample permittivity can be established, and from this relation, the complex permittivity of liquid samples can be estimated. The technique is capable of sensing liquid flowing in the channel with a cross-sectional area as small as (0.001 λ 0 ) 2 , where λ 0 denotes the free-space wavelength of the wave excitation. This work motivates the use of SRR-based microfluidic sensors for identification, classification, and characterization of chemical and biochemical analytes.

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Metamaterial-based microfluidic sensor for dielectric characterization

This work was supported by National Basic Research Program of China
(Project No. 2013CB933301) and National Natural Science Foundation of
China (Project No. 51272038). L.V.B. was supported by China Postdoctoral
Science Foundation. A.O.G. was supported by the Volkswagen
Foundation (Germany) and via the Chang Jiang (Yangtze River)
Chair Professorship (China). G.P.W. acknowledges support from the
Center for Nanoscale Materials, a U.S. Department of Energy Office of
Science User Facility, and support by the U.S. Department of Energy,
Office of Science, under Contract No. DE-AC02-06CH11357. In addition,
the authors acknowledge financial support obtained from the Virtual
Institute for Theoretical Photonics and Energy. This review is part of the
Advanced Optical Materials Hall of Fame article series, which recognizes
the excellent contributions of leading researchers to the field of optical
materials science.

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Broadband Metamaterial Absorbers

Terahertz time-domain spectroscopy (THz-TDS) is a powerful technique for material’s characterization and process control. It has been used for contact-free conductivity measurements of metals, semiconductors, 2D materials, and superconductors. Furthermore, THz-TDS has been used to identify chemical components such as amino acids, peptides, pharmaceuticals, and explosives, which makes it particularly valuable for fundamental science, security, and medical applications. This tutorial is intended for a reader completely new to the field of THz-TDS and presents a basic understanding of THz-TDS. Hundreds of articles and many books can be consulted after reading this tutorial. We explore the basic concepts of TDS and discuss the relationship between temporal and frequency domain information. We illustrate how THz radiation can be generated and detected, and we discuss common noise sources and limitations for THz-TDS. This tutorial concludes by discussing some common experimental scenarios and explains how THz-TDS measurements can be used to identify materials, determine complex refractive indices (phase delay and absorption), and extract conductivity.

Tutorial: An introduction to terahertz time domain spectroscopy (THz-TDS)

Terahertz (THz) technology has attracted great worldwide interest and novel high-intensity THz sources and plasmonics are two of the most active fields of recent research. Being situated between infrared light and microwave radiation, the absorption of THz rays in molecular and biomolecular systems is dominated by the excitation of intramolecular and intermolecular vibrations. This indicates that THz technology is an effective tool for sensing applications. However, the low sensitivity of free-space THz detection limits the sensing applications, which gives a great opportunity to metamaterials. Metamaterials are periodic artificial electromagnetic media structured with a size scale smaller than the wavelength of external stimuli. They present localized electric field enhancement and large values of quality factor (Q factor) and show high sensitivity to minor environment changes. In the present work, the mechanism of THz metamaterial sensing and dry sample and microfluidic sensing applications based on metamaterials are introduced. Moreover, new directions of THz metamaterial sensing advancement and introduction of two-dimensional materials and nanoparticles for future THz applications are summarized and discussed.

Mechanisms and applications of terahertz metamaterial sensing: a review

Terahertz plasmonics: The rise of toroidal metadevices towards immunobiosensings

We present a metamaterial-based terahertz (THz) sensor for thickness measurements of subwavelength-thin materials and refractometry of liquids and liquid mixtures. The sensor operates in reflection geometry and exploits the frequency shift of a sharp Fano resonance minimum in the presence of dielectric materials. We obtained a minimum thickness resolution of 12.5 nm (1/16 000 times the wavelength of the THz radiation) and a refractive index sensitivity of 0.43 THz per refractive index unit. We support the experimental results by an analytical model that describes the dependence of the resonance frequency on the sample material thickness and the refractive index.

Metamaterial near-field sensor for deep-subwavelength thickness measurements and sensitive refractometry in the terahertz frequency range

We present a metamaterial-based terahertz (THz) sensor for thickness measurements of subwavelength-thin materials and refractometry of liquids and liquid mixtures. The sensor operates in reflection geometry and exploits the frequency shift of a sharp Fano resonance minimum in the presence of dielectric materials. We obtained a minimum thickness resolution of 12.5 nm (1/16000 times the wavelength of the THz radiation) and a refractive index sensitivity of 0.43 THz per refractive index unit. We support the experimental results by an analytical model that describes the dependence of the resonance frequency on the sample material thickness and the refractive index.

We present a fabrication method for flexible optically tunable terahertz metamaterial membranes based on thinning and embedding of commercially available silicon wafers in the metamaterial structure. The resulting membrane thickness of less than 25 em allows for quasi etalon-effect free devices which can be designed to show impedance matching to the surrounding air. We fabricated a thin film spectral bandpass filter with a maximal transmission of 85% and a modulation depth upon optical tuning of 98% at an operating frequency of 0.65THz. Further, we discussed the charge carrier dynamics and the requirements for optical tuning.

Optical tuning of ultra-thin, silicon-based flexible metamaterial membranes in the terahertz regime

In single-pixel coded aperture terahertz-imaging, the individual pixel size in the spatial terahertz modulator is usually comparable to the terahertz wavelength in order to obtain a sufficient spatial image resolution. Therefore, diffraction plays an important role in the imaging process and must be accurately taken into account when the image is computationally retrieved. For this reason, we analyzed the impact of diffraction from the spatial terahertz modulator on the quality of the reconstructed image in single-pixel coded aperture imaging. We observed that the most important fraction of the image information is already contained in the zero order diffracted radiation. Higher diffraction orders do not contain enough information to retrieve the image from them solely, yet can contribute to an improved image quality when added to the zero order information.

Evaluation of the impact of diffraction on image reconstruction in single-pixel imaging systems.

Efficient, high speed spatial modulators with predictable performance are a key element in any coded aperture terahertz imaging system. For spectroscopy, the modulators must also provide a broad modulation frequency range. In this study, we numerically analyze the electromagnetic behavior of a dynamically reconfigurable spatial terahertz wave modulator based on a micromirror grating in Littrow configuration. We show that such a modulator can modulate terahertz radiation over a wide frequency range from 1.7 THz to beyond 3 THz at a modulation depth of more than 0.6. As a specific example, we numerically simulated coded aperture imaging of an object with binary transmissive properties and successfully reconstructed the image.

Klemens M. Schmitt

Papers

Metamaterial near-field sensor for deep-subwavelength thickness measurements and sensitive refractometry in the terahertz frequency range

Metamaterial near-field sensor for deep-subwavelength thickness measurements and sensitive refractometry in the terahertz frequency range

Optical tuning of ultra-thin, silicon-based flexible metamaterial membranes in the terahertz regime

Evaluation of the impact of diffraction on image reconstruction in single-pixel imaging systems.

Electromagnetic behavior of spatial terahertz wave modulators based on reconfigurable micromirror gratings in Littrow configuration.