Kofi Adomako-Ansah

Bio: Kofi Adomako-Ansah is an academic researcher from University of Mines and Technology. The author has contributed to research in topics: Zircon & Quartz-porphyry. The author has an hindex of 1, co-authored 3 publications receiving 3 citations.

Depositional Environment and Genesis of the Nabeba Banded Iron Formation (BIF) in the Ivindo Basement Complex, Republic of the Congo: Perspective from Whole-Rock and Magnetite Geochemistry

Abstract: The Nabeba high-grade iron deposit (Republic of the Congo) is hosted by banded iron formation (BIF) in the Ivindo Basement Complex, which lies in the northwestern part of the Congo Craton. The Nabeba BIF is intercalated with chlorite-sericite-quartz schist and comprises two facies (oxide and a carbonate-oxide). In this study, whole-rock and LA-ICP-MS magnetite geochemistry of the BIF was reported. Magnetite samples from both BIF facies had fairly similar trace element compositions except for the rare earth element plus yttrium (REE + Y) distribution patterns. The high V, Ni, Cr, and Mg contents of the magnetite in the Nabeba BIF could be ascribed to the involvement of external medium-high temperature hydrothermal fluids during their deposition in relatively reduced environment. The Post-Archean Australian Shale (PAAS)-normalized REY patterns of the Nabeba BIF magnetite were characterized by LREE depletion coupled with varying La and positive Eu anomalies. Processing of the information gathered from the geochemical signatures of magnetite and the whole-rock BIF suggested that the Nabeba BIF was formed by the mixing of predominantly anoxic seawater (99.9%) with 0.1% of high-temperature (>250 °C) hydrothermal vent fluids, similar to the formation mechanism of many Archean Algoma-type BIFs reported elsewhere in the world.

Earth's first stable continents did not form by subduction

Abstract: Phase equilibria modelling of rocks from Western Australia confirms that the ancient continental crust could have formed by multistage melting of basaltic ‘parents’ along high geothermal gradients—a process incompatible with modern-style subduction Tim Johnson et al perform phase equilibria modelling of the Coucal basalts from Western Australia and confirm their suitability as parent rocks of the Archaean continental crust The authors suggest that these early crustal rocks were produced by 20–30 per cent melting along high geothermal gradients They conclude that the production and stabilization of the first continents required a protracted, multistage process When coupled with the high geothermal gradients, this suggests that the continents did not form by subduction Instead it favours a 'stagnant lid' regime in the early Archaean eon in which a single, rigid plate lay over the mantle The geodynamic environment in which Earth’s first continents formed and were stabilized remains controversial1 Most exposed continental crust that can be dated back to the Archaean eon (4 billion to 25 billion years ago) comprises tonalite–trondhjemite–granodiorite rocks (TTGs) that were formed through partial melting of hydrated low-magnesium basaltic rocks2; notably, these TTGs have ‘arc-like’ signatures of trace elements and thus resemble the continental crust produced in modern subduction settings3 In the East Pilbara Terrane, Western Australia, low-magnesium basalts of the Coucal Formation at the base of the Pilbara Supergroup have trace-element compositions that are consistent with these being source rocks for TTGs These basalts may be the remnants of a thick (more than 35 kilometres thick), ancient (more than 35 billion years old) basaltic crust4,5 that is predicted to have existed if Archaean mantle temperatures were much hotter than today’s6,7,8 Here, using phase equilibria modelling of the Coucal basalts, we confirm their suitability as TTG ‘parents’, and suggest that TTGs were produced by around 20 per cent to 30 per cent melting of the Coucal basalts along high geothermal gradients (of more than 700 degrees Celsius per gigapascal) We also analyse the trace-element composition of the Coucal basalts, and propose that these rocks were themselves derived from an earlier generation of high-magnesium basaltic rocks, suggesting that the arc-like signature in Archaean TTGs was inherited from an ancestral source lineage This protracted, multistage process for the production and stabilization of the first continents—coupled with the high geothermal gradients—is incompatible with modern-style plate tectonics, and favours instead the formation of TTGs near the base of thick, plateau-like basaltic crust9 Thus subduction was not required to produce TTGs in the early Archaean eon

Lithostratigraphy, Origin, and Geodynamic Setting of Iron Formations and Host Rocks of the Anyouzok Region, Congo Craton, Southwestern Cameroon

Abstract: In Cameroon, most of the iron formation occurrences reported are found within the Nyong and Ntem Complexes. The Anyouzok iron deposit is located in the Nyong Complex greenstone belts, which represent the NW margin of this Congo craton. The main lithological units comprise the iron formations (IFs) unit, consisting of banded IFs (BIFs) and sheared BIFs (SBIFs), and the associated metavolcanic rocks unit consisting of mafic granulite, garnet amphibolite, and biotite gneiss. Within the Anyouzok area, BIFs are rare, while SBIFs are ubiquitous. This study reports the petrography, mineralogy, and whole rock geochemistry of IFs and interbedded metavolcanic rocks of the Anyouzok iron deposit. The abundance of cavities, higher Fe contents (49.60–55.20 wt%), and strong Eu anomalies (Eu/Eu* = 2.14–3.17) within the SBIFs compared to the BIFs suggest that SBIFs were upgraded through post-depositional hydrothermal alteration activities. REE signatures indicate the contribution of both seawater and hydrothermal fluids during BIFs precipitation. Mafic granulite and garnet amphibolite protoliths were derived from the partial melting of a metasomatized spinel lherzolite depleted mantle source. The overall compositional variations of the Anyouzok IFs and interbedded metavolcanic rocks endorse an Algoma-type formation deposited in the back-arc basin under suboxic to anoxic conditions.

Petrology and geochemistry of metamorphosed rocks associated with iron formations of the Toko‐Nlokeng iron deposit, (Southern Cameroon): Implications for geodynamic evolution and mineralization

Abstract: Detailed petrographic, lithostratigraphic, and geochemical data of metamorphosed orthogneisses and mafic‐ultramafic metavolcanic rocks intruded into the greenstone belt of the Toko‐Nlokeng iron deposit have enabled the reconstruction of the tectonic and geodynamic setting and crustal evolution of the Nyong Complex. Samples were collected from the drill holes TNF11_01 and TNF11_02 from 17.16 m to 335.85 m depth. The lithostratigraphy supported by field and petrographic observations outlines two main lithologies: Iron formations (IFs) and metamorphosed host rocks. The IFs (granular iron formations (GIF) and banded iron formations (BIF)) are intercalated with host rocks consisting of orthogneisses and mafic‐ultramafic rocks. New and published geochemical data of metamorphosed associated IFs from Anyouzok (TNF08 prospect) of the Toko‐Nlokeng iron deposit, Mewengo iron deposit, Bipindi, and Kribi metavolcanic rocks in the Nyong Complex, suggest that these rocks were formed by material from intrusive and extrusive magmatic episodes with mid‐ocean ridge basalts (MORB) contaminated by either subduction or crustal components. CaO/Al2O3 and (Gd/Yb)N ratios >1 and positive Nb anomalies in ultramafic rocks indicate a mantle plume source contaminated by metasomatized subduction mantle lithosphere. These data also show that the mafic‐ultramafic metavolcanic rocks derive from magma of basaltic and basaltic andesite compositions, with a tholeiitic to calc‐alkaline tendency characteristic of the upper mantle. These data reveal that gneisses derive from granite and diorite subalkaline, peraluminous, and ferroan to magnesian compatible with Cordilleran magmas and island arcs with polygenetic crustal signatures. All samples of mafic granulites, garnet‐amphibolite, metabasites, and ultramafic granulites in the Nyong Complex reveal no residual garnet and predominantly show ca. 4% partial melting of an amphibole‐spinel‐peridotite source in the Dy/Yb versus La/Yb. Otherwise, hornblendites of Toko‐Nlokeng display ca. 5% partial melting of an amphibole‐garnet‐peridotite source, average (Gd/Yb)CN ratio of the hornblendites is (Gd/Yb)CN = 7.56 > 2. This result suggests these hornblendites do not have the same magmatic source as other mafic‐ultramafic rocks of the Nyong Complex. Mafic‐ultramafic host rock protoliths are classified as E‐MORB, P‐MORB, and G‐MORB (hornblendites) compositional types and arc, back‐arc ‘B’ in subduction unrelated, rifted margin setting with minor crustal contamination. The tholeiitic to calc‐alkaline and peraluminous affinity of these rocks indicate a mature arc and thickened crust during the Eburnean Trans‐Amazonian orogenic belts of the Congo Craton. This study shows that the host rocks were emplaced in a convergent tectonic setting and affected by a syn‐collisional episode where melts were derived from the partial melting of thick basaltic crust into amphibolite–eclogite facies in the subduction zone. The geochemical signatures of the mafic‐ultramafic rocks support the tectonic accretionary of the Palaeoproterozoic plume arc in Nyong Complex. Furthermore, the resulting hydrothermal alteration process was accompanied by an increase in Fe; particularly under conditions dominated by seawater, the origin and source of iron and silica in the Toko‐Nlokeng deposit.