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L.B. Rogers

Bio: L.B. Rogers is an academic researcher from Purdue University. The author has contributed to research in topics: Bond energy & Pyridine. The author has an hindex of 1, co-authored 1 publications receiving 37 citations.

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TL;DR: A series of transition-metal pyridine complexes, [M(py) 2 X 2] and two series of copper (II) chloride complexes with mono-and dimethyl substituted pyridines and with 4-substituted pyrids were studied by differential thermal analysis as mentioned in this paper.

38 citations


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TL;DR: In this article, the stochastic properties of the thermal decomposition of Ni(pyNO)Cl2H2O (I, III, IV, VIII) and Ni(4-MepyNO)2Cl2(V, VI, VII) were studied.
Abstract: The stoichiometry of thermal decomposition was studied for the following compounds: Ni(pyNO)Cl2H2O (I), (pyNO=pyridine N-oxide), Ni(2-MepyNO)Cl2·2H2O (II), Ni(3-MepyNo)Cl2·2H2O (III) and Ni(4-MepyNO)2Cl2·C2H5OH (IV). The heating of the compounds led first to the release of H2O molecules (or C2H5OH molecules), with the formation of Ni(pyNO)Cl2 (V), Ni(2-MepyNO)Cl2(VI), Ni(3-MepyNO)Cl2 (VII) and Ni(4-MepyNO)2Cl2 (VIII). In the next stage, decomposition of the heterocyclic liugands set in. The compositions and spectral and magnetic properties of these complexes indicate their dimeric (II, III, IV, VIII) of polymeric (I, V, VI, VII) structure with coordinated molecules of H2O (or C2H5OH).

36 citations

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TL;DR: The thermal decomposition of palladium(II) chloride with pyridine and several methyl and dimethylpyridines has been studied using differential scanning calorimetry as mentioned in this paper.

30 citations

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TL;DR: In this article, a DTA study of the adsorption of aliphatic and aromatic amines by montmorillonite is described in detail, in order to demonstrate how this technique is applicable for the study of surface reactions.

30 citations

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TL;DR: In this paper, the suitability of some chelate compounds to the zone melting process, some β-diketone chelates of copper, beryllium, palladium, nickel and cobalt were prepared in the hope of identifying those of low melting points and of high thermal stabilities.

28 citations