Kodakkal Kannan Viswanathan

Bio: Kodakkal Kannan Viswanathan is an academic researcher from Universiti Teknologi Malaysia. The author has contributed to research in topics: Boundary value problem & Spline (mathematics). The author has an hindex of 14, co-authored 75 publications receiving 665 citations. Previous affiliations of Kodakkal Kannan Viswanathan include SRM University & AMET University.

A Numerical Study of Dissipative Chemically Reactive Radiative MHD Flow Past a Vertical Cone with Nonuniform Mass Flux

Abstract: Abstract A computational model is presented to explore the properties of heat source, chemically reacting radiative, viscous dissipative MHD flow of an incompressible viscous fluid past an upright cone under inhomogeneous mass flux. A numerical study has been carried out to explore the mass flux features with the help of Crank-Nicolson finite difference scheme. This investigation reveals the influence of distinct significant parameters and the obtained outputs for the transient momentum, temperature and concentration distribution near the boundary layer is discussed and portrayed graphically for the active parameters such as the Schmidt number Sc, thermal radiation Rd, viscous dissipation parameter ɛ, chemical reaction parameter λ, MHD parameter M and heat generation parameter Δ. The significant effect of parameters on shear stress, heat and mass transfer rates are also illustrated.

A shallow water model for the propagation of tsunami via Lattice Boltzmann method

Abstract: An efficient implementation of the lattice Boltzmann method (LBM) for the numerical simulation of the propagation of long ocean waves (e.g. tsunami), based on the nonlinear shallow water (NSW) wave equation is presented. The LBM is an alternative numerical procedure for the description of incompressible hydrodynamics and has the potential to serve as an efficient solver for incompressible flows in complex geometries. This work proposes the NSW equations for the irrotational surface waves in the case of complex bottom elevation. In recent time, equation involving shallow water is the current norm in modelling tsunami operations which include the propagation zone estimation. Several test-cases are presented to verify our model. Some implications to tsunami wave modelling are also discussed. Numerical results are found to be in excellent agreement with theory.

Free Vibration of Layered Circular Cylindrical Shells of Variable Thickness Using Spline Function Approximation

Abstract: Free vibration of layered circular cylindrical shells of variable thickness is studied using spline function approximation by applying a point collocation method. The shell is made up of uniform layers of isotropic or specially orthotropic materials. The equations of motions in longitudinal, circumferential and transverse displacement components, are derived using extension of Love’s first approximation theory. The coupled differential equations are solved using Bickley-type splines of suitable order, which are cubic and quintic, by applying the point collocation method. This results in the generalized eigenvalue problem by combining the suitable boundary conditions. The effect of frequency parameters and the corresponding mode shapes of vibration are studied with different thickness variation coefficients, and other parameters. The thickness variations are assumed to be linear, exponential, and sinusoidal along the axial direction. The results are given graphically and comparisons are made with those results obtained using finite element method.

Free vibration analysis of composite cylindrical shells with non-uniform thickness walls

Abstract: The paper proposes to characterize the free vibration behaviour of non-uniform cylindrical shells using spline approximation under first order shear deformation theory. The system of coupled differential equations in terms of displacement and rotational functions are obtained. These functions are approximated by cubic splines. A generalized eigenvalue problem is obtained and solved numerically for an eigenfrequency parameter and an associated eigenvector which are spline coefficients. Four and two layered cylindrical shells consisting of two different lamination materials and plies comprising of same as well as different materials under two different boundary conditions are analyzed. The effect of length parameter, circumferential node number, material properties, ply orientation, number of lay ups, and coefficients of thickness variations on the frequency parameter is investigated.

Free vibration of cross-ply laminated plates based on higher-order shear deformation theory

Abstract: Free vibration of cross-ply laminated plates using a higher-order shear deformation theory is studied. The arbitrary number of layers is oriented in symmetric and anti-symmetric manners. The plate kinematics are based on higher-order shear deformation theory (HSDT) and the vibrational behaviour of multi-layered plates are analysed under simply supported boundary conditions. The differential equations are obtained in terms of displacement and rotational functions by substituting the stress-strain relations and strain-displacement relations in the governing equations and separable method is adopted for these functions to get a set of ordinary differential equations in term of single variable, which are coupled. These displacement and rotational functions are approximated using cubic and quantic splines which results in to the system of algebraic equations with unknown spline coefficients. Incurring the boundary conditions with the algebraic equations, a generalized eigen value problem is obtained. This eigen value problem is solved numerically to find the eigen frequency parameter and associated eigenvectors which are the spline coefficients.The material properties of Kevlar-49/epoxy, Graphite/Epoxy and E-glass epoxy are used to show the parametric effects of the plates aspect ratio, side-to-thickness ratio, stacking sequence, number of lamina and ply orientations on the frequency parameter of the plate. The current results are verified with those results obtained in the previous work and the new results are presented in tables and graphs.

Transition probability from the ground to the first-excited 2^+ state of even-even nuclides

Abstract: Adopted values for the reduced electric quadrupole transition probability, B(E2)↑, from the ground state to the first-excited 2+ state of even–even nuclides are given in Table I. Values of τ, the mean life of the 2+ state; E, the energy; and β, the quadrupole deformation parameter, are also listed there. The ratio of β to the value expected from the single-particle model is presented. The intrinsic quadrupole moment, Q0, is deduced from the B(E2)↑ value. The product E×B(E2)↑ is expressed as a percentage of the energy-weighted total and isoscalar E2 sum-rule strengths. Table II presents the data on which Table I is based, namely the experimental results for B(E2)↑ values with quoted uncertainties. Information is also given on the quantity measured and the method used. The literature has been covered to November 2000. The adopted B(E2)↑ values are compared in Table III with the values given by systematics and by various theoretical models. Predictions of unmeasured B(E2)↑ values are also given in Table III.

Compound Copper Chalcogenide Nanocrystals

Abstract: This review captures the synthesis, assembly, properties, and applications of copper chalcogenide NCs, which have achieved significant research interest in the last decade due to their compositional and structural versatility. The outstanding functional properties of these materials stems from the relationship between their band structure and defect concentration, including charge carrier concentration and electronic conductivity character, which consequently affects their optoelectronic, optical, and plasmonic properties. This, combined with several metastable crystal phases and stoichiometries and the low energy of formation of defects, makes the reproducible synthesis of these materials, with tunable parameters, remarkable. Further to this, the review captures the progress of the hierarchical assembly of these NCs, which bridges the link between their discrete and collective properties. Their ubiquitous application set has cross-cut energy conversion (photovoltaics, photocatalysis, thermoelectrics), en...

Trapped charge-driven degradation of perovskite solar cells

Abstract: Perovskite solar cells have shown unprecedent performance increase up to 22% efficiency. However, their photovoltaic performance has shown fast deterioration under light illumination in the presence of humid air even with encapulation. The stability of perovskite materials has been unsolved and its mechanism has been elusive. Here we uncover a mechanism for irreversible degradation of perovskite materials in which trapped charges, regardless of the polarity, play a decisive role. An experimental setup using different polarity ions revealed that the moisture-induced irreversible dissociation of perovskite materials is triggered by charges trapped along grain boundaries. We also identified the synergetic effect of oxygen on the process of moisture-induced degradation. The deprotonation of organic cations by trapped charge-induced local electric field would be attributed to the initiation of irreversible decomposition.

A piperidinium salt stabilizes efficient metal-halide perovskite solar cells.

Abstract: Longevity has been a long-standing concern for hybrid perovskite photovoltaics. We demonstrate high-resilience positive-intrinsic-negative perovskite solar cells by incorporating a piperidinium-based ionic compound into the formamidinium-cesium lead-trihalide perovskite absorber. With the bandgap tuned to be well suited for perovskite-on-silicon tandem cells, this piperidinium additive enhances the open-circuit voltage and cell efficiency. This additive also retards compositional segregation into impurity phases and pinhole formation in the perovskite absorber layer during aggressive aging. Under full-spectrum simulated sunlight in ambient atmosphere, our unencapsulated and encapsulated cells retain 80 and 95% of their peak and post-burn-in efficiencies for 1010 and 1200 hours at 60° and 85°C, respectively. Our analysis reveals detailed degradation routes that contribute to the failure of aged cells.

Quantum dot-sensitized solar cells

Abstract: Quantum dot-sensitized solar cells (QDSCs) have emerged as a promising candidate for next-generation solar cells due to the distinct optoelectronic features of quantum dot (QD) light-harvesting materials, such as high light, thermal, and moisture stability, facilely tunable absorption range, high absorption coefficient, multiple exciton generation possibility, and solution processability as well as their facile fabrication and low-cost availability. In recent years, we have witnessed a dramatic boost in the power conversion efficiency (PCE) of QDSCs from 5% to nearly 13%, which is comparable to other kinds of emerging solar cells. Both the exploration of new QD light-harvesting materials and interface engineering have contributed to this fantastically fast improvement. The outstanding development trend of QDSCs indicates their great potential as a promising candidate for next-generation photovoltaic cells. In this review article, we present a comprehensive overview of the development of QDSCs, including: (1) the fundamental principles, (2) a history of the brief evolution of QDSCs, (3) the key materials in QDSCs, (4) recombination control, and (5) stability issues. Finally, some directions that can further promote the development of QDSCs in the future are proposed to help readers grasp the challenges and opportunities for obtaining high-efficiency QDSCs.