Laurence S. Rothman

Bio: Laurence S. Rothman is an academic researcher from Air Force Research Laboratory. The author has contributed to research in topics: HITRAN & Environment variable. The author has an hindex of 5, co-authored 14 publications receiving 999 citations.

The HITRAN molecular spectroscopic database and HAWKS (HITRAN atmospheric workstation)

Abstract: Nineteen ninety-eight marks the 25th anniversary of the release of the first HITRAN database. HITRAN is recognized as the international standard of the fundamental spectroscopic parameters for diverse atmospheric and laboratory transmission and radiance calculations. There have been periodic editions of HITRAN over the past decades as the database has been expanded and improved with respect to the molecular species and spectral range covered, the number of parameters included, and the accuracy of this information. The 1996 edition not only includes the customary line-by-line transition parameters familiar to HITRAN users, but also cross-section data, aerosol indices of refraction, software to filter and manipulate the data, and documentation. This paper describes the data and features that have been added or replaced since the previous edition of HITRAN. We also cite instances of critical data that is forthcoming. A new release is planned for 1998.

IUPAC Technical report

Abstract: The report and results of an IUPAC Task Group (TG) formed in 2004 on "A Database of Water Tran- sitions from Experiment and Theory" (Project No. 2004-035-1-100) are presented. Energy levels and recom- mended labels involving exact and approximate quantum numbers for the main isotopologues of water in the gas phase, H 2 16 O, H 2 18 O, H 2 17 O, HD 16 O, HD 18 O, HD 17 O, D 2 16 O, D 2 18 O, and D 2 17 O, are determined from meas- ured transition frequencies. The transition frequencies and energy levels are validated using first-princi- ples nuclear motion computations and the MARVEL (measured active rotational-vibrational energy levels) approach. The extensive data including lines and levels are required for analysis and synthesis of spectra, thermochemical applications, the construction of theoretical models, and the removal of spectral contamina- tion by ubiquitous water lines. These datasets can also be used to assess where measurements are lacking for each isotopologue and to provide accurate frequencies for many yet-to-be measured transitions. The lack of high-quality frequency calibration standards in the near infrared is identified as an issue that has hindered the determination of high-accuracy energy levels at higher frequencies. The generation of spectra using the MARVEL energy levels combined with transition intensities computed using high accuracy ab initio dipole moment surfaces are discussed. A recommendation of the TG is for further work to identify a single, suitable model to represent pressure- (and temperature-) dependent line profiles more accurately than Voigt profiles.

Absorption cross-sections in HITRAN2016 database: extensive update in the infrared for climate, environment, and atmospheric applications

Abstract: Accounting for volatile organic compounds (VOCs) is crucial for many applications, including, for example, climate change monitoring, tracking of pollution and biomass burning, and atmospheric remote sensing For many such molecules, the line-by-line spectroscopic data are still either unavailable, or incomplete The spectroscopic databases, however, often give the wavenumber-dependent absorption cross-sections for each temperature and pressure set In this paper we give a detailed overview for the current state of the HITRAN2016 infrared absorption cross-section part The updated cross-sections include data for around 320 compounds, with more than 260 compounds being included in the database for the first time These cross-sections come from high-resolution laboratory observations, predominantly from Fourier transform spectrometers The update largely relies on spectra from the Pacific Northwest National Laboratory quantitative spectroscopic database and the Hodnebrog et al (Rev Geophys 2013) compilation, but also on other recently published data We give a description for the most atmospherically important compounds arranged by chemical categories, and validate the existing data sources for many of them We also describe the HITRAN infrastructure which gives access to the data for all molecules from HITRAN, and discuss the best practices of searching the data This update increases the amount of molecules in the HITRAN database almost six-fold compared to the previous edition, HITRAN2012; it is available via the HITRANonline website (wwwhitranorg) and HITRAN Application Programming Interface (HAPI)

The HITRAN 2008 molecular spectroscopic database

Abstract: This paper describes the contents of the 2016 edition of the HITRAN molecular spectroscopic compilation. The new edition replaces the previous HITRAN edition of 2012 and its updates during the intervening years. The HITRAN molecular absorption compilation is composed of five major components: the traditional line-by-line spectroscopic parameters required for high-resolution radiative-transfer codes, infrared absorption cross-sections for molecules not yet amenable to representation in a line-by-line form, collision-induced absorption data, aerosol indices of refraction, and general tables such as partition sums that apply globally to the data. The new HITRAN is greatly extended in terms of accuracy, spectral coverage, additional absorption phenomena, added line-shape formalisms, and validity. Moreover, molecules, isotopologues, and perturbing gases have been added that address the issues of atmospheres beyond the Earth. Of considerable note, experimental IR cross-sections for almost 300 additional molecules important in different areas of atmospheric science have been added to the database. The compilation can be accessed through www.hitran.org. Most of the HITRAN data have now been cast into an underlying relational database structure that offers many advantages over the long-standing sequential text-based structure. The new structure empowers the user in many ways. It enables the incorporation of an extended set of fundamental parameters per transition, sophisticated line-shape formalisms, easy user-defined output formats, and very convenient searching, filtering, and plotting of data. A powerful application programming interface making use of structured query language (SQL) features for higher-level applications of HITRAN is also provided.

Atmospheric radiative transfer modeling: a summary of the AER codes

Abstract: The radiative transfer models developed at AER are being used extensively for a wide range of applications in the atmospheric sciences. This communication is intended to provide a coherent summary of the various radiative transfer models and associated databases publicly available from AER ( http://www.rtweb.aer.com ). Among the communities using the models are the remote sensing community (e.g. TES, IASI), the numerical weather prediction community (e.g. ECMWF, NCEP GFS, WRF, MM5), and the climate community (e.g. ECHAM5). Included in this communication is a description of the central features and recent updates for the following models: the line-by-line radiative transfer model (LBLRTM); the line file creation program (LNFL); the longwave and shortwave rapid radiative transfer models, RRTM_LW and RRTM_SW; the Monochromatic Radiative Transfer Model (MonoRTM); the MT_CKD Continuum; and the Kurucz Solar Source Function. LBLRTM and the associated line parameter database (e.g. HITRAN 2000 with 2001 updates) play a central role in the suite of models. The physics adopted for LBLRTM has been extensively analyzed in the context of closure experiments involving the evaluation of the model inputs (e.g. atmospheric state), spectral radiative measurements and the spectral model output. The rapid radiative transfer models are then developed and evaluated using the validated LBLRTM model.

Optical gas sensing: a review

Abstract: The detection and measurement of gas concentrations using the characteristic optical absorption of the gas species is important for both understanding and monitoring a variety of phenomena from industrial processes to environmental change. This study reviews the field, covering several individual gas detection techniques including non-dispersive infrared, spectrophotometry, tunable diode laser spectroscopy and photoacoustic spectroscopy. We present the basis for each technique, recent developments in methods and performance limitations. The technology available to support this field, in terms of key components such as light sources and gas cells, has advanced rapidly in recent years and we discuss these new developments. Finally, we present a performance comparison of different techniques, taking data reported over the preceding decade, and draw conclusions from this benchmarking.

The HITRAN molecular spectroscopic database: edition of 2000 including updates through 2001

Abstract: This paper describes the status circa 2001, of the HITRAN compilation that comprises the public edition available through 2001. The HITRAN compilation consists of several components useful for radiative transfer calculation codes: high-resolution spectroscopic parameters of molecules in the gas phase, absorption cross-sections for molecules with very dense spectral features, aerosol refractive indices, ultraviolet line-by-line parameters and absorption cross-sections, and associated database management software. The line-by-line portion of the database contains spectroscopic parameters for 38 molecules and their isotopologues and isotopomers suitable for calculating atmospheric transmission and radiance properties. Many more molecular species are presented in the infrared cross-section data than in the previous edition, especially the chlorofluorocarbons and their replacement gases. There is now sufficient representation so that quasi-quantitative simulations can be obtained with the standard radiance codes. In addition to the description and justification of new or modified data that have been incorporated since the last edition of HITRAN (1996), future modifications are indicated for cases considered to have a significant impact on remote-sensing experiments. (C) 2003 Elsevier Ltd. All rights reserved.

The Global Ozone Monitoring Experiment (GOME): Mission Concept and First Scientific Results

Abstract: The Global Ozone Monitoring Experiment (GOME) is a new instrument aboard the European Space Agency’s (ESA) Second European Remote Sensing Satellite (ERS-2), which was launched in April 1995. The main scientific objective of the GOME mission is to determine the global distribution of ozone and several other trace gases, which play an important role in the ozone chemistry of the earth’s stratosphere and troposphere. GOME measures the sunlight scattered from the earth’s atmosphere and/or reflected by the surface in nadir viewing mode in the spectral region 240–790 nm at a moderate spectral resolution of between 0.2 and 0.4 nm. Using the maximum 960-km across-track swath width, the spatial resolution of a GOME ground pixel is 40 × 320 km2 for the majority of the orbit and global coverage is achieved in three days after 43 orbits. Operational data products of GOME as generated by DLR-DFD, the German Data Processing and Archiving Facility (D-PAF) for GOME, comprise absolute radiometrically calibrated e...