Author
L. C. Brinson
Other affiliations: National Instruments, California Institute of Technology
Bio: L. C. Brinson is an academic researcher from Northwestern University. The author has contributed to research in topics: Viscoelasticity & Constitutive equation. The author has an hindex of 36, co-authored 68 publications receiving 10409 citations. Previous affiliations of L. C. Brinson include National Instruments & California Institute of Technology.
Papers published on a yearly basis
Papers
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TL;DR: Modulus, ultimate strength and thermal stability follow a similar trend, with values for functionalized graphene sheet- poly(methyl methacrylate) rivaling those for single-walled carbon nanotube-poly(methyl methamphetamine) composites.
Abstract: Polymer-based composites were heralded in the 1960s as a new paradigm for materials. By dispersing strong, highly stiff fibres in a polymer matrix, high-performance lightweight composites could be developed and tailored to individual applications. Today we stand at a similar threshold in the realm of polymer nanocomposites with the promise of strong, durable, multifunctional materials with low nanofiller content. However, the cost of nanoparticles, their availability and the challenges that remain to achieve good dispersion pose significant obstacles to these goals. Here, we report the creation of polymer nanocomposites with functionalized graphene sheets, which overcome these obstacles and provide superb polymer-particle interactions. An unprecedented shift in glass transition temperature of over 40 degrees C is obtained for poly(acrylonitrile) at 1 wt% functionalized graphene sheet, and with only 0.05 wt% functionalized graphene sheet in poly(methyl methacrylate) there is an improvement of nearly 30 degrees C. Modulus, ultimate strength and thermal stability follow a similar trend, with values for functionalized graphene sheet- poly(methyl methacrylate) rivaling those for single-walled carbon nanotube-poly(methyl methacrylate) composites.
3,245 citations
01 Jan 1993
TL;DR: In this paper, a one-dimensional constitutive model for the thermomechanical behavior of shape memory alloys is developed based on previous work by Liang and Tanaka, where an internal variable approach is used to derive a comprehensive constitutive law for shape memory alloy materials from first principles without the assumption of constant material functions.
Abstract: A one-dimensional constitutive model for the thermomechanical behavior of shape memory alloys is developed based on previous work by Liang and Tanaka. An internal variable approach is used to derive a comprehensive constitutive law for shape memory alloy materials from first principles without the assumption of constant material functions. This constitutive law is of such a form that it is well suited to further practical engineering applications and calculations. A separation of the martensite fraction internal variable into temperature-induced and stress-induced parts is presented and justified which then allows the derived constitutive law to accurately represent both the pseudoelastic and shape memory effects at all temperatures. Several numerical examples are given which illustrate the ability of the constitutive law to capture the unique thermomechanical behavior of shape memory alloys due to their internal phase transformations with stress and temperature.
1,350 citations
TL;DR: In this article, single-walled carbon nanotubes (SWCNTs) were functionalized with amino groups via chemical modification of carboxyl groups introduced on the carbon nanotide surface.
Abstract: Single-walled carbon nanotubes (SWCNT) functionalized with amino groups were prepared via chemical modification of carboxyl groups introduced on the carbon nanotube surface. Two different approaches (amide and amine-moieties) were used to produce the amino-functionalized nanotubes. The amino-termination allows further chemistry of the functionalized SWCNTs and makes possible covalent bonding to polymers and biological systems such as DNA and carbohydrates. The functionalization of the SWCNTs was characterized in detail using FTIR and XPS.
965 citations
TL;DR: In this paper, a model combining finite element results and micromechanical methods was developed to determine the effective reinforcing modulus of a wavy embedded nanotube, which was then used within a multiphase micro-computational model to predict the effective modulus for polymers with a distribution of wavy nanotubes.
464 citations
TL;DR: In this paper, the authors focused on the reinforcement mechanisms in multiwalled carbon nanotube (MWCNT)/bisphenol-A polycarbonate (PC) composites.
325 citations
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TL;DR: An overview of the synthesis, properties, and applications of graphene and related materials (primarily, graphite oxide and its colloidal suspensions and materials made from them), from a materials science perspective.
Abstract: There is intense interest in graphene in fields such as physics, chemistry, and materials science, among others. Interest in graphene's exceptional physical properties, chemical tunability, and potential for applications has generated thousands of publications and an accelerating pace of research, making review of such research timely. Here is an overview of the synthesis, properties, and applications of graphene and related materials (primarily, graphite oxide and its colloidal suspensions and materials made from them), from a materials science perspective.
8,919 citations
TL;DR: The use of colloidal suspensions to produce new materials composed of graphene and chemically modified graphene is reviewed, which is both versatile and scalable, and is adaptable to a wide variety of applications.
Abstract: Interest in graphene centres on its excellent mechanical, electrical, thermal and optical properties, its very high specific surface area, and our ability to influence these properties through chemical functionalization. There are a number of methods for generating graphene and chemically modified graphene from graphite and derivatives of graphite, each with different advantages and disadvantages. Here we review the use of colloidal suspensions to produce new materials composed of graphene and chemically modified graphene. This approach is both versatile and scalable, and is adaptable to a wide variety of applications.
6,178 citations
TL;DR: In this article, a new family of two-dimensional early transition metal carbides and carbonitrides, called MXenes, was discovered and a detailed outlook for future research on MXenes is also presented.
Abstract: Recently a new, large family of two-dimensional (2D) early transition metal carbides and carbonitrides, called MXenes, was discovered. MXenes are produced by selective etching of the A element from the MAX phases, which are metallically conductive, layered solids connected by strong metallic, ionic, and covalent bonds, such as Ti2AlC, Ti3AlC2, and Ta4AlC3. MXenes combine the metallic conductivity of transition metal carbides with the hydrophilic nature of their hydroxyl or oxygen terminated surfaces. In essence, they behave as “conductive clays”. This article reviews progress—both experimental and theoretical—on their synthesis, structure, properties, intercalation, delamination, and potential applications. MXenes are expected to be good candidates for a host of applications. They have already shown promising performance in electrochemical energy storage systems. A detailed outlook for future research on MXenes is also presented.
3,973 citations
TL;DR: Department of Materials Science, University of Patras, Greece, Theoretical and Physical Chemistry Institute, National Hellenic Research Foundation, and Dipartimento di Scienze Farmaceutiche, Universita di Trieste, Piazzale Europa 1, 34127 Triesteadays.
Abstract: Department of Materials Science, University of Patras, 26504 Rio Patras, Greece, Theoretical and Physical Chemistry Institute, National Hellenic Research Foundation, 48 Vass. Constantinou Avenue, 116 35 Athens, Greece, Institut de Biologie Moleculaire et Cellulaire, UPR9021 CNRS, Immunologie et Chimie Therapeutiques, 67084 Strasbourg, France, and Dipartimento di Scienze Farmaceutiche, Universita di Trieste, Piazzale Europa 1, 34127 Trieste, Italy
3,886 citations
TL;DR: The direct synthesis of three-dimensional foam-like graphene macrostructures, which are called graphene foams (GFs), by template-directed chemical vapour deposition is reported, demonstrating the great potential of GF/poly(dimethyl siloxane) composites for flexible, foldable and stretchable conductors.
Abstract: [Chen, Zongping; Ren, Wencai; Gao, Libo; Liu, Bilu; Pei, Songfeng; Cheng, Hui-Ming] Chinese Acad Sci, Shenyang Natl Lab Mat Sci, Inst Met Res, Shenyang 110016, Peoples R China.;Cheng, HM (reprint author), Chinese Acad Sci, Shenyang Natl Lab Mat Sci, Inst Met Res, Shenyang 110016, Peoples R China;cheng@imr.ac.cn
3,517 citations